Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia (original) (raw)

Achyrophanite (TL)

Formula: (K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5

Type Locality:

Aegirine

Formula: NaFe3+Si2O6

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Aegirine-augite

Formula: (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Alarsite

Formula: AlAsO4

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03

Albite

Formula: Na(AlSi3O8)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Albite var. Anorthoclase

Formula: (Na,K)AlSi3O8

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Aleutite (TL)

Formula: [Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)Cl

Type Locality:

Allochalcoselite (TL)

Formula: Cu+PbCu2+5(SeO3)2Cl5O2

Type Locality:

References:

Vergasova, L.P., Krivovichev, S.V., Britvin, S.N., Fitatov, S.K., Berns, P.K., Ananyev, V.V. (2005) Allochalcoselite, Cu+Cu2+5 PbO2(SeO3)2Cl5 - a new mineral from volcanic exhalations (Kamchatka, Russia). Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva, 134(3), 70-74 .

Ercit, T.S., Piilonen, P.C., Locock, A.J., Kolitsch, U., Rowe, R. (2006) New mineral names. American Mineralogist, 91, 1201-1209.

Alumoedtollite (TL)

Formula: K2NaCu5AlO2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Ksenofontov, Dmitry A., Pautov, Leonid A., Sidorov, Evgeny G., Britvin, Sergey N., Vigasina, Marina F., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineralogical Magazine, 83 (4) 485-495 doi:10.1180/mgm.2018.155

Alumoklyuchevskite

Formula: K3Cu3(Al,Fe3+)(SO4)4O2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Anatolyite (TL)

Formula: Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6

Type Locality:

References:

Pekov, Igor V., Lykova, Inna S., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Scheidl, Katharina S. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XI. Anatolyite, Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6. Mineralogical Magazine, 83 (5) 633-638 doi:10.1180/mgm.2019.11

Andradite

Formula: Ca3Fe3+2(SiO4)3

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Anglesite

Formula: PbSO4

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Anglesite var. Copper-bearing Anglesite

Formula: (Pb,Cu)SO4

Anhydrite

Formula: CaSO4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Anorthite

Formula: Ca(Al2Si2O8)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Anorthite var. Labradorite

Formula: (Ca,Na)[Al(Al,Si)Si2O8]

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Antipovite (TL)

Formula: Cu5O2(PO4)2

Type Locality:

Antofagastaite

Formula: Na2Ca(SO4)2 · 1.5H2O

References:

Pekov, Igor V., Kovrugin, Vadim M., Siidra, Oleg I., Chukanov, Nikita V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Yapaskurt, Vasiliy O., Turchkova, Anna G., Möhn, Gerhard (2019) Antofagastaite, Na2Ca(SO4)2·1.5H2O, a new mineral related to syngenite. Mineralogical Magazine, 83 (6) 781-790 doi:10.1180/mgm.2019.17

Aphthitalite

Formula: (K,Na)3Na(SO4)2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Arcanite

Formula: K2SO4

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Arsenatrotitanite (TL)

Formula: NaTi(AsO4)O

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134

Arsenowagnerite (TL)

Formula: Mg2(AsO4)F

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2018) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VIII. Arsenowagnerite, Mg2(AsO4)F. Mineralogical Magazine, 82 (4) 877-888 doi:10.1180/minmag.2017.081.067

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Arsenudinaite (TL)

Formula: NaMg4(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Arsmirandite (TL)

Formula: Na18Cu12Fe3+O8(AsO4)8Cl5

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO, 149. 1-17

Atacamite

Formula: Cu2(OH)3Cl

References:

Chukanov, N. V., Murashko, M. N., Zadov, A. E., & Bushmakin, A. F. (2007). Avdoninite, K 2 Cu 5 Cl 8 (OH) 4· H 2 O, a new mineral species from volcanic exhalations and the technogenic zone at volcanic-hosted massive sulfide deposits. Geology of Ore Deposits, 49(7), 505-508.

Atlasovite

Formula: K(BiO)Cu6Fe3+(SO4)5O3Cl

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Avdoninite (TL)

Formula: K2Cu5(OH)4Cl8 · H2O

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Averievite

Formula: Cu6(VO4)2O2Cl2

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Axelite (TL)

Formula: Na14Cu7(AsO4)8F2Cl2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Britvin, Sergey N., Sidorov, Evgeny G., Kutyrev, Anton V., Pushcharovsky, Dmitry Yu. (2023) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIX. Axelite, Na14Cu7(AsO4)8F2Cl2. Mineralogical Magazine, 87 (1) 109-117 doi:10.1180/mgm.2022.120

Badalovite (TL)

Formula: Na2Mg2Fe(AsO4)3

Type Locality:

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Pekov, Igor V., Koshlyakova, Natalia N., Agakhanov, Atali A., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIV. Badalovite, NaNaMg(MgFe3+)(AsO4)3, a member of the alluaudite group. Mineralogical Magazine, 84 (4) 616-622 doi:10.1180/mgm.2020.43

Bakakinite (TL)

Formula: Ca2V2O7

Type Locality:

Baryte

Formula: BaSO4

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Belloite

Formula: Cu(OH)Cl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Belomarinaite

Formula: KNa(SO4)

Belousovite (TL)

Formula: KZn(SO4)Cl

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Lukina, Evgeniya A., Zaitsev, Anatoly N., Shilovskikh, Vladimir V. (2018) Belousovite, KZn(SO4)Cl, a new sulfate mineral from the Tolbachik volcano with apophyllite sheet-topology. Mineralogical Magazine, 82 (5) 1079-1088 doi:10.1180/minmag.2017.081.084

Berzeliite

Formula: (NaCa2)Mg2(AsO4)3

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Bischofite

Formula: MgCl2 · 6H2O

Blödite

Formula: Na2Mg(SO4)2 · 4H2O

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Borisenkoite (TL)

Formula: Cu3[(V,As)O4]2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals, 47 (3) doi:10.1007/s00269-020-01081-y

Bradaczekite (TL)

Formula: NaCu4(AsO4)3

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Burnsite (TL)

Formula: KCdCu2+7(SeO3)2O2Cl9

Type Locality:

References:

Krivovichev, S. V., Vergasova, L. P., Starova, G. L., Filatov, S. K., Britvin, S. N., Roberts, A. C., Steele, I. M. (2002) Burnsite, KCdCu7O2(SeO3)2Cl9, a new mineral species from the Tolbachik Volcano, Kamchatka Peninsula, Russia. The Canadian Mineralogist, 40 (4) 1171-1175 doi:10.2113/gscanmin.40.4.1171

Calciohatertite (TL)

Formula: NaNaCa(CaFe3+)(AsO4)3

Type Locality:

Calciojohillerite (TL)

Formula: NaCaMg3(AsO4)3

Type Locality:

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Pekov, Igor V., Koshlyakova, Natalia N., Agakhanov, Atali A., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2021) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XV. Calciojohillerite, NaCaMgMg2(AsO4)3, a member of the alluaudite group. Mineralogical Magazine, 85 (2) 215-223 doi:10.1180/mgm.2021.2

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Calciolangbeinite (TL)

Formula: K2Ca2(SO4)3

Type Locality:

References:

Pekov, I. V., Zelenski, M. E., Zubkova, N. V., Yapaskurt, V. O., Chukanov, N. V., Belakovskiy, D. I., Pushcharovsky, D. Y. (2012) Calciolangbeinite, K2Ca2(SO4)3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 76 (3) 673-682 doi:10.1180/minmag.2012.076.3.16

Bulakh, M.O., Pekov, I.V., Koshlyakova, N.N., Britvin, S.N., Nazarova, M.A. (2022) [ Langbeinite-Group Minerals and Vanthoffite from Fumarolic Exhalations of the Tolbachik Volcano (Kamchatka)]. Записки Российского Минералогического Общества [Zapiski RMO (Proceedings of the Russian Mineralogical Society)], 151 (3) 96-122

Carnallite

Formula: KMgCl3 · 6H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Cassiterite

Formula: SnO2

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Cesiodymite (TL)

Formula: CsKCu5O(SO4)5

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Pushcharovsky, Dmitry Y., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N. (2018) Cryptochalcite, K2Cu5O(SO4)5, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series. European Journal of Mineralogy, 30 (3) 593-607 doi:10.1127/ejm/2018/0030-2725

Chalcanthite

Formula: CuSO4 · 5H2O

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Chalcocyanite

Formula: CuSO4

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chladniite

Formula: Na3CaMg11(PO4)9

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Chlorargyrite

Formula: AgCl

References:

Pekov, I. V., Agakhanov, A. A., Zubkova, N. V., Koshlyakova, N. N., Shchipalkina, N. V., Sandalov, F. D., ... & Sidorov, E. G. (2020). Oxidizing-type fumaroles of the Tolbachik Volcano, a mineralogical and geochemical unique. Russian Geology and Geophysics, 61(5-6), 675-688.

Chloromenite (TL)

Formula: Cu9(SeO3)4O2Cl6

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chlorothionite

Formula: K2Cu(SO4)Cl2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chromite

Formula: Fe2+Cr3+2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Chrysothallite (TL)

Formula: K6Cu6Tl3+Cl17(OH)4 · H2O

Localities:

Pyatno fumarole (Spot), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chubarovite (TL)

Formula: KZn2(BO3)Cl2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Pautov, Leonid A., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) Chubarovite, KZn2(BO3)Cl2, a new mineral species from the Tolbachik volcano, Kamchatka, Russia. The Canadian Mineralogist, 53 (2) 273-284 doi:10.3749/canmin.1400080

Clinoenstatite

Formula: MgSiO3

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Cohenite

Formula: Fe3C

Coparsite (TL)

Formula: Cu4(AsO4,VO4)O2Cl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Corundum

Formula: Al2O3

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Cotunnite

Formula: PbCl2

Cryptochalcite (TL)

Formula: K2Cu5O(SO4)5

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Pushcharovsky, Dmitry Y., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N. (2018) Cryptochalcite, K2Cu5O(SO4)5, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series. European Journal of Mineralogy, 30 (3) 593-607 doi:10.1127/ejm/2018/0030-2725

Cuprodobrovolskyite (TL)

Formula: Na4Cu(SO4)3

Type Locality:

Cupromolybdite (TL)

Formula: Cu3O(MoO4)2

Type Locality:

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Cuprospinel

Formula: Cu2+Fe3+2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Cyanochroite

Formula: K2Cu(SO4)2 · 6H2O

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Diopside

Formula: CaMgSi2O6

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Dioskouriite (TL)

Formula: CaCu4Cl6(OH)4 · 4H2O

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Dmisokolovite (TL)

Formula: K3Cu5AlO2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IV. Shchurovskyite, K2CaCu6O2(AsO4)4 and dmisokolovite, K3Cu5AlO2(AsO4)4. Mineralogical Magazine, 79 (7) 1737-1753 doi:10.1180/minmag.2015.079.7.02

Dobrovolskyite (TL)

Formula: Na4Ca(SO4)3

Type Locality:

References:

Shablinskii, A.P., Filatov, S.K., Vergasova, L.P., Moskaleva, S.V., Avdontseva, E.Y., Bubnova, R.S. (2020): Dobrovolskyite, IMA 2019-106

Shablinskii, Andrey P., Filatov, Stanislav K., Krivovichev, Sergey V., Vergasova, Lidiya P., Moskaleva, Svetlana V., Avdontseva, Eugeniya Yu., Knyazev, Alexander V., Bubnova, Rimma S. (2021) Dobrovolskyite, Na4Ca(SO4)3, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia. Mineralogical Magazine, 85 (2) 233-241 doi:10.1180/mgm.2021.9

Dokuchaevite (TL)

Formula: Cu8O2(VO4)3Cl3

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Zaitsev, Anatoly N., Polekhovsky, Yury S., Wenzel, Thomas, Spratt, John (2019) Dokuchaevite, Cu8O2(VO4)3Cl3, a new mineral with remarkably diverse Cu2+ mixed-ligand coordination environments. Mineralogical Magazine, 83 (5) 749-755 doi:10.1180/mgm.2019.41

Dolerophanite

Formula: Cu2(SO4)O

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Dravertite (TL)

Formula: CuMg(SO4)2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2017) Dravertite, CuMg(SO4)2, a new mineral species from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 29 (2) 323-330 doi:10.1127/ejm/2017/0029-2596

Eastonite

Formula: KMg2Al(Al2Si2O10)(OH)2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Edtollite (TL)

Formula: K2NaCu5Fe3+O2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Ksenofontov, Dmitry A., Pautov, Leonid A., Sidorov, Evgeny G., Britvin, Sergey N., Vigasina, Marina F., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineralogical Magazine, 83 (4) 485-495 doi:10.1180/mgm.2018.155

Elasmochloite (TL)

Formula: Na3Cu6BiO4(SO4)5

Type Locality:

References:

Pekov, Igor V., Britvin, Sergey N., Agakhanov, Atali A., Vigasina, Marina F., Sidorov, Evgeny G. (2019) Elasmochloite, Na3Cu6BiO4(SO4)5, a new fumarolic mineral from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 31 (5) 1025-1032 doi:10.1127/ejm/2019/0031-2887

Eleomelanite (TL)

Formula: (K2Pb)Cu4O2(SO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Britvin, Sergey N., Turchkova, Anna G., Pushcharovsky, Dmitry Yu. (2020) Eleomelanite, (K2Pb)Cu4O2(SO4)4, a new mineral species from the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 58 (5) 625-636 doi:10.3749/canmin.2000032

Enstatite

Formula: Mg2Si2O6

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Ericlaxmanite (TL)

Formula: Cu4O(AsO4)2

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03

Eriochalcite

Formula: CuCl2 · 2H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Esseneite

Formula: CaFe3+[AlSiO6]

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Euchlorine

Formula: KNaCu3(SO4)3O

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Evseevite (TL)

Formula: Na2Mg(AsO4)F

Type Locality:

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Belakovskiy, D.I., Vigasina, M.F., Yapaskurt, V.O., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky,

Fedotovite

Formula: K2Cu3(SO4)3O

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Feldspar Group'

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Feodosiyite (TL)

Formula: Cu11Mg2Cl18(OH)8 · 16H2O

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Lykova, Inna S., Vigasina, Marina F., Ksenofontov, Dmitry A., Britvin, Sergey N., Sidorov, Evgeny G., Khanin, Dmitry A., Pushcharovsky, Dmitry Yu. (2018) Feodosiyite, Cu11Mg2Cl18(OH)8·16H2O, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Neues Jahrbuch für Mineralogie - Abhandlungen Journal of Mineralogy and Geochemistry, 195 (1) 27-39 doi:10.1127/njma/2017/0081

Ferrisanidine (TL)

Formula: K[Fe3+Si3O8]

Type Locality:

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Filatovite (TL)

Formula: K(Al,Zn)2(As,Si)2O8

Type Locality:

References:

Vergasova, Lidiya P., Krivovichev, Sergey V., Britvin, Sergey N., Burns, Peter N., Ananiev, Vladimir V. (2004) Filatovite, K(Al,Zn)2(As,Si)2O8, a new mineral species from the Tolbachik volcano, Kamchatka peninsula, Russia. European Journal of Mineralogy, 16 (3) 533-536 doi:10.1127/0935-1221/2004/0016-0533

Flinteite

Formula: K2ZnCl4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Fluoborite

Formula: Mg3(BO3)(F,OH)3

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018

Zubkova, N. V., Pekov, I. V., Ksenofontov, D. A., Yapaskurt, V. O., Pushcharovsky, D. Y., & Sidorov, E. G. (2018, March). Arcanite from Fumarole Exhalations of the Tolbachik Volcano (Kamchatka, Russia) and Its Crystal Structure. In Doklady Earth Sciences (Vol. 479, pp. 339-341). Pleiades Publishing.

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Fluorapatite

Formula: Ca5(PO4)3F

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Fluorite

Formula: CaF2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Fluorophlogopite

Formula: KMg3(Si3Al)O10F2

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Forsterite

Formula: Mg2SiO4

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Franklinite

Formula: Zn2+Fe3+2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Gahnite

Formula: ZnAl2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

'Garnet Group'

Formula: X3Z2(SiO4)3

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

'Garnet Supergroup'

Formula: X3 Z2(TO4)3

References:

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Georgbokiite

Formula: Cu5(SeO3)2O2Cl2

Glauberite

Formula: Na2Ca(SO4)2

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Glikinite (TL)

Formula: Zn3O(SO4)2

Type Locality:

References:

Miyawaki, Ritsuro, Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 47. European Journal of Mineralogy, 31 (1) 197-202 doi:10.1127/ejm/2019/0031-2839

Nazarchuk, Evgeny V., Siidra, Oleg I., Nekrasova, Diana O., Shilovskikh, Vladimir V., Borisov, Artem S., Avdontseva, Evgeniya Y. (2020) Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4 tetrahedra. Mineralogical Magazine, 84 (4) 563-567 doi:10.1180/mgm.2020.33

Gold

Formula: Au

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Grigorievite (TL)

Formula: Cu3Fe3+2Al2(VO4)6

Type Locality:

Gypsum

Formula: CaSO4 · 2H2O

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Halite

Formula: NaCl

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Hatertite

Formula: Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Lykova, I. S., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3+,Mg,Cu)4(AsO4)6. Mineralogical Magazine, 78 (4) 905-917 doi:10.1180/minmag.2014.078.4.10

Haüyne

Formula: Na3Ca(Si3Al3)O12(SO4)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Hematite

Formula: Fe2O3

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Hermannjahnite (TL)

Formula: CuZn(SO4)2

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Agakhanov, Atali A., Lukina, Evgeniya A., Zaitsev, Anatoly N., Turner, Rick, Filatov, Stanislav K., Pekov, Igor V., Karpov, Gennady A., Yapaskurt, Vasiliy O. (2018) Hermannjahnite, CuZn(SO4)2, a new mineral with chalcocyanite derivative structure from the Naboko scoria cone of the 2012–2013 fissure eruption at Tolbachik volcano, Kamchatka, Russia. Mineralogy and Petrology, 112 (1) 123-134 doi:10.1007/s00710-017-0520-4

Hydrokenoralstonite

Formula: Na0.5(Al,Mg)2(F,OH)6 · H2O

'Hydrophilite'

Ilinskite (TL)

Formula: (Na,K)Cu5(SeO3)2O2Cl3

Type Locality:

Indialite

Formula: Mg2Al3(AlSi5O18)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Iron

Formula: Fe

Johillerite

Formula: Na(Mg,Zn)3Cu(AsO4)3

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kainite

Formula: KMg(SO4)Cl · 3H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Kainotropite (TL)

Formula: Cu4Fe3+O2(V2O7)(VO4)

Type Locality:

Description: It forms prismatic crystals up to 0.2 × 0.2 × 0.5 mm3, isolated or combined in clusters up to 0.7 mm across.

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) Kainotropite, Cu4Fe3+O2(V2O7)(VO4), a new mineral with a complex vanadate anion from fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. The Canadian Mineralogist, 58 (2) 155-165 doi:10.3749/canmin.1900073

Kaliochalcite (TL)

Formula: KCu2(SO4)2[(OH)(H2O)]

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kalsilite

Formula: KAlSiO4

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Kamchatkite (TL)

Formula: KCu3(SO4)2OCl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kantorite (TL)

Formula: K2NaMg(SO4)2F

Type Locality:

References:

Pekov, I. V., Britvin, S. N., Bulakh, M. O., Belakovskiy, D. I., Yapaskurt, V. O., Turchkova, A. G., and Anikin, L. P.: Kantorite, IMA 2024-042, in: CNMNC Newsletter 81, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-917-2024, 2024.

Karlditmarite (TL)

Formula: Cu9O4(PO4)2(SO4)2

Type Locality:

Katiarsite (TL)

Formula: KTiO(AsO4)

Type Locality:

References:

Pekov, Igor V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Zubkova, Natalia V., Vigasina, Marina F., Sidorov, Evgeny G. (2016) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. V. Katiarsite, KTiO(AsO4) Mineralogical Magazine, 80 (4) 639-646 doi:10.1180/minmag.2016.080.007

Khrenovite (TL)

Formula: Na3Fe3+2(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVIII. Khrenovite, Na3Fe3+2(AsO4)3, the member with the highest sodium in the alluaudite supergroup. Mineralogical Magazine, 86 (6) 897-902 doi:10.1180/mgm.2022.64

Klyuchevskite

Formula: K3Cu3(Fe3+,Al)(SO4)4O2

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Kononovite (TL)

Formula: NaMg(SO4)F

Type Locality:

References:

Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G. (2015) Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 27 (4) 575-580 doi:10.1127/ejm/2015/0027-2457

Koryakite (TL)

Formula: NaKMg2Al2(SO4)6

Type Locality:

Kozyrevskite (TL)

Formula: Cu4O(AsO4)2

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03

Krasheninnikovite (TL)

Formula: KNa2CaMg(SO4)3F

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Lammerite

Formula: Cu3(AsO4)2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Langbeinite

Formula: K2Mg2(SO4)3

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Lebedevite (TL)

Formula: K4Na14Cu14O8(AsO4)8Cl6

Type Locality:

References:

Koshlyakova, N.N., Pekov, I.V., Agakhanov, A.A., Bullock, E., Zubkova, N.V., Vigasina, M.F., Britvin, S.N., Burns, P.C., Hazen, R.M. and Zhitova, E.S. (2024) Lebedevite, IMA 2023-089. CNMNC Newsletter 77; Mineralogical Magazine, 88, https://doi.org/10.1180/mgm.2024.5

Lehmannite (TL)

Formula: Na18Cu12TiO8(AsO4)8FCl5

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO: 149: 1-17.

Leningradite (TL)

Formula: PbCu3(VO4)2Cl

Type Locality:

References:

Vergasova, L.P., Filatov, S.K., Semenova, T.F., Anan'yev, V.V. (1990) Leningradite PbCu3(VO4)2Cl2, a new mineral from volcanic exhalations. Doklady Akademii Nauk SSSR, 310, 1434-1437.

Leucite

Formula: K(AlSi2O6)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Litidionite

Formula: CuNaKSi4O10

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Löweite

Formula: Na12Mg7(SO4)13 · 15H2O

Description: XRD and Wet Chemical by Joy Desor, Gerhard Möhn

Ludwigite

Formula: Mg2Fe3+(BO3)O2

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Lyonsite

Formula: Cu3Fe4(VO4)6

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Colour: dark brown

Magganasite (TL)

Formula: CuFe3+3O(AsO4)3

Type Locality:

Magnesiochromite

Formula: MgCr2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Magnesioferrite

Formula: MgFe3+2O4

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Magnesiohatertite (TL)

Formula: (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3

Type Locality:

Magnetite

Formula: Fe2+Fe3+2O4

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Majzlanite (TL)

Formula: K2Na(ZnNa)Ca(SO4)4

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Zaitsev, Anatoly N., Shilovskikh, Vladimir V. (2020) Majzlanite, K2Na(ZnNa)Ca(SO4)4, a new anhydrous sulfate mineral with complex cation substitutions from Tolbachik volcano. Mineralogical Magazine, 84 (1) 153-158 doi:10.1180/mgm.2019.68

Manganobadalovite (TL)

Formula: NaNaMn(MgFe3+)(AsO4)3

Type Locality:

Manganohatertite (TL)

Formula: NaNaCa(MnFe3+)(AsO4)3

Type Locality:

References:

Koshlyakova, N.N., Pekov, I.V., Agakhanov, A.A., Bullock, E., Belakovskiy, D.I., Zubkova, N.V., Chukanov, N.V., Britvin, S.N., Bulakh, M.O., Burns, P.C., Hazen, R.M. and Zhitova, E.S. (2024) Manganohatertite, IMA 2023-098. CNMNC Newsletter 77; Mineralogical Magazine, 88, https://doi.org/10.1180/mgm.2024.5

Masaitisite (TL)

Formula: KCu5O2(SeO3)2Cl3

Type Locality:

Mcbirneyite

Formula: Cu3(VO4)2

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Melanarsite (TL)

Formula: K3Cu7Fe3+O4(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Belakovskiy, Dmitry I., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2016) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VI. Melanarsite, K3Cu7Fe3+O4(AsO4)4. Mineralogical Magazine, 80 (5) 855-867 doi:10.1180/minmag.2016.080.027

Melanothallite

Formula: Cu2Cl2O

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Mellizinkalite (TL)

Formula: K3Zn2Cl7

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Meniaylovite (TL)

Formula: Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O

Type Locality:

Metathénardite (TL)

Formula: Na2SO4

Localities:

Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Milkovoite (TL)

Formula: Cu4O(PO4)(AsO4)

Type Locality:

Mitscherlichite

Formula: K2CuCl4 · 2H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Nabokoite (TL)

Formula: KCu7(SO4)5(Te4+O3)OCl

Type Locality:

Natroaphthitalite (TL)

Formula: KNa3(SO4)2

Type Locality:

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Chukanov, Nikita V., Belakovskiy, Dmitry I., Zubkova, Natalia V., Koshlyakova, Natalia N., Britvin, Sergey N., Sidorov, Evgeny G. (2020) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik volcano, Kamchatka, Russia. II. A new mineral, natroaphthitalite, and new data on belomarinaite. The Canadian Mineralogist, 58 (2). 167-181 doi:10.3749/canmin.1900076

Natromolybdite (TL)

Formula: Na2MoO4 · 2H2O

Type Locality:

Nepheline

Formula: Na3K(Al4Si4O16)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Nickenichite

Formula: Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Nicksobolevite (TL)

Formula: Cu7(SeO3)2O2Cl6

Type Locality:

References:

Vergasova, Lidiya P., Semenova, Tatiana F., Krivovichev, Sergey V., Filatov, Stanislav K., Zolotarev Jr, Andrey A., Ananiev, Vladimir V. (2014) Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia. European Journal of Mineralogy, 26 (3) 439-449 doi:10.1127/0935-1221/2014/0026-2383

Nishanbaevite (TL)

Formula: KAl2O(AsO4)(SO4)

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Britvin, Sergey N., Agakhanov, Atali A., Turchkova, Anna G., Sidorov, Evgeny G., Kutyrev, Anton V., Blatov, Vladislav A., Pushcharovsky, Dmitry Y. (2023) Nishanbaevite, KAl2O(AsO4)(SO4), a new As/S-ordered arsenate-sulfate mineral of fumarolic origin. Mineralogy and Petrology, 117 (2) 247-257 doi:10.1007/s00710-022-00803-0

'Oborite'

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Orthoclase

Formula: K(AlSi3O8)

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Orthoclase var. Arsenic-bearing Orthoclase

Formula: KAl(Si,As)3O8

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Ozerovaite (TL)

Formula: Na2KAl3(AsO4)4

Type Locality:

Palmierite

Formula: K2Pb(SO4)2

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Pansnerite (TL)

Formula: K3Na3(Fe3+,Al)6(AsO4)8

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Koshlyakova, Natalia N., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2020) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIII. Pansnerite, K3Na3Fe3+6(AsO4)8. Mineralogical Magazine, 84 (1) 143-151 doi:10.1180/mgm.2019.48

Paraberzeliite (TL)

Formula: NaCa2Mg2(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVII. Paraberzeliite, NaCaCaMg2(AsO4)3, an alluaudite-group member dimorphous with berzeliite. Mineralogical Magazine, 86 (1) 103-111 doi:10.1180/mgm.2021.82

Parageorgbokiite (TL)

Formula: Cu5(SeO3)2O2Cl2

Type Locality:

Paralammerite

Formula: Cu3(AsO4)2

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Paratacamite

Formula: Cu3(Cu,Zn)(OH)6Cl2

References:

Chukanov, N. V., Murashko, M. N., Zadov, A. E., & Bushmakin, A. F. (2007). Avdoninite, K 2 Cu 5 Cl 8 (OH) 4· H 2 O, a new mineral species from volcanic exhalations and the technogenic zone at volcanic-hosted massive sulfide deposits. Geology of Ore Deposits, 49(7), 505-508.

Parawulffite (TL)

Formula: K5Na3Cu8O4(SO4)8

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Paulgrothite (TL)

Formula: Cu9Fe3+O4(PO4)4Cl3

Type Locality:

Petrovite (TL)

Formula: Na12Cu2(SO4)8

Type Locality:

Pharmazincite (TL)

Formula: KZnAsO4

Type Locality:

References:

Pekov, Igor V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Sidorov, Evgeny G. (2017) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VII. Pharmazincite, KZnAsO4. Mineralogical Magazine, 81 (4) 1001-1008 doi:10.1180/minmag.2016.080.146

Philoxenite (TL)

Formula: (K,Na,Pb)4(Na,Ca)2(Mg,Cu)3(Fe3+0.5Al0.5)(SO4)8

Type Locality:

References:

Pekov, I.V., Agakhanov, A.A., Zubkova, N.V., Belakovskiy, D.I., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G. (2020) Philoxenite, (K,Na,Pb)4(Na,Ca)2(Mg,Cu)3( Al0.5)(SO4)8, a new mineral from fumarole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Notes of the Russian Mineralogical Society: 149(4): 67-77.

Pilipenkoite (TL)

Formula: KCu(AsO4) · H2O

Type Locality:

Piypite

Formula: K4Cu4O2(SO4)4 · (Na,Cu)Cl

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Pliniusite

Formula: Ca5(VO4)3F

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Polyarsite (TL)

Formula: Na7CaMgCu2(AsO4)4F2Cl

Type Locality:

Ponomarevite

Formula: K4Cu4Cl10O

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Popovite (TL)

Formula: Cu5O2(AsO4)2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. III. Popovite, Cu5O2(AsO4)2. Mineralogical Magazine, 79 (1) 133-143 doi:10.1180/minmag.2015.079.1.11

Potassic-fluoro-richterite

Formula: {K}{CaNa}{Mg5}(Si8O22)(F,OH)2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Potassic-magnesio-fluoro-arfvedsonite

Formula: [(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Powellite

Formula: Ca(MoO4)

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Pseudobrookite

Formula: Fe2TiO5

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Pseudolyonsite

Formula: Cu3(VO4)2

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Puninite (TL)

Formula: Na2Cu3O(SO4)3

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgenii V., Zaitsev, Anatoly N., Lukina, Evgeniya A., Avdontseva, Evgeniya Y., Vergasova, Lidiya P, Vlasenko, Natalia S., Filatov, Stanislav K., Turner, Rick, Karpov, Gennady A. (2017) Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na2Cu3O(SO4)3 – a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite. European Journal of Mineralogy, 29 (3) 499-510 doi:10.1127/ejm/2017/0029-2619

Quartz

Formula: SiO2

Reznitskyite (TL)

Formula: CaMg(VO4)F

Type Locality:

References:

Koshlyakova, Natalia N., Pekov, Igor V., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) Reznitskyite, CaMg(VO4)F, a new mineral from the Tolbachik volcano, Kamchatka, Russia and the first vanadate with a titanite-type structure. Mineralogical Magazine, 86 (2) 307-313 doi:10.1180/mgm.2022.16

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Rhabdoborite-(Mo) (TL)

Formula: Mg12Mo6+1.33O6(BO3)6F2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Agakhanov, Atali A., Vigasina, Marina F., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) Rhabdoborite-(V), rhabdoborite-(Mo) and rhabdoborite-(W): a new group of borate minerals with the general formula Mg12M1 1/3[(BO3)6–x(PO4)xF2–x] (M = V5+, Mo6+ or W6+ and x < 1) Physics and Chemistry of Minerals, 47 (10) doi:10.1007/s00269-020-01105-7

Rhabdoborite-(V) (TL)

Formula: Mg12(V5+,Mo6+,W6+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1)

Type Locality:

Rhabdoborite-(W) (TL)

Formula: Mg12(W6+,V5+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x}

Type Locality:

Romanorlovite (TL)

Formula: K8Cu6Cl17(OH)3

Type Locality:

References:

Pekov, I.V., Yapaskurt, V.O., Britvin, S.N., Vigasina, M.F., Lykova, I.S., Zubkova, N.V., Krivovichev, S.V., Sidorov, E.G. (2017) Romanorlovite, a New Copper and Potassium Hydroxychloride from the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits: 59(7): 601–608.

Rutile

Formula: TiO2

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Rutile var. Iron- and Antimony-bearing Rutile

Formula: (Ti,Fe,Sb)O2

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018

Ryabchikovite (TL)

Formula: CuMgSi2O6

Type Locality:

References:

Shchipalkina, Nadezhda V., Vereshchagin, Oleg S., Pekov, Igor V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Shilovskikh, Vladimir V., Pankin, Dmitriy V., Britvin, Sergey N., Sandalov, Fedor D., Sidorov, Evgeny G. (2023) Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates. American Mineralogist, 108 (7) 1399-1408 doi:10.2138/am-2022-8620

Sanguite (TL)

Formula: KCuCl3

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Lykova, Inna S., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) Sanguite, KCuCl3, A New Mineral From the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 53 (4) 633-641 doi:10.3749/canmin.1500012

Sanidine

Formula: K(AlSi3O8)

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Schäferite

Formula: (NaCa2)Mg2(VO4)3

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Scheelite

Formula: Ca(WO4)

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Sellaite

Formula: MgF2

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Shcherbinaite

Formula: V5+2O5

Shchurovskyite (TL)

Formula: K2CaCu6O2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IV. Shchurovskyite, K2CaCu6O2(AsO4)4 and dmisokolovite, K3Cu5AlO2(AsO4)4. Mineralogical Magazine, 79 (7) 1737-1753 doi:10.1180/minmag.2015.079.7.02

Shuvalovite (TL)

Formula: K2(Ca2Na)(SO4)3F

Type Locality:

References:

Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), CNMNC Newsletter No. 22. Mineralogical Magazine, 78 (5) 1241-1248 doi:10.1180/minmag.2014.078.5.10

Silver

Formula: Ag

Sodalite

Formula: Na4(Si3Al3)O12Cl

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Sofiite

Formula: Zn2(SeO3)Cl2

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Spinel

Formula: MgAl2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Starovaite (TL)

Formula: KCu5O(VO4)3

Type Locality:

References:

Pekov, Igor V., Zelenski, Michael E., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Murashko, M Ikhailn. (2013) Starovaite, KCu5O(VO4)3, a new mineral from fumarole sublimates of the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 25 (1) 91-96 doi:10.1127/0935-1221/2013/0025-2258

Steklite (TL)

Formula: KAl(SO4)2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Svabite

Formula: Ca5(AsO4)3F

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Sylvite

Formula: KCl

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Tenorite

Formula: CuO

Localities: Reported from at least 6 localities in this region.

Thénardite

Formula: Na2SO4

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Thermaerogenite (TL)

Formula: CuAl2O4

Type Locality:

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia. Minerals, 8: 498.

Tilasite

Formula: CaMg(AsO4)F

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Lykova, I. S., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3+,Mg,Cu)4(AsO4)6. Mineralogical Magazine, 78 (4) 905-917 doi:10.1180/minmag.2014.078.4.10

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Titanite

Formula: CaTi(SiO4)O

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Tolbachite

Formula: CuCl2

Tridymite

Formula: SiO2

Tripuhyite

Formula: Fe3+Sb5+O4

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals, 47 (3) doi:10.1007/s00269-020-01081-y

Udinaite (TL)

Formula: NaMg4(VO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Uklonskovite

Formula: NaMg(SO4)F · 2H2O

References:

Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G. (2015) Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 27 (4) 575-580 doi:10.1127/ejm/2015/0027-2457

'Unnamed (Lyonsite-like Cu-Fe-Vanadate)'

Formula: (Cu,Zn)2(Fe,Al)2[(V,Mo,S,As)O4]3

Urusovite (TL)

Formula: CuAl(AsO4)O

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vanthoffite

Formula: Na6Mg(SO4)4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vasilseverginite (TL)

Formula: Cu9O4(AsO4)2(SO4)2

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Krivovichev, S.V., Vigasina, M.F. and Sidorov, E.G. (2021) Vasilseverginite, Cu9O4(AsO4)2(SO4)2, a new fumarolic mineral with a hybrid structure containing novel anion-centered tetrahedral structural units. American Mineralogist: 106: 633-640.

Vergasovaite (TL)

Formula: Cu3(SO4)(MoO4,SO4)O

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vladkuzminite (TL)

Formula: K4CuZn3(AsO4)4

Type Locality:

References:

Koshlyakova, N. N., Pekov, I. V., Agakhanov, A. A., Burns, P. C., Zubkova, N. V., Vigasina, M. F., Britvin, S. N., Hazen, R. M., and Zhitova, E. S.: Vladkuzminite, IMA 2023-106, in: CNMNC Newsletter 78, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-361-2024, 2024.

Vlodavetsite (TL)

Formula: AlCa2(SO4)2F2Cl · 4H2O

Type Locality:

Wagnerite

Formula: Mg2(PO4)F

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Wollastonite

Formula: Ca3(Si3O9)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Wrightite (TL)

Formula: K2Al2O(AsO4)2

Type Locality:

References:

Shablinskii, Andrey P., Filatov, Stanislav K., Vergasova, Lidyua P., Avdontseva, Eugeniya Yu., Moskaleva, Svetlana V. (2018) Wrightite, K2Al2O(AsO4)2, a new oxo-orthoarsenate from the Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik volcano, Kamchatka peninsula, Russia. Mineralogical Magazine, 82 (6) 1243-1251 doi:10.1180/minmag.2017.081.091

Wulffite (TL)

Formula: K3NaCu4O2(SO4)4

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Yangzhumingite

Formula: KMg2.5(Si4O10)F2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Yaroshevskite (TL)

Formula: Cu9O2(VO4)4Cl2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Yuanfuliite

Formula: Mg(Fe3+,Al)O(BO3)

References:

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Yurgensonite (TL)

Formula: K2SnTiO2(AsO4)2

Type Locality:

Yurmarinite (TL)

Formula: Na7(Fe3+,Mg,Cu)4(AsO4)6

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Lykova, I. S., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3+,Mg,Cu)4(AsO4)6. Mineralogical Magazine, 78 (4) 905-917 doi:10.1180/minmag.2014.078.4.10

Zincite

Formula: ZnO

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Zincobradaczekite (TL)

Formula: NaZn2Cu2(AsO4)3

Type Locality:

References:

Pekov, I.V., Lykova, I., Koshlyakova, N.N., Belakovskiy, D.I., Vigasina, M.F., Turchkova, A.G., Britvin, S.N., Sidorov, E.G., Scheidl, K.S. (2020) A new mineral species zincobradaczekite, NaCuCuZn2(AsO4)3, and a new isomorphous series bradaczekite–zincobradaczekite in the alluaudite group. Physics and Chemistry of Minerals, 47, 36.

Zincochromite

Formula: ZnCr2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Zircarsite (TL)

Formula: Na18Cu12ZrO8(AsO4)8Cl6

Type Locality:

References:

Koshlyakova, N. N., Pekov, I. V., Agakhanov, A. A., Burns, P. C., Bullock, E., Yapaskurt, V. O., Zubkova, N. V., Britvin, S. N., Hazen, R. M., and Zhitova, E. S.: Zircarsite, IMA 2024-037, in: CNMNC Newsletter 81, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-917-2024, 2024.

Zubkovaite (TL)

Formula: Ca3Cu3(AsO4)4

Type Locality:

References:

Pekov, Igor V., Lykova, Inna S., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Scheidl, Katharina S. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XII. Zubkovaite, Ca3Cu3(AsO4)4. Mineralogical Magazine, 83 (6) 879-886 doi:10.1180/mgm.2019.33