Edwardsite (original) (raw)

A valid IMA mineral species

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About EdwardsiteHide

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Formula:

Cu3Cd2(SO4)2(OH)6 · 4H2O

Specific Gravity:

3.53 (Calculated)

Crystal System:

Monoclinic

Name:

Named in 2010 by P. Elliott, J. Brugger, and T. Caradoc-Davies in honor of Dr. Austin Burton Edwards (15 August 1909, Caulfield, Victoria, Australia - 8 October 1960, Rome, Italy), mineralogist and petrologist from 1934-1960 at CSIRO, for his contribution to the earth sciences, in particular, studies of the geology, geochemistry and mineralogy of Australian ore deposits. He published 18 papers on Broken Hill geology and mineralogy.

One of the rare secondary Cd minerals.

May be confused with Cd-bearing varieties of christelite.

Unique IdentifiersHide

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Long-form identifier:

mindat:1:1:39682:4

6807c540-69f4-4660-a5fa-c5270479e19e

IMA Classification of EdwardsiteHide

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IMA Formula:

Cu3Cd2(SO4)2(OH)6 · 4H2O

Type description reference:

Elliott, P., Brugger, J., Caradoc-Davies, T. (2010) Description and crystal structure of a new mineral, edwardsite, Cu3Cd2(SO4)2(OH)6·4H2O, from Broken Hill, New South Wales, Australia. Mineralogical Magazine, 74 (1) 39-53 doi:10.1180/minmag.2010.074.1.39

Classification of EdwardsiteHide

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7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra

31.6.10.

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O

Mineral SymbolsHide

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As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol Source Reference
Edw IMA–CNMNC Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of EdwardsiteHide

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Comment:

Approximate value.

Cleavage:

Perfect
Excellent cleavage parallel to {100}.

Fracture:

Irregular/Uneven

Density:

3.53 g/cm3 (Calculated)

Optical Data of EdwardsiteHide

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RI values:

_n_α = 1.740 _n_β = 1.762(4) _n_γ = 1.770

δ = 0.030

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Optical Extinction:

X = b, Y ~ a, Z ~ c, with inclined extinction

Pleochroism:

Non-pleochroic

Comments:

Negative elongation (i.e. length-fast).

Refractive indices were obtained in white light using Cargille immersion liquids.

Chemistry of EdwardsiteHide

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Mindat Formula:

Cu3Cd2(SO4)2(OH)6 · 4H2O

Crystallography of EdwardsiteHide

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Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Cell Parameters:

a = 10.863(2) Å, b = 13.129(3) Å, c = 11.169(2) Å
β = 113.04(3)°

Ratio:

a:b:c = 0.827 : 1 : 0.851

Unit Cell V:

1,465.86 ų (Calculated from Unit Cell)

Morphology:

Flattened on {100} and often elongated along [010], with predominant crystal forms {100}, {001} and possibly {043}, with minor {010} plus other minor prisms and domes.

Crystal StructureHide

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ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0014597 Edwardsite Elliot P, Brugger J, Caradoc-Davies T (2010) Description and crystal structure of a new mineral, edwardsite, Cu3Cd2(SO4)2(OH)6*4H2O, from Broken Hill, New South Wales, Australia Mineralogical Magazine 74 39-53 2010 Block 14 Opencut, Broken Hill, Australia 0 293

CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Powder Diffraction Data:

d-spacing Intensity
9.991 Å (90)
5.001 Å (90)
4.591 Å (45)
3.332 Å (60)
2.824 Å (40)
2.769 Å (55)
2.670 Å (47)

Geological EnvironmentHide

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Type Occurrence of EdwardsiteHide

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General Appearance of Type Material:

Druses of tabular and bladed crystals up to 0.06 mm in size.

Place of Conservation of Type Material:

Holotype specimen is deposited in the South Australian Museum, Adelaide, South Australia, (registration number G32703).

Geological Setting of Type Material:

Ore stockpile from a Ag-Pb-Zn deposit.

Associated Minerals at Type Locality:

Reference:

Elliott, P., Brugger, J. Caradoc-Davies, T. (2010) Description and crystal structure of a new mineral, edwardsite, Cu3Cd2(SO4)2(OH)6•4H2O, from Broken Hill, New South Wales, Australia. Mineralogical Magazine: 74: 39–53.

Synonyms of EdwardsiteHide

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Common AssociatesHide

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Associated Minerals Based on Photo Data:

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7.DD. Asagiite NiCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.05 Felsőbányaite Al4(SO4)(OH)10 · 4H2O Mon. 2 : _P_21
7.DD.07 Llantenesite Cu6Al[SeO4](OH)12Cl · 3H2O Trig. 3_m_ : P_31_c
7.DD.10 Langite Cu4(SO4)(OH)6 · 2H2O Mon. m
7.DD.10 Posnjakite Cu4(SO4)(OH)6 · H2O Mon. m : P m
7.DD.10 Wroewolfeite Cu4(SO4)(OH)6 · 2H2O Mon. m : P m
7.DD.10 Gobelinite CoCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/m
7.DD.10 Fehrite MgCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.15 Spangolite Cu6Al(SO4)(OH)12Cl · 3H2O Trig. 3_m_ : P_31_c
7.DD.15 Kobyashevite Cu5(SO4)2(OH)6 · 4H2O Tric. 1 : _P_1
7.DD.15 Unnamed (Dimorph of Devilline) CaCu4(SO4)2(OH)6 · 3H2O Mon. 2/m : _P_21/b
7.DD.20 Ktenasite ZnCu4(SO4)2(OH)6 · 6H2O Mon. 2/m : _P_21/b
7.DD.25 Christelite Cu2Zn3(SO4)2(OH)6 · 4H2O Tric. 1 : _P_1
7.DD.30 Campigliaite Mn2+Cu4(SO4)2(OH)6 · 4H2O Mon. 2 : _B_2
7.DD.30 Devilline CaCu4(SO4)2(OH)6 · 3H2O Mon. 2/m : _P_21/b
7.DD.30 Orthoserpierite Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O Orth. m _m_2 : P c _a_21
7.DD.30 Serpierite Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O Mon. 2/m : _B_2/b
7.DD.30 Niedermayrite CdCu4(SO4)2(OH)6 · 4H2O Mon. 2/m : _P_21/m
7.DD.35 Carrboydite (Ni1-xAlx)(SO4)x/2(OH)2 · nH2O Hex.
7.DD.35 Glaucocerinite (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O Hex.
7.DD.35 Honessite (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O Trig.
7.DD.35 Hydrohonessite (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O Hex.
7.DD.35 Motukoreaite Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Mountkeithite [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O Hex.
7.DD.35 Shigaite Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Trig. 3 : _R_3
7.DD.35 Wermlandite Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O Trig. 3_m_ _(_32/m ) : _P_3_c_1
7.DD.35 Woodwardite Cu1-xAlx(OH)2(SO4)x/2 · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Zincaluminite (Zn1-xAlx)(SO4)x/2(OH)2 · nH2O
7.DD.35 Hydrowoodwardite (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O Trig. 3_m_ _(_32/m ) : R_3_m
7.DD.35 Zincowoodwardite Zn1-xAlx(OH)2[SO4]x/2 · nH2O Trig.
7.DD.35 Natroglaucocerinite Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Hex.
7.DD.35 Nikischerite Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O Trig. 3 : _R_3
7.DD.40 Isselite Cu6(SO4)(OH)10(H2O)4 · H2O Orth. m _m_2 : P m _n_21
7.DD.40 Lawsonbauerite (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O Mon. 2/m : _P_21/b
7.DD.40 Torreyite (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O Mon. 2/m : _P_21/b
7.DD.45 Mooreite Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O Mon. 2/m : _P_2/b
7.DD.45 Hodgesmithite (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O Trig. 3 : _P_3
7.DD.47 Lahnsteinite Zn4(SO4)(OH)6 · 3H2O Tric. 1 : _P_1
7.DD.50 Namuwite Zn4(SO4)(OH)6 · 4H2O Trig. 3 : _P_3
7.DD.50 Minohlite (Cu,Zn)7(SO4)2(OH)10 · 8H2O Hex.
7.DD.52 Lauraniite Cu6Cd2(SO4)2(OH)12 · 5H2O Mon. 2/m : _P_21/b
7.DD.55 Bechererite Zn7Cu(OH)13[(SiO(OH)3(SO4)] Trig. 3 : _P_3
7.DD.60 Ramsbeckite (Cu,Zn)15(SO4)4(OH)22 · 6H2O Mon. 2/m
7.DD.65 Vonbezingite Ca6Cu3(SO4)3(OH)12 · 2H2O Mon. 2/m : _P_21/b
7.DD.70 Redgillite Cu6(SO4)(OH)10 · H2O Mon. 2/m : _P_21/b
7.DD.75 Chalcoalumite CuAl4(SO4)(OH)12 · 3H2O Mon. 2 : _P_21
7.DD.75 Nickelalumite NiAl4(SO4)(OH)12(H2O)3 Mon. 2/m
7.DD.75 Kyrgyzstanite ZnAl4(SO4)(OH)12 · 3H2O Mon. 2/m
7.DD.80 Guarinoite Zn6(SO4)(OH)10 · 5H2O Hex.
7.DD.80 Schulenbergite (Cu,Zn)7(SO4)2(OH)10 · 3H2O Trig. 3
7.DD.80 Thérèsemagnanite NaCo4(SO4)(OH)6Cl · 6H2O Trig. 3 : _P_3
7.DD.80 UM1992-30-SO:CCuHZn (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O Trig. 3 : _P_3
7.DD.85 Montetrisaite Cu6(SO4)(OH)10 · 2H2O Orth. m _m_2 : C m _c_21

Fluorescence of EdwardsiteHide

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Other InformationHide

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Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

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References for EdwardsiteHide

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Reference List:

Elliott, P., Brugger, J., Caradoc-Davies, T. (2010) Description and crystal structure of a new mineral, edwardsite, Cu3Cd2(SO4)2(OH)6·4H2O, from Broken Hill, New South Wales, Australia. Mineralogical Magazine, 74 (1) 39-53 doi:10.1180/minmag.2010.074.1.39

Localities for EdwardsiteHide

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This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

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- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.

Australia (TL)
New South Wales Yancowinna Co. Broken Hill district Broken Hill Block 14 opencut (TL) Elliott et al. (2010)
Greece
Attica East Attica Lavreotiki Lavrion Mining District Agios Konstantinos (Kamariza) Kamariza Mines (Kamareza Mines) Hilarion Mine Rieck et al. (2018)
Km 3 Kaminiza mines Esperanza Mine Rieck et al. (2018) +1 other reference
Sounion Cato Sounio mines Sounion Mine No. 19 Rieck et al. (2018)
Namibia
Oshikoto Region Tsumeb Tsumeb Mine (Ongopolo Mine) Joy Desor specimen