Piccoliite (original) (raw)

A valid IMA mineral species

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About PiccoliiteHide

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Formula:

NaCaMn3+2(AsO4)2O(OH)

Colour:

Black. It is transparent in thin section although very deep red coloured.

Specific Gravity:

4.084 (Calculated)

Crystal System:

Orthorhombic

Name:

In honour of the mineral collectors Gian Paolo Piccoli (1928–1996) and his son Gian Carlo (b. 1953) for their contribution to the knowledge of the regional mineralogy of Piedmont. It was first recognized on a specimen found in 2007 by Gian Carlo.

Co-Type Localities:

Valletta Mine, Vallone della Valletta, Canosio, Cuneo Province, Piedmont, Italy
Montaldo Mine (Montaldo di Mondovì Mine), Borgata Oberti, Montaldo di Mondovì, Cuneo Province, Piedmont, Italy

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:51847:1

f9ce2bd8-5f6e-4323-8ef0-50a49595c104

IMA Classification of PiccoliiteHide

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Classification of PiccoliiteHide

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8.BH.85

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Pcc IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PiccoliiteHide

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Colour:

Black. It is transparent in thin section although very deep red coloured.

Hardness:

VHN5=584 - 657 kg/mm2 - Vickers

Fracture:

Irregular/Uneven

Density:

4.084 g/cm3 (Calculated)

Comment:

Density was not measured. Calculated value is based on empirical data from Montaldo di Mondovì (4.011 for Valletta sample).

Optical Data of PiccoliiteHide

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Anisotropism:

Distinct, in shades of grey.

Reflectivity:

Wavelength R1 R2
470nm 7.7% 9.8%
546nm 7.7% 9.5%
589nm 7.4% 9.3%
650nm 7.4% 9.2%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 9.8%.
R1 shown in black, R2 shown in red

Colour in reflected light:

Grey.

Internal Reflections:

Common, in brownish tints.

Comments:

Calculated mean refractive index is 1.878.

Chemistry of PiccoliiteHide

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Mindat Formula:

NaCaMn3+2(AsO4)2O(OH)

Chemical AnalysisHide

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Empirical formulas:

Sample ID Empirical Formula
1 (Na0.64Ca0.35)?0.99(Ca0.75Na0.24)?0.99(Mn3+1.08Fe3+0.59Mg0.20Ca0.10)?1.97(As2.03V0.03Si0.01)?2.07O9(OH)

Crystallography of PiccoliiteHide

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Crystal System:

Orthorhombic

Class (H-M):

m m m _(_2/_m_2/_m_2/m ) - Dipyramidal

Cell Parameters:

a = 8.8761(9) Å, b = 7.5190(8) Å, c = 11.689(1) Å

Ratio:

a:b:c = 1.18 : 1 : 1.555

Unit Cell V:

780.12 ų (Calculated from Unit Cell)

Comment:

Data above for Montaldo di Mondovì sample. a = 8.8889, b = 7.5269, c = 11.6795 Å for Valletta sample.

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
4.85 Å (57)
3.470 Å (59)
3.167 Å (100)
2.742 Å (30)
2.683 Å (53)
2.580 Å (50)
2.325 Å (19)

Comments:

Montaldo Mine, Piedmont, Italy. Data from the type description.

Geological EnvironmentHide

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Type Occurrence of PiccoliiteHide

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Co-Type Localities:

Valletta Mine, Vallone della Valletta, Canosio, Cuneo Province, Piedmont, Italy
Montaldo Mine (Montaldo di Mondovì Mine), Borgata Oberti, Montaldo di Mondovì, Cuneo Province, Piedmont, Italy

General Appearance of Type Material:

Aggregates of black anhedral crystals, embedded in the quartz matrix, and rarely as black well-developed prisms.

Place of Conservation of Type Material:

Type material is deposited in the mineralogical collections of the Museo di Storia Naturale Naturale, Università di Pisa,Italy, catalogue number 19906 (holotype), and the Museo Civico Archeologico e di Scienze Naturali “F. Eusebio”, Alba, Italy, catalogue number.

Geological Setting of Type Material:

In Fe–Mn ore hosted in metaquartzites.

Associated Minerals at Type Locality:

Synonyms of PiccoliiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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8.BH. Crimsonite PbFe3+2(PO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH. Reznitskyite CaMg(VO4)F Mon. 2/m : _B_2/b
8.BH. Cuprozheshengite Pb4CuZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Zheshengite Pb4ZnZn2(AsO4)2(PO4)2(OH)2 Tric. 1 : _P_1
8.BH. Peterchinite Zn3Zn2(OH)6As[O3(OH)3] Mon. 2/m : _B_2/m
8.BH.05 Thadeuite Ca(Mg,Fe2+)3(PO4)2(OH,F)2 Orth. 222 : _C_2221
8.BH.10 Durangite NaAl(AsO4)F Mon. 2/m : _B_2/b
8.BH.10 Isokite CaMg(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Lacroixite NaAl(PO4)F Mon. 2/m : _B_2/b
8.BH.10 Maxwellite NaFe3+(AsO4)F Mon. 2/m : _P_2/m
8.BH.10 Panasqueiraite CaMg(PO4)(OH,F) Mon.
8.BH.10 Kononovite NaMg(SO4)F Mon. 2/m : _B_2/b
8.BH.10 Arsenatrotitanite NaTi(AsO4)O Mon. 2/m : _B_2/b
8.BH.15 Drugmanite Pb2(Fe3+,Al)(PO4)(PO3OH)(OH)2 Mon. 2/m : _P_21/b
8.BH.20 Bjarebyite (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Cirrolite Ca3Al2(PO4)3(OH)3 (?)
8.BH.20 Kulanite Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Penikisite Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Perloffite Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Johntomaite BaFe2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Bjarebyite Group
8.BH.20 Strontioperloffite SrMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.20 Plumboperloffite PbMn2+2Fe3+2(PO4)3(OH)3 Mon. 2/m : _P_21/m
8.BH.25 Bertossaite (Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Palermoite (Li,Na)2(Sr,Ca)Al4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.25 Natropalermoite Na2SrAl4(PO4)4(OH)4 Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.30 Carminite PbFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.30 Sewardite CaFe3+2(AsO4)2(OH)2 Orth. m m m _(_2/_m_2/_m_2/m ) : C c c m
8.BH.35 Adelite CaMg(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Arsendescloizite PbZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Austinite CaZn(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Cobaltaustinite CaCo(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Conichalcite CaCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite PbCu(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Gabrielsonite PbFe3+(As3+O3)O Orth. m _m_2 : P m _c_21
8.BH.35 Nickelaustinite CaNi(AsO4)(OH) Orth. 222 : _P_212121
8.BH.35 Tangeite CaCu(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Duftite-alpha PbCu(AsO4)(OH)
8.BH.35 Gottlobite CaMg(VO4)(OH) Orth. 222 : _P_212121
8.BH.35 Hermannroseite CaCu(PO4)(OH) Orth. 222 : _P_212121
8.BH.40 Čechite PbFe2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m )
8.BH.40 Descloizite PbZn(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Mottramite PbCu(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Pyrobelonite PbMn2+(VO4)(OH) Orth. m m m _(_2/_m_2/_m_2/m ) : P n m a
8.BH.40 Khorixasite (Bi0.67◻0.33)Cu(VO4)(OH) Mon. 2/m : _P_2/m
8.BH.45 Bayldonite PbCu3(AsO4)2(OH)2 Mon. 2/m : _B_2/b
8.BH.45 Vésigniéite BaCu3(VO4)2(OH)2 Mon. 2/m : _B_2/m
8.BH.50 Paganoite NiBi(AsO4)O Tric. 1 : _P_1
8.BH.55 Harrisonite Ca(Fe2+,Mg)6(PO4)2(SiO4)2 Trig. 3_m_ _(_32/m ) : R_3_m
8.BH.55 Jagowerite BaAl2(PO4)2(OH)2 Tric.
8.BH.60 Attakolite CaMn2+Al4(SiO3OH)(PO4)3(OH)4 Mon. 2/m : _B_2/m
8.BH.65 Leningradite PbCu3(VO4)2Cl Orth. m m m _(_2/_m_2/_m_2/m ) : I b a m
8.BH.70 Katiarsite KTiO(AsO4) Orth. m _m_2 : P n _a_21
8.BH.70 Yurgensonite K2SnTiO2(AsO4)2 Orth. m _m_2 : P n _a_21
8.BH.75 Melanarsite K3Cu7Fe3+O4(AsO4)4 Mon. 2/m : _B_2/b
8.BH.80 Moraskoite Na2Mg(PO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n
8.BH.80 Evseevite Na2Mg(AsO4)F Orth. m m m _(_2/_m_2/_m_2/m ) : P b c n

Fluorescence of PiccoliiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for PiccoliiteHide

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Reference List:

Cámara, F., Biagioni, C., Ciriotti, M.E., Bosi, F., Kolitsch, U., Paar, W.H., Blass, G., Bittarello, E. (2017) Piccoliite, a new mineral of the pilawite group. Joint SIMP-SGI-AIV-SoGeI 2017 Conference "Geosciences: a tool in a changing world", Pisa, Italy, September 3-6, 2017, Abstract book: 120. http://www.socgeol.it/files/download/abstract%20book/abstract_book_pisa_2017_doi.pdf

Cámara, Fernando, Biagioni, Cristian, Ciriotti, Marco E., Bosi, Ferdinando, Kolitsch, Uwe, Paar, Werner H., Hålenius, Ulf, Lepore, Giovanni O., Blass, Günter, Bittarello, Erica (2022) Piccoliite, NaCaMn3+2(AsO4)2O(OH), a new arsenate from the manganese deposits of Montaldo di Mondovì and Valletta, Piedmont, Italy. Mineralogical Magazine, 87 (2) 204-217 doi:10.1180/mgm.2022.129

Localities for PiccoliiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Italy (TL)
Piedmont Cuneo Province Canosio Vallone della Valletta Valletta Mine (TL) Hålenius et al. (2017) +2 other references
Montaldo di Mondovì Borgata Oberti Montaldo Mine (Montaldo di Mondovì Mine) (TL) www.socgeol.it (n.d.) +5 other references