Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia (original) (raw)

Acanthite

Formula: Ag2S

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Achyrophanite (TL)

Formula: (K,Na)3(Fe3+,Ti,Al,Mg)5O2(AsO4)5

Type Locality:

Aegirine

Formula: NaFe3+Si2O6

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Aegirine-augite

Formula: (NaaCabFe2+cMgd)(Fe3+eAlfFe2+gMgh)Si2O6

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Alarsite (TL)

Formula: AlAsO4

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Colour: colorless aggregates with yellowish, pale green, and bluish tints

Description: May occur as equant grains to 0.3 mm in diameter, some with poorly developed faces

Albite

Formula: Na(AlSi3O8)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Albite var. Anorthoclase

Formula: (Na,K)AlSi3O8

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Aleutite (TL)

Formula: [Cu5O2](AsO4)(VO4) · (Cu,K,Pb,Rb,Cs,)Cl

Type Locality:

Allochalcoselite (TL)

Formula: Cu+PbCu2+5(SeO3)2Cl5O2

Type Locality:

References:

Vergasova, L.P., Krivovichev, S.V., Britvin, S.N., Fitatov, S.K., Berns, P.K., Ananyev, V.V. (2005) Allochalcoselite, Cu+Cu2+5 PbO2(SeO3)2Cl5 - a new mineral from volcanic exhalations (Kamchatka, Russia). Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva, 134(3), 70-74 .

Ercit, T.S., Piilonen, P.C., Locock, A.J., Kolitsch, U., Rowe, R. (2006) New mineral names. American Mineralogist, 91, 1201-1209.

'α-Brass'

Formula: Cu3Zn

Aluminium

Formula: Al

Alumoåkermanite

Formula: (CaNa)Al[Si2O7]

Alumoedtollite (TL)

Formula: K2NaCu5AlO2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Ksenofontov, Dmitry A., Pautov, Leonid A., Sidorov, Evgeny G., Britvin, Sergey N., Vigasina, Marina F., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineralogical Magazine, 83 (4) 485-495 doi:10.1180/mgm.2018.155

Alumoklyuchevskite (TL)

Formula: K3Cu3(Al,Fe3+)(SO4)4O2

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: From thesecond cone of the Northern Breakthrough. Alumoklyuchevskite occurs as aggregates of dark green acicular crystals, elongate <010>, to 1 mm length and <0.1 mm width. Almost equant in cross-section, transparent,…Turns white on exposure to air, probably by hydration.

Anatolyite (TL)

Formula: Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6

Type Locality:

References:

Pekov, Igor V., Lykova, Inna S., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Scheidl, Katharina S. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XI. Anatolyite, Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6. Mineralogical Magazine, 83 (5) 633-638 doi:10.1180/mgm.2019.11

Andradite

Formula: Ca3Fe3+2(SiO4)3

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Anglesite

Formula: PbSO4

Localities: Reported from at least 11 localities in this region.

Anglesite var. Copper-bearing Anglesite

Formula: (Pb,Cu)SO4

Anhydrite

Formula: CaSO4

Localities: Reported from at least 8 localities in this region.

Anorthite

Formula: Ca(Al2Si2O8)

Localities:

Southern Breakthrough (South Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Anorthite var. Labradorite

Formula: (Ca,Na)[Al(Al,Si)Si2O8]

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Antipovite (TL)

Formula: Cu5O2(PO4)2

Type Locality:

Antlerite

Formula: Cu3(SO4)(OH)4

Antofagastaite

Formula: Na2Ca(SO4)2 · 1.5H2O

References:

Pekov, Igor V., Kovrugin, Vadim M., Siidra, Oleg I., Chukanov, Nikita V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Yapaskurt, Vasiliy O., Turchkova, Anna G., Möhn, Gerhard (2019) Antofagastaite, Na2Ca(SO4)2·1.5H2O, a new mineral related to syngenite. Mineralogical Magazine, 83 (6) 781-790 doi:10.1180/mgm.2019.17

'Apatite'

Formula: Ca5(PO4)3(Cl/F/OH)

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Aphthitalite

Formula: (K,Na)3Na(SO4)2

Localities: Reported from at least 6 localities in this region.

Aragonite

Formula: CaCO3

Arcanite

Formula: K2SO4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Arsenatrotitanite (TL)

Formula: NaTi(AsO4)O

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134

Arsenowagnerite (TL)

Formula: Mg2(AsO4)F

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2018) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VIII. Arsenowagnerite, Mg2(AsO4)F. Mineralogical Magazine, 82 (4) 877-888 doi:10.1180/minmag.2017.081.067

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Arsenudinaite (TL)

Formula: NaMg4(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Arsmirandite (TL)

Formula: Na18Cu12Fe3+O8(AsO4)8Cl5

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO, 149. 1-17

Atacamite

Formula: Cu2(OH)3Cl

Localities:

Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Atlasovite (TL)

Formula: K(BiO)Cu6Fe3+(SO4)5O3Cl

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: Atlasovite occurs as tabular crystals showing the forms {001}, {110}, {012}, and {014}; the crystals may consist predominately of atlasovite, or atlasovite may occur as zones within nabokoite.

Augite

Formula: (CaxMgyFez)(Mgy1Fez1)Si2O6

Avdoninite (TL)

Formula: K2Cu5(OH)4Cl8 · H2O

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Averievite (TL)

Formula: Cu6(VO4)2O2Cl2

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Axelite (TL)

Formula: Na14Cu7(AsO4)8F2Cl2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Britvin, Sergey N., Sidorov, Evgeny G., Kutyrev, Anton V., Pushcharovsky, Dmitry Yu. (2023) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIX. Axelite, Na14Cu7(AsO4)8F2Cl2. Mineralogical Magazine, 87 (1) 109-117 doi:10.1180/mgm.2022.120

Babingtonite

Formula: Ca2(Fe,Mn)FeSi5O14(OH)

Badalovite (TL)

Formula: Na2Mg2Fe(AsO4)3

Type Locality:

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Pekov, Igor V., Koshlyakova, Natalia N., Agakhanov, Atali A., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIV. Badalovite, NaNaMg(MgFe3+)(AsO4)3, a member of the alluaudite group. Mineralogical Magazine, 84 (4) 616-622 doi:10.1180/mgm.2020.43

Bakakinite (TL)

Formula: Ca2V2O7

Type Locality:

Bannermanite

Formula: (Na,K)0.7V4+0.7V5+5.3O15

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Baryte

Formula: BaSO4

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Bassanite

Formula: Ca(SO4) · 0.5H2O

Belloite

Formula: Cu(OH)Cl

Localities:

Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Belomarinaite (TL)

Formula: KNa(SO4)

Localities:

Toludskoe lava field, 2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Belousovite (TL)

Formula: KZn(SO4)Cl

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Lukina, Evgeniya A., Zaitsev, Anatoly N., Shilovskikh, Vladimir V. (2018) Belousovite, KZn(SO4)Cl, a new sulfate mineral from the Tolbachik volcano with apophyllite sheet-topology. Mineralogical Magazine, 82 (5) 1079-1088 doi:10.1180/minmag.2017.081.084

Berzeliite

Formula: (NaCa2)Mg2(AsO4)3

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Bischofite

Formula: MgCl2 · 6H2O

Blödite

Formula: Na2Mg(SO4)2 · 4H2O

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: XRD and Wet Chemical by Joy Desor, Gerhard Möhn

Blossite

Formula: α-Cu2(V2O7)

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Bobjonesite

Formula: (V4+O)(SO4) · 3H2O

References:

Siidra, Oleg I., Vergasova, Lidiya P., Kretser, Yuri L., Polekhovsky, Yuri S., Filatov, Stanislav K., Krivovichev, Sergey V. (2014) Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. III. Evdokimovite, Tl4(VO)3(SO4)5(H2O)5. Mineralogical Magazine, 78 (7) 1711-1724 doi:10.1180/minmag.2014.078.7.14

Bonattite

Formula: CuSO4 · 3H2O

Boothite

Formula: CuSO4 · 7H2O

Borisenkoite (TL)

Formula: Cu3[(V,As)O4]2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) A new mineral borisenkoite, Cu3[(V,As)O4]2, and the isomorphous series borisenkoite–lammerite-β in fumarolic exhalations of the Tolbachik volcano, Kamchatka, Russia. Physics and Chemistry of Minerals, 47 (3) doi:10.1007/s00269-020-01081-y

Bradaczekite (TL)

Formula: NaCu4(AsO4)3

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Brochantite

Formula: Cu4(SO4)(OH)6

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Krzątała, Arkadiusz, Belakovskiy, Dmitry I., Galuskina, Irina O., Galuskin, Evgeny V., Britvin, Sergey N., Sidorov, Evgeny G., Vapnik, Yevgeny, Pushcharovsky, Dmitry Yu (2022) Pliniusite, Ca5(VO4)3F, a new apatite-group mineral and the novel natural ternary solid-solution system pliniusite–svabite–fluorapatite. American Mineralogist, 107 (8) 1626-1634 doi:10.2138/am-2022-8100

Bubnovaite (TL)

Formula: K2Na8Ca(SO4)6

Localities:

Naboko cinder cone, Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Bunsenite

Formula: NiO

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Burnsite (TL)

Formula: KCdCu2+7(SeO3)2O2Cl9

Type Locality:

References:

Krivovichev, S. V., Vergasova, L. P., Starova, G. L., Filatov, S. K., Britvin, S. N., Roberts, A. C., Steele, I. M. (2002) Burnsite, KCdCu7O2(SeO3)2Cl9, a new mineral species from the Tolbachik Volcano, Kamchatka Peninsula, Russia. The Canadian Mineralogist, 40 (4) 1171-1175 doi:10.2113/gscanmin.40.4.1171

Cadmium

Formula: Cd

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Cadwaladerite

Formula: Al5(H2O)3(OH)12 · n(Cl,H2O)

Calciohatertite (TL)

Formula: NaNaCa(CaFe3+)(AsO4)3

Type Locality:

Calciojohillerite (TL)

Formula: NaCaMg3(AsO4)3

Type Locality:

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Pekov, Igor V., Koshlyakova, Natalia N., Agakhanov, Atali A., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2021) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XV. Calciojohillerite, NaCaMgMg2(AsO4)3, a member of the alluaudite group. Mineralogical Magazine, 85 (2) 215-223 doi:10.1180/mgm.2021.2

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Calciolangbeinite (TL)

Formula: K2Ca2(SO4)3

Type Locality:

References:

Pekov, I. V., Zelenski, M. E., Zubkova, N. V., Yapaskurt, V. O., Chukanov, N. V., Belakovskiy, D. I., Pushcharovsky, D. Y. (2012) Calciolangbeinite, K2Ca2(SO4)3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 76 (3) 673-682 doi:10.1180/minmag.2012.076.3.16

Bulakh, M.O., Pekov, I.V., Koshlyakova, N.N., Britvin, S.N., Nazarova, M.A. (2022) [ Langbeinite-Group Minerals and Vanthoffite from Fumarolic Exhalations of the Tolbachik Volcano (Kamchatka)]. Записки Российского Минералогического Общества [Zapiski RMO (Proceedings of the Russian Mineralogical Society)], 151 (3) 96-122

Calcite

Formula: CaCO3

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Carmeltazite

Formula: ZrAl2Ti4O11

Carnallite

Formula: KMgCl3 · 6H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Cassiterite

Formula: SnO2

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Cesiodymite (TL)

Formula: CsKCu5O(SO4)5

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Pushcharovsky, Dmitry Y., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N. (2018) Cryptochalcite, K2Cu5O(SO4)5, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series. European Journal of Mineralogy, 30 (3) 593-607 doi:10.1127/ejm/2018/0030-2725

Chalcanthite

Formula: CuSO4 · 5H2O

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Chalcocyanite

Formula: CuSO4

Localities: Reported from at least 7 localities in this region.

Chalcopyrite

Formula: CuFeS2

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Challacolloite

Formula: KPb2Cl5

Localities:

Northern fumarole field, First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chladniite

Formula: Na3CaMg11(PO4)9

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Turchova, A.G., Zhitova, E.S., Pushcharovskii, D.Yu. (2023): New Chladniite Variety from Volcanic Exhalations. The Genetic Crystal Chemistry of Chladniite. Doklady Earth Sciences, 512, 975-988.

Chlorargyrite

Formula: AgCl

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chlorartinite (TL)

Formula: Mg2(CO3)(OH)Cl · 2H2O

Type Locality:

Chloromenite (TL)

Formula: Cu9(SeO3)4O2Cl6

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chlorothionite

Formula: K2Cu(SO4)Cl2

Localities:

Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Chlor-spodiosite'

Formula: Ca2PO4Cl

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Chromite

Formula: Fe2+Cr3+2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Chromviskontite (TL)

Formula: Pb5Cu2(CrO4)3(SeO3)(OH)6

Type Locality:

References:

Pekov, I. V., Britvin, S. N., Agakhanov, A. A., Yapaskurt, V. O., Strel'nikov, M. V., Turchkova, A. G., and Kupchinenko, A. N.: Chromviskontite, IMA 2024-019, in: CNMNC Newsletter 80, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-599-2024, 2024.

Chrysocolla

Formula: Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O, x < 1

Chrysothallite (TL)

Formula: K6Cu6Tl3+Cl17(OH)4 · H2O

Localities:

Pyatno fumarole (Spot), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Chubarovite (TL)

Formula: KZn2(BO3)Cl2

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Northern fumarole field, First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Clinoenstatite

Formula: MgSiO3

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

'Clinopyroxene Subgroup'

Cohenite

Formula: Fe3C

Coparsite (TL)

Formula: Cu4(AsO4,VO4)O2Cl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Copper

Formula: Cu

References:

Gordeev, E. I., Karpov, G. A., Anikin, L. P., Krivovichev, S. V., Filatov, S. K., Antonov, A. V., & Ovsyannikov, A. A. (2014, January). Diamonds in lavas of the Tolbachik fissure eruption in Kamchatka. In Doklady Earth Sciences (Vol. 454, No. 1, pp. 47-49). Pleiades Publishing.

Cordierite

Formula: (Mg,Fe)2Al3(AlSi5O18)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 1: Neso-, cyclo-, ino- and phyllosilicates. European Journal of Mineralogy, 32 (1) 101-119 doi:10.5194/ejm-32-101-2020

Corundum

Formula: Al2O3

Localities:

Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Cotunnite

Formula: PbCl2

Localities: Reported from at least 6 localities in this region.

Cristobalite

Formula: SiO2

Cryobostryxite (TL)

Formula: KZnCl3 · 2H2O

Type Locality:

References:

Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), CNMNC Newsletter No. 22. Mineralogical Magazine, 78 (5) 1241-1248 doi:10.1180/minmag.2014.078.5.10

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Cryptochalcite (TL)

Formula: K2Cu5O(SO4)5

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Pushcharovsky, Dmitry Y., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N. (2018) Cryptochalcite, K2Cu5O(SO4)5, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series. European Journal of Mineralogy, 30 (3) 593-607 doi:10.1127/ejm/2018/0030-2725

Cubanite

Formula: CuFe2S3

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Cuprodobrovolskyite (TL)

Formula: Na4Cu(SO4)3

Type Locality:

Cupromolybdite (TL)

Formula: Cu3O(MoO4)2

Type Locality:

References:

Zelenski, Michael E., Zubkova, Natalia V., Pekov, Igor V., Polekhovsky, Yuri S., Pushcharovsky, Dmitry Y.U. (2012) Cupromolybdite, Cu3O(MoO4)2, a new fumarolic mineral from the Tolbachik volcano, Kamchatka Peninsula, Russia. European Journal of Mineralogy, 24 (4) 749-757 doi:10.1127/0935-1221/2012/0024-2221

Cuprospinel

Formula: Cu2+Fe3+2O4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Cyanochroite

Formula: K2Cu(SO4)2 · 6H2O

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Deltalumite (TL)

Formula: (Al0.67◻0.33)Al2O4

Type Locality:

Demartinite

Formula: K2[SiF6]

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Diamond ?

Formula: C

Diaspore

Formula: AlO(OH)

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Digenite

Formula: Cu9S5

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Diopside

Formula: CaMgSi2O6

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Dioskouriite (TL)

Formula: CaCu4Cl6(OH)4 · 4H2O

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Dmisokolovite (TL)

Formula: K3Cu5AlO2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IV. Shchurovskyite, K2CaCu6O2(AsO4)4 and dmisokolovite, K3Cu5AlO2(AsO4)4. Mineralogical Magazine, 79 (7) 1737-1753 doi:10.1180/minmag.2015.079.7.02

Dobrovolskyite (TL)

Formula: Na4Ca(SO4)3

Type Locality:

References:

Shablinskii, A.P., Filatov, S.K., Vergasova, L.P., Moskaleva, S.V., Avdontseva, E.Y., Bubnova, R.S. (2020): Dobrovolskyite, IMA 2019-106

Shablinskii, Andrey P., Filatov, Stanislav K., Krivovichev, Sergey V., Vergasova, Lidiya P., Moskaleva, Svetlana V., Avdontseva, Eugeniya Yu., Knyazev, Alexander V., Bubnova, Rimma S. (2021) Dobrovolskyite, Na4Ca(SO4)3, a new fumarolic sulfate from the Great Tolbachik fissure eruption, Kamchatka Peninsula, Russia. Mineralogical Magazine, 85 (2) 233-241 doi:10.1180/mgm.2021.9

Dokuchaevite (TL)

Formula: Cu8O2(VO4)3Cl3

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Zaitsev, Anatoly N., Polekhovsky, Yury S., Wenzel, Thomas, Spratt, John (2019) Dokuchaevite, Cu8O2(VO4)3Cl3, a new mineral with remarkably diverse Cu2+ mixed-ligand coordination environments. Mineralogical Magazine, 83 (5) 749-755 doi:10.1180/mgm.2019.41

Dolerophanite

Formula: Cu2(SO4)O

Localities: Reported from at least 6 localities in this region.

Dravertite (TL)

Formula: CuMg(SO4)2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2017) Dravertite, CuMg(SO4)2, a new mineral species from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 29 (2) 323-330 doi:10.1127/ejm/2017/0029-2596

Dypingite

Formula: Mg5(CO3)4(OH)2 · 5H2O

Eastonite

Formula: KMg2Al(Al2Si2O10)(OH)2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Edtollite (TL)

Formula: K2NaCu5Fe3+O2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Ksenofontov, Dmitry A., Pautov, Leonid A., Sidorov, Evgeny G., Britvin, Sergey N., Vigasina, Marina F., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)4. Mineralogical Magazine, 83 (4) 485-495 doi:10.1180/mgm.2018.155

Elasmochloite (TL)

Formula: Na3Cu6BiO4(SO4)5

Type Locality:

References:

Pekov, Igor V., Britvin, Sergey N., Agakhanov, Atali A., Vigasina, Marina F., Sidorov, Evgeny G. (2019) Elasmochloite, Na3Cu6BiO4(SO4)5, a new fumarolic mineral from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 31 (5) 1025-1032 doi:10.1127/ejm/2019/0031-2887

Eleomelanite (TL)

Formula: (K2Pb)Cu4O2(SO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Chukanov, Nikita V., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Britvin, Sergey N., Turchkova, Anna G., Pushcharovsky, Dmitry Yu. (2020) Eleomelanite, (K2Pb)Cu4O2(SO4)4, a new mineral species from the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 58 (5) 625-636 doi:10.3749/canmin.2000032

Enstatite

Formula: Mg2Si2O6

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Ericlaxmanite (TL)

Formula: Cu4O(AsO4)2

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03

Eriochalcite

Formula: CuCl2 · 2H2O

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Erythrosiderite

Formula: K2[Fe3+Cl5(H2O)]

Esseneite

Formula: CaFe3+[AlSiO6]

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Euchlorine

Formula: KNaCu3(SO4)3O

Localities: Reported from at least 9 localities in this region.

Eugsterite

Formula: Na4Ca(SO4)3 · 2H2O

References:

Shablinskii, Andrey P., Avdontceva, Margarita S., Vergasova, Lidiya P., Filatov, Stanislav K., Avdontseva, Evgenia Yu., Povolotskiy, Alexey V., Moskaleva, Svetlana V., Kargopoltsev, Anatoly A., Britvin, Sergey N., Shorets, Olga U. (2022) Medvedevite, KMn2+V5+2O6Cl⋅2H2O, a new fumarolic mineral from the Tolbachik fissure eruption 2012–2013, Kamchatka Peninsula, Russia. Mineralogical Magazine, 86 (3) 478-485 doi:10.1180/mgm.2022.38

Evdokimovite (TL)

Formula: Tl4(VO)3(SO4)5(H2O)5

Type Locality:

References:

Siidra, Oleg I., Vergasova, Lidiya P., Kretser, Yuri L., Polekhovsky, Yuri S., Filatov, Stanislav K., Krivovichev, Sergey V. (2014) Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. III. Evdokimovite, Tl4(VO)3(SO4)5(H2O)5. Mineralogical Magazine, 78 (7) 1711-1724 doi:10.1180/minmag.2014.078.7.14

Evseevite (TL)

Formula: Na2Mg(AsO4)F

Type Locality:

References:

Pekov, I.V., Zubkova, N.V., Agakhanov, A.A., Belakovskiy, D.I., Vigasina, M.F., Yapaskurt, V.O., Britvin, S.N., Turchkova, A.G., Sidorov, E.G., Pushcharovsky,

Fairchildite

Formula: K2Ca(CO3)2

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

'Fayalite-Forsterite Series'

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Fedotovite (TL)

Formula: K2Cu3(SO4)3O

Localities: Reported from at least 6 localities in this region.

'Feldspar Group'

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Feodosiyite (TL)

Formula: Cu11Mg2Cl18(OH)8 · 16H2O

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Lykova, Inna S., Vigasina, Marina F., Ksenofontov, Dmitry A., Britvin, Sergey N., Sidorov, Evgeny G., Khanin, Dmitry A., Pushcharovsky, Dmitry Yu. (2018) Feodosiyite, Cu11Mg2Cl18(OH)8·16H2O, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Neues Jahrbuch für Mineralogie - Abhandlungen Journal of Mineralogy and Geochemistry, 195 (1) 27-39 doi:10.1127/njma/2017/0081

Ferberite

Formula: FeWO4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Ferrisanidine (TL)

Formula: K[Fe3+Si3O8]

Type Locality:

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Filatovite (TL)

Formula: K(Al,Zn)2(As,Si)2O8

Type Locality:

References:

Vergasova, Lidiya P., Krivovichev, Sergey V., Britvin, Sergey N., Burns, Peter N., Ananiev, Vladimir V. (2004) Filatovite, K(Al,Zn)2(As,Si)2O8, a new mineral species from the Tolbachik volcano, Kamchatka peninsula, Russia. European Journal of Mineralogy, 16 (3) 533-536 doi:10.1127/0935-1221/2004/0016-0533

Fingerite

Formula: Cu11(VO4)6O2

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Flinteite (TL)

Formula: K2ZnCl4

Localities:

Northern fumarole field, First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Fluoborite

Formula: Mg3(BO3)(F,OH)3

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018

Zubkova, N. V., Pekov, I. V., Ksenofontov, D. A., Yapaskurt, V. O., Pushcharovsky, D. Y., & Sidorov, E. G. (2018, March). Arcanite from Fumarole Exhalations of the Tolbachik Volcano (Kamchatka, Russia) and Its Crystal Structure. In Doklady Earth Sciences (Vol. 479, pp. 339-341). Pleiades Publishing.

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Fluorapatite

Formula: Ca5(PO4)3F

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Fluorite

Formula: CaF2

Localities: Reported from at least 7 localities in this region.

Fluorophlogopite

Formula: KMg3(Si3Al)O10F2

Localities:

Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Fluor-uvite-Uvite Series'

Forsterite

Formula: Mg2SiO4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Franklinite

Formula: Zn2+Fe3+2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Gahnite

Formula: ZnAl2O4

Localities:

Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Galena

Formula: PbS

'Garnet Group'

Formula: X3Z2(SiO4)3

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

'Garnet Supergroup'

Formula: X3 Z2(TO4)3

References:

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Georgbokiite (TL)

Formula: Cu5(SeO3)2O2Cl2

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnoye fumarole, Southern Breakthrough (South Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Glass'

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Glauberite

Formula: Na2Ca(SO4)2

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Glikinite (TL)

Formula: Zn3O(SO4)2

Type Locality:

References:

Miyawaki, Ritsuro, Hålenius, Ulf, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2019) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) NEWSLETTER 47. European Journal of Mineralogy, 31 (1) 197-202 doi:10.1127/ejm/2019/0031-2839

Nazarchuk, Evgeny V., Siidra, Oleg I., Nekrasova, Diana O., Shilovskikh, Vladimir V., Borisov, Artem S., Avdontseva, Evgeniya Y. (2020) Glikinite, Zn3O(SO4)2, a new anhydrous zinc oxysulfate mineral structurally based on OZn4 tetrahedra. Mineralogical Magazine, 84 (4) 563-567 doi:10.1180/mgm.2020.33

Goethite

Formula: α-Fe3+O(OH)

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Gold

Formula: Au

Localities: Reported from at least 6 localities in this region.

Goryainovite

Formula: Ca2(PO4)Cl

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Graphite

Formula: C

Grigorievite (TL)

Formula: Cu3Fe3+2Al2(VO4)6

Type Locality:

Grossite

Formula: CaAl4O7

Grossular

Formula: Ca3Al2(SiO4)3

Gypsum

Formula: CaSO4 · 2H2O

Localities: Reported from at least 8 localities in this region.

Halite

Formula: NaCl

Localities: Reported from at least 8 localities in this region.

Hatertite (TL)

Formula: Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3

Localities:

Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Haüyne

Formula: Na3Ca(Si3Al3)O12(SO4)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Hematite

Formula: Fe2O3

Localities: Reported from at least 13 localities in this region.

Hematite var. Stannian Cuprian Antimonian Hematite

References:

Sandalov, F.D., Pekov, I.V., Koshlyakova, N.N., Latyshev, A.V., Zhegunov, P.S. (2023): Hematite from Fumaroles of the Tolbachik Volcano (Kamchatka, Russia): Chemistry, Relationship with Associated Minerals, Morphological and Genetic Features. Zapiski RMO, 152(4), 16-46.

Hematite var. Stannian Cuprian Hematite

References:

Sandalov, F.D., Pekov, I.V., Koshlyakova, N.N., Latyshev, A.V., Zhegunov, P.S. (2023): Hematite from Fumaroles of the Tolbachik Volcano (Kamchatka, Russia): Chemistry, Relationship with Associated Minerals, Morphological and Genetic Features. Zapiski RMO, 152(4), 16-46.

Hermannjahnite (TL)

Formula: CuZn(SO4)2

Localities:

Naboko cinder cone, Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Hibonite

Formula: CaAl12O19

Hollandite

Formula: Ba(Mn4+6Mn3+2)O16

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry . YU (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. II. Flinteite, K2ZnCl4. European Journal of Mineralogy, 27 (4) 581-588 doi:10.1127/ejm/2015/0027-2459

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Hydrokenoralstonite

Formula: Na0.5(Al,Mg)2(F,OH)6 · H2O

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Northern fumarole field, First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Hydromagnesite

Formula: Mg5(CO3)4(OH)2 · 4H2O

'Hydrophilite'

Ilinskite (TL)

Formula: (Na,K)Cu5(SeO3)2O2Cl3

Localities:

Glavnoye fumarole, Southern Breakthrough (South Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Ilmenite

Formula: Fe2+TiO3

Indialite

Formula: Mg2Al3(AlSi5O18)

Localities:

Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Iron

Formula: Fe

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Itelmenite (TL)

Formula: Na4Mg3Cu3(SO4)8

Localities:

Naboko cinder cone, Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Ivsite (TL)

Formula: Na3H(SO4)2

Jakobssonite

Formula: CaAlF5

References:

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Johillerite

Formula: Na(Mg,Zn)3Cu(AsO4)3

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kainite

Formula: KMg(SO4)Cl · 3H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Kainotropite (TL)

Formula: Cu4Fe3+O2(V2O7)(VO4)

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: It forms prismatic crystals up to 0.2 × 0.2 × 0.5 mm3, isolated or combined in clusters up to 0.7 mm across.

Kaliochalcite (TL)

Formula: KCu2(SO4)2[(OH)(H2O)]

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kalithallite (TL)

Formula: K3Tl3+Cl6 · 2H2O

Type Locality:

References:

Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Sidorov, Evgeny G., Zhegunov, Pavel S. (2023) Kalithallite, K3Tl3+Cl6⋅2H2O, a new mineral with trivalent thallium from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 87 (2) 186-193 doi:10.1180/mgm.2022.124

Kalsilite

Formula: KAlSiO4

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Kamchatkite (TL)

Formula: KCu3(SO4)2OCl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kantorite (TL)

Formula: K2NaMg(SO4)2F

Type Locality:

References:

Pekov, I. V., Britvin, S. N., Bulakh, M. O., Belakovskiy, D. I., Yapaskurt, V. O., Turchkova, A. G., and Anikin, L. P.: Kantorite, IMA 2024-042, in: CNMNC Newsletter 81, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-917-2024, 2024.

Karlditmarite (TL)

Formula: Cu9O4(PO4)2(SO4)2

Type Locality:

Karpovite (TL)

Formula: Tl2VO(SO4)2(H2O)

Type Locality:

References:

Siidra, Oleg I., Vergasova, Lidiya P., Kretser, Yuri L., Polekhovsky, Yuri S., Filatov, Stanislav K., Krivovichev, Sergey V. (2014) Unique thallium mineralization in the fumaroles of the Tolbachik volcano, Kamchatka Peninsula, Russia. II. Karpovite, Tl2VO(SO4)2(H2O) Mineralogical Magazine, 78 (7) 1699-1709 doi:10.1180/minmag.2014.078.7.13

Siidra, Oleg I., Vergasova, Lidiya P., Kretser, Yuri L., Polekhovsky, Yuri S., Filatov, Stanislav K., Krivovichev, Sergey V. (2014) Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. III. Evdokimovite, Tl4(VO)3(SO4)5(H2O)5. Mineralogical Magazine, 78 (7) 1711-1724 doi:10.1180/minmag.2014.078.7.14

Katiarsite (TL)

Formula: KTiO(AsO4)

Type Locality:

References:

Pekov, Igor V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Zubkova, Natalia V., Vigasina, Marina F., Sidorov, Evgeny G. (2016) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. V. Katiarsite, KTiO(AsO4) Mineralogical Magazine, 80 (4) 639-646 doi:10.1180/minmag.2016.080.007

'K Feldspar'

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Khrenovite (TL)

Formula: Na3Fe3+2(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVIII. Khrenovite, Na3Fe3+2(AsO4)3, the member with the highest sodium in the alluaudite supergroup. Mineralogical Magazine, 86 (6) 897-902 doi:10.1180/mgm.2022.64

Kieserite

Formula: MgSO4 · H2O

References:

Shablinskii, Andrey P., Avdontceva, Margarita S., Vergasova, Lidiya P., Filatov, Stanislav K., Avdontseva, Evgenia Yu., Povolotskiy, Alexey V., Moskaleva, Svetlana V., Kargopoltsev, Anatoly A., Britvin, Sergey N., Shorets, Olga U. (2022) Medvedevite, KMn2+V5+2O6Cl⋅2H2O, a new fumarolic mineral from the Tolbachik fissure eruption 2012–2013, Kamchatka Peninsula, Russia. Mineralogical Magazine, 86 (3) 478-485 doi:10.1180/mgm.2022.38

Klyuchevskite (TL)

Formula: K3Cu3(Fe3+,Al)(SO4)4O2

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Kononovite (TL)

Formula: NaMg(SO4)F

Type Locality:

References:

Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G. (2015) Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 27 (4) 575-580 doi:10.1127/ejm/2015/0027-2457

Koryakite (TL)

Formula: NaKMg2Al2(SO4)6

Type Locality:

Kozyrevskite (TL)

Formula: Cu4O(AsO4)2

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. II. Ericlaxmanite and kozyrevskite, two natural modifications of Cu4O(AsO4)2. Mineralogical Magazine, 78 (7) 1553-1569 doi:10.1180/minmag.2014.078.7.03

Krasheninnikovite (TL)

Formula: KNa2CaMg(SO4)3F

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Krasnogorite'

Formula: WO3

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Lammerite

Formula: Cu3(AsO4)2

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Langbeinite

Formula: K2Mg2(SO4)3

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Lead

Formula: Pb

Lebedevite (TL)

Formula: K4Na14Cu14O8(AsO4)8Cl6

Type Locality:

References:

Koshlyakova, N.N., Pekov, I.V., Agakhanov, A.A., Bullock, E., Zubkova, N.V., Vigasina, M.F., Britvin, S.N., Burns, P.C., Hazen, R.M. and Zhitova, E.S. (2024) Lebedevite, IMA 2023-089. CNMNC Newsletter 77; Mineralogical Magazine, 88, https://doi.org/10.1180/mgm.2024.5

Lehmannite (TL)

Formula: Na18Cu12TiO8(AsO4)8FCl5

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Koshlyakova, N.N., Polekhovsky, Yu.S., Göttlicher, J., Chukanov, N.V., Vigasina, M.F., Krivovichev, S.V., Turhkova, A.G., Sidorov, E.G. (2020) Arsmirandite, Na18Cu12Fe3+O8(AsO4)8Cl5, and lehmannite, Na18Cu12TiO8(AsO4)8FCl5, new minerals from fumerole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Zapiski RMO: 149: 1-17.

Leningradite (TL)

Formula: PbCu3(VO4)2Cl

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Leonardsenite

Formula: MgAlF5 · 2H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Leonite

Formula: K2Mg(SO4)2 · 4H2O

References:

Shablinskii, Andrey P., Avdontceva, Margarita S., Vergasova, Lidiya P., Filatov, Stanislav K., Avdontseva, Evgenia Yu., Povolotskiy, Alexey V., Moskaleva, Svetlana V., Kargopoltsev, Anatoly A., Britvin, Sergey N., Shorets, Olga U. (2022) Medvedevite, KMn2+V5+2O6Cl⋅2H2O, a new fumarolic mineral from the Tolbachik fissure eruption 2012–2013, Kamchatka Peninsula, Russia. Mineralogical Magazine, 86 (3) 478-485 doi:10.1180/mgm.2022.38

Leucite

Formula: K(AlSi2O6)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Linarite

Formula: PbCu(SO4)(OH)2

Litidionite

Formula: CuNaKSi4O10

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Löweite

Formula: Na12Mg7(SO4)13 · 15H2O

Description: XRD and Wet Chemical by Joy Desor, Gerhard Möhn

Ludwigite

Formula: Mg2Fe3+(BO3)O2

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Lyonsite

Formula: Cu3Fe4(VO4)6

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Lyonsite var. Cu-rich lyonsite

Formula: Cu3Fe4(VO4)6

References:

Pekov, I. V., Zubkova, N. V., Chernyshov, D. Yu., Zelenski, M. E., Yapaskurt, V. O., Pushcharovskii, D. Yu. (2013) A new Cu-rich variety of lyonsite from fumarolic sublimates of the Tolbachik volcano (Kamchatka, Russia) and its crystal structure. Doklady Earth Sciences, 448 (1) 112-116 doi:10.1134/s1028334x13010194

Mackinawite

Formula: FeS

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Magganasite (TL)

Formula: CuFe3+3O(AsO4)3

Type Locality:

Maghemite

Formula: (Fe3+0.67◻0.33)Fe3+2O4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Magnesiochromite

Formula: MgCr2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Magnesioferrite

Formula: MgFe3+2O4

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: Copper rich

Magnesiohatertite (TL)

Formula: (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3

Type Locality:

Magnetite

Formula: Fe2+Fe3+2O4

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Magnetite var. Titanium-bearing Magnetite

Formula: Fe2+(Fe3+,Ti)2O4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Majzlanite (TL)

Formula: K2Na(ZnNa)Ca(SO4)4

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgeny V., Zaitsev, Anatoly N., Shilovskikh, Vladimir V. (2020) Majzlanite, K2Na(ZnNa)Ca(SO4)4, a new anhydrous sulfate mineral with complex cation substitutions from Tolbachik volcano. Mineralogical Magazine, 84 (1) 153-158 doi:10.1180/mgm.2019.68

Malladrite

Formula: Na2[SiF6]

References:

Serafimova, E.K., Semenova, T.F., Vergasova, L.P., Filatov, S.K., Epifanova, V.B., Anan’yev, V.V. (1996) New data on malladrite Na2SiF6, a mineral of volcanic exhalations from the Large Tolbachik Fissure Eruption. Volcanol. Seismol.: 1: 46–55.

Mallardite

Formula: MnSO4 · 7H2O

Manganobadalovite (TL)

Formula: NaNaMn(MgFe3+)(AsO4)3

Type Locality:

Manganohatertite (TL)

Formula: NaNaCa(MnFe3+)(AsO4)3

Type Locality:

References:

Koshlyakova, N.N., Pekov, I.V., Agakhanov, A.A., Bullock, E., Belakovskiy, D.I., Zubkova, N.V., Chukanov, N.V., Britvin, S.N., Bulakh, M.O., Burns, P.C., Hazen, R.M. and Zhitova, E.S. (2024) Manganohatertite, IMA 2023-098. CNMNC Newsletter 77; Mineralogical Magazine, 88, https://doi.org/10.1180/mgm.2024.5

Marinaite (TL)

Formula: Cu2Fe3+O2(BO3)

Type Locality:

Markhininite (TL)

Formula: TlBi(SO4)2

Type Locality:

References:

Siidra, Oleg I., Vergasova, Lidiya P., Krivovichev, Sergey V., Kretser, Yuri L., Zaitsev, Anatoly N., Filatov, Stanislav K. (2014) Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. I. Markhininite, TlBi(SO4)2. Mineralogical Magazine, 78 (7) 1687-1698 doi:10.1180/minmag.2014.078.7.12

Siidra, Oleg I., Vergasova, Lidiya P., Kretser, Yuri L., Polekhovsky, Yuri S., Filatov, Stanislav K., Krivovichev, Sergey V. (2014) Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. III. Evdokimovite, Tl4(VO)3(SO4)5(H2O)5. Mineralogical Magazine, 78 (7) 1711-1724 doi:10.1180/minmag.2014.078.7.14

Masaitisite (TL)

Formula: KCu5O2(SeO3)2Cl3

Type Locality:

Mcbirneyite

Formula: Cu3(VO4)2

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Medvedevite (TL)

Formula: KMn2+2V2O6Cl · 2H2O

Type Locality:

References:

Shablinskii, Andrey P., Avdontceva, Margarita S., Vergasova, Lidiya P., Filatov, Stanislav K., Avdontseva, Evgenia Yu., Povolotskiy, Alexey V., Moskaleva, Svetlana V., Kargopoltsev, Anatoly A., Britvin, Sergey N., Shorets, Olga U. (2022) Medvedevite, KMn2+V5+2O6Cl⋅2H2O, a new fumarolic mineral from the Tolbachik fissure eruption 2012–2013, Kamchatka Peninsula, Russia. Mineralogical Magazine, 86 (3) 478-485 doi:10.1180/mgm.2022.38

Melanarsite (TL)

Formula: K3Cu7Fe3+O4(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Vigasina, Marina F., Belakovskiy, Dmitry I., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2016) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VI. Melanarsite, K3Cu7Fe3+O4(AsO4)4. Mineralogical Magazine, 80 (5) 855-867 doi:10.1180/minmag.2016.080.027

Melanothallite

Formula: Cu2Cl2O

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Melilite Group'

Formula: Ca2M(XSiO7)

Mellizinkalite (TL)

Formula: K3Zn2Cl7

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Meniaylovite (TL)

Formula: Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O

Localities:

Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Mercallite

Formula: KHSO4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Metathénardite (TL)

Formula: Na2SO4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Description: see image of associated belomarinaite

Milkovoite (TL)

Formula: Cu4O(PO4)(AsO4)

Type Locality:

Mitscherlichite

Formula: K2CuCl4 · 2H2O

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Lykova, Inna S., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Britvin, Sergey N., Yu. Pushcharovsky, Dmitry (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27 (2) 247-253 doi:10.1127/ejm/2015/0027-2430

Moissanite

Formula: SiC

Molybdite

Formula: MoO3

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Molybdomenite

Formula: PbSeO3

Monticellite

Formula: CaMgSiO4

Nabokoite (TL)

Formula: KCu7(SO4)5(Te4+O3)OCl

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Nataliyamalikite

Formula: TlI

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Natrite

Formula: Na2CO3

Natroaphthitalite (TL)

Formula: KNa3(SO4)2

Type Locality:

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Chukanov, Nikita V., Belakovskiy, Dmitry I., Zubkova, Natalia V., Koshlyakova, Natalia N., Britvin, Sergey N., Sidorov, Evgeny G. (2020) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik volcano, Kamchatka, Russia. II. A new mineral, natroaphthitalite, and new data on belomarinaite. The Canadian Mineralogist, 58 (2). 167-181 doi:10.3749/canmin.1900076

Natromolybdite (TL)

Formula: Na2MoO4 · 2H2O

Type Locality:

Nepheline

Formula: Na3K(Al4Si4O16)

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Nesquehonite

Formula: MgCO3 · 3H2O

Nickel

Formula: Ni

Nickenichite

Formula: Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3

References:

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Nicksobolevite (TL)

Formula: Cu7(SeO3)2O2Cl6

Type Locality:

References:

Vergasova, Lidiya P., Semenova, Tatiana F., Krivovichev, Sergey V., Filatov, Stanislav K., Zolotarev Jr, Andrey A., Ananiev, Vladimir V. (2014) Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia. European Journal of Mineralogy, 26 (3) 439-449 doi:10.1127/0935-1221/2014/0026-2383

Nishanbaevite (TL)

Formula: KAl2O(AsO4)(SO4)

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Britvin, Sergey N., Agakhanov, Atali A., Turchkova, Anna G., Sidorov, Evgeny G., Kutyrev, Anton V., Blatov, Vladislav A., Pushcharovsky, Dmitry Y. (2023) Nishanbaevite, KAl2O(AsO4)(SO4), a new As/S-ordered arsenate-sulfate mineral of fumarolic origin. Mineralogy and Petrology, 117 (2) 247-257 doi:10.1007/s00710-022-00803-0

Novograblenovite (TL)

Formula: (NH4)MgCl3 · 6H2O

Type Locality:

References:

Okrugin, V.M., Kudaeva, S.S., Karimova, O.V., Yakubovich, O.V., Belakovskiy, D.I., Chukanov, N.V., Zolotarev, A.A., Gurzhiy, V.V., Zinovieva, N.G., Shiryaev, A.A., Kartashov, P.M. (2019) The new mineral novograblenovite, (NH4,K)MgCl3·6H2O from the Tolbachik volcano, Kamchatka, Russia: mineral description and crystal structure. Mineralogical Magazine: 83(2): 223-231.

'Oborite'

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

'Olivine Group'

Formula: M2SiO4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Olsacherite

Formula: Pb2(Se6+O4)(SO4)

References:

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Opal

Formula: SiO2 · nH2O

References:

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Orthoclase

Formula: K(AlSi3O8)

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Orthoclase var. Arsenic-bearing Orthoclase

Formula: KAl(Si,As)3O8

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Orthopyroxene Subgroup'

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Ozerovaite (TL)

Formula: Na2KAl3(AsO4)4

Type Locality:

Palladium

Formula: (Pd,Pt)

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Palmierite

Formula: K2Pb(SO4)2

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Pansnerite (TL)

Formula: K3Na3(Fe3+,Al)6(AsO4)8

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Koshlyakova, Natalia N., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2020) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XIII. Pansnerite, K3Na3Fe3+6(AsO4)8. Mineralogical Magazine, 84 (1) 143-151 doi:10.1180/mgm.2019.48

Paraberzeliite (TL)

Formula: NaCa2Mg2(AsO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XVII. Paraberzeliite, NaCaCaMg2(AsO4)3, an alluaudite-group member dimorphous with berzeliite. Mineralogical Magazine, 86 (1) 103-111 doi:10.1180/mgm.2021.82

Parageorgbokiite (TL)

Formula: Cu5(SeO3)2O2Cl2

Type Locality:

Paralammerite (TL)

Formula: Cu3(AsO4)2

Localities:

Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Paramolybdomenite (TL)

Formula: PbSeO3

Type Locality:

Paratacamite

Formula: Cu3(Cu,Zn)(OH)6Cl2

References:

Chukanov, N. V., Murashko, M. N., Zadov, A. E., & Bushmakin, A. F. (2007). Avdoninite, K 2 Cu 5 Cl 8 (OH) 4· H 2 O, a new mineral species from volcanic exhalations and the technogenic zone at volcanic-hosted massive sulfide deposits. Geology of Ore Deposits, 49(7), 505-508.

Paratellurite

Formula: TeO2

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Parawulffite (TL)

Formula: K5Na3Cu8O4(SO4)8

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Parsettensite

Formula: (K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2O

Pauflerite (TL)

Formula: (V4+O)SO4

Localities:

Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Paulgrothite (TL)

Formula: Cu9Fe3+O4(PO4)4Cl3

Type Locality:

Pentlandite

Formula: (NixFey)Σ9S8

References:

Zelenski, M., Kamenetsky, V. S., Mavrogenes, J. A., Gurenko, A. A., & Danyushevsky, L. V. (2018). Silicate-sulfide liquid immiscibility in modern arc basalt (Tolbachik volcano, Kamchatka): Part I. Occurrence and compositions of sulfide melts. Chemical Geology, 478, 102-111.

Perovskite

Formula: CaTiO3

Petrovite (TL)

Formula: Na12Cu2(SO4)8

Type Locality:

Pharmazincite (TL)

Formula: KZnAsO4

Type Locality:

References:

Pekov, Igor V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Zubkova, Natalia V., Sidorov, Evgeny G. (2017) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. VII. Pharmazincite, KZnAsO4. Mineralogical Magazine, 81 (4) 1001-1008 doi:10.1180/minmag.2016.080.146

Philoxenite (TL)

Formula: (K,Na,Pb)4(Na,Ca)2(Mg,Cu)3(Fe3+0.5Al0.5)(SO4)8

Type Locality:

References:

Pekov, I.V., Agakhanov, A.A., Zubkova, N.V., Belakovskiy, D.I., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G. (2020) Philoxenite, (K,Na,Pb)4(Na,Ca)2(Mg,Cu)3( Al0.5)(SO4)8, a new mineral from fumarole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Notes of the Russian Mineralogical Society: 149(4): 67-77.

Pickeringite

Formula: MgAl2(SO4)4 · 22H2O

Pilipenkoite (TL)

Formula: KCu(AsO4) · H2O

Type Locality:

Piypite (TL)

Formula: K4Cu4O2(SO4)4 · (Na,Cu)Cl

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Plagioclase'

Formula: (Na,Ca)[(Si,Al)AlSi2]O8

Platinum

Formula: Pt

Pliniusite (TL)

Formula: Ca5(VO4)3F

Localities:

Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Polyarsite (TL)

Formula: Na7CaMgCu2(AsO4)4F2Cl

Type Locality:

Ponomarevite (TL)

Formula: K4Cu4Cl10O

Localities:

First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Popovite (TL)

Formula: Cu5O2(AsO4)2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. III. Popovite, Cu5O2(AsO4)2. Mineralogical Magazine, 79 (1) 133-143 doi:10.1180/minmag.2015.079.1.11

Potassic-fluoro-richterite

Formula: {K}{CaNa}{Mg5}(Si8O22)(F,OH)2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Potassic-magnesio-fluoro-arfvedsonite

Formula: [(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Powellite

Formula: Ca(MoO4)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Prewittite (TL)

Formula: KPb1.5ZnCu6(SeO3)2O2Cl10

Type Locality:

Habit: Separate tabular crystals up to 0.2 mm in maximum dimension.

Colour: Olive green

References:

Shuvalov, R.R., Vergasova, L.P., Semenova, T.F., Filatov, S.K., Krivovichev, S.V., Siidra, O.I., Rudashevsky, N.S. (2013): Prewittite, KPb1.5Cu6Zn(SeO3)2O2Cl10, a new mineral from Tolbachik fumaroles, Kamchatka peninsula, Russia: description and crystal structure. American Mineralogist, 98, 463–469.

Pseudobrookite

Formula: Fe2TiO5

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Pseudolyonsite (TL)

Formula: Cu3(VO4)2

Localities:

Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Puninite (TL)

Formula: Na2Cu3O(SO4)3

Type Locality:

References:

Siidra, Oleg I., Nazarchuk, Evgenii V., Zaitsev, Anatoly N., Lukina, Evgeniya A., Avdontseva, Evgeniya Y., Vergasova, Lidiya P, Vlasenko, Natalia S., Filatov, Stanislav K., Turner, Rick, Karpov, Gennady A. (2017) Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na2Cu3O(SO4)3 – a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite. European Journal of Mineralogy, 29 (3) 499-510 doi:10.1127/ejm/2017/0029-2619

Pyrite

Formula: FeS2

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Pyromorphite

Formula: Pb5(PO4)3Cl

'Pyroxene Group'

Formula: ADSi2O6

Quartz

Formula: SiO2

Qusongite

Formula: WC

Reznitskyite (TL)

Formula: CaMg(VO4)F

Type Locality:

References:

Koshlyakova, Natalia N., Pekov, Igor V., Vigasina, Marina F., Zubkova, Natalia V., Agakhanov, Atali A., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) Reznitskyite, CaMg(VO4)F, a new mineral from the Tolbachik volcano, Kamchatka, Russia and the first vanadate with a titanite-type structure. Mineralogical Magazine, 86 (2) 307-313 doi:10.1180/mgm.2022.16

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Rhabdoborite-(Mo) (TL)

Formula: Mg12Mo6+1.33O6(BO3)6F2

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Koshlyakova, Natalia N., Belakovskiy, Dmitry I., Agakhanov, Atali A., Vigasina, Marina F., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2020) Rhabdoborite-(V), rhabdoborite-(Mo) and rhabdoborite-(W): a new group of borate minerals with the general formula Mg12M1 1/3[(BO3)6–x(PO4)xF2–x] (M = V5+, Mo6+ or W6+ and x < 1) Physics and Chemistry of Minerals, 47 (10) doi:10.1007/s00269-020-01105-7

Rhabdoborite-(V) (TL)

Formula: Mg12(V5+,Mo6+,W6+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1)

Type Locality:

Rhabdoborite-(W) (TL)

Formula: Mg12(W6+,V5+)1.5O6{[BO3]6-x[(P,As)O4]xF2-x}

Type Locality:

Rheniite

Formula: ReS2

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Romanorlovite (TL)

Formula: K8Cu6Cl17(OH)3

Type Locality:

References:

Pekov, I.V., Yapaskurt, V.O., Britvin, S.N., Vigasina, M.F., Lykova, I.S., Zubkova, N.V., Krivovichev, S.V., Sidorov, E.G. (2017) Romanorlovite, a New Copper and Potassium Hydroxychloride from the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits: 59(7): 601–608.

Rutile

Formula: TiO2

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Rutile var. Iron- and Antimony-bearing Rutile

Formula: (Ti,Fe,Sb)O2

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018

Ryabchikovite (TL)

Formula: CuMgSi2O6

Type Locality:

References:

Shchipalkina, Nadezhda V., Vereshchagin, Oleg S., Pekov, Igor V., Belakovskiy, Dmitry I., Koshlyakova, Natalia N., Shilovskikh, Vladimir V., Pankin, Dmitriy V., Britvin, Sergey N., Sandalov, Fedor D., Sidorov, Evgeny G. (2023) Ryabchikovite, CuMg(Si2O6), a new pyroxene group mineral, and some genetic features of natural anhydrous copper silicates. American Mineralogist, 108 (7) 1399-1408 doi:10.2138/am-2022-8620

Saltonseaite

Formula: K3NaMnCl6

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry . YU (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. II. Flinteite, K2ZnCl4. European Journal of Mineralogy, 27 (4) 581-588 doi:10.1127/ejm/2015/0027-2459

Pekov, Igor V., Zubkova, Natalia V., Britvin, Sergey N., Yapaskurt, Vasiliy O., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. III. Cryobostryxite, KZnCl3·2H2O. European Journal of Mineralogy, 27 (6) 805-812 doi:10.1127/ejm/2015/0027-2482

Sanguite (TL)

Formula: KCuCl3

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Lykova, Inna S., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) Sanguite, KCuCl3, A New Mineral From the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 53 (4) 633-641 doi:10.3749/canmin.1500012

Sanidine

Formula: K(AlSi3O8)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Saranchinaite (TL)

Formula: Na2Cu(SO4)2

Localities:

Naboko cinder cone, Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Schäferite

Formula: (NaCa2)Mg2(VO4)3

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Scheelite

Formula: Ca(WO4)

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Selenium

Formula: Se

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Sellaite

Formula: MgF2

Localities: Reported from at least 7 localities in this region.

Shcherbinaite

Formula: V5+2O5

Localities:

Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Shchurovskyite (TL)

Formula: K2CaCu6O2(AsO4)4

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Belakovskiy, Dmitry I., Yapaskurt, Vasiliy O., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IV. Shchurovskyite, K2CaCu6O2(AsO4)4 and dmisokolovite, K3Cu5AlO2(AsO4)4. Mineralogical Magazine, 79 (7) 1737-1753 doi:10.1180/minmag.2015.079.7.02

Shuvalovite (TL)

Formula: K2(Ca2Na)(SO4)3F

Type Locality:

References:

Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC), CNMNC Newsletter No. 22. Mineralogical Magazine, 78 (5) 1241-1248 doi:10.1180/minmag.2014.078.5.10

Silicon

Formula: Si

Silver

Formula: Ag

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Sodalite

Formula: Na4(Si3Al3)O12Cl

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Sofiite (TL)

Formula: Zn2(SeO3)Cl2

Localities: Reported from at least 7 localities in this region.

Spinel

Formula: MgAl2O4

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Western paleo-fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Starovaite (TL)

Formula: KCu5O(VO4)3

Type Locality:

References:

Pekov, Igor V., Zelenski, Michael E., Yapaskurt, Vasiliy O., Polekhovsky, Yury S., Murashko, M Ikhailn. (2013) Starovaite, KCu5O(VO4)3, a new mineral from fumarole sublimates of the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 25 (1) 91-96 doi:10.1127/0935-1221/2013/0025-2258

Steklite (TL)

Formula: KAl(SO4)2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

'Sulfurite'

Formula: S

'Sulfurite var. Arsensulfurite'

Formula: (S,As)8

Sulphur

Formula: S8

Svabite

Formula: Ca5(AsO4)3F

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Southern fumarole field, Mountain 1004, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Sylvite

Formula: KCl

Localities: Reported from at least 6 localities in this region.

Syngenite

Formula: K2Ca(SO4)2 · H2O

Localities:

Toludskoe lava field, 2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Tantite

Formula: Ta2O5

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Tellurium

Formula: Te

Tenorite

Formula: CuO

Localities: Reported from at least 12 localities in this region.

Thénardite

Formula: Na2SO4

Localities: Reported from at least 6 localities in this region.

Thermaerogenite (TL)

Formula: CuAl2O4

Type Locality:

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia. Minerals, 8: 498.

Thermonatrite

Formula: Na2CO3 · H2O

Tilasite

Formula: CaMg(AsO4)F

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Lykova, I. S., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3+,Mg,Cu)4(AsO4)6. Mineralogical Magazine, 78 (4) 905-917 doi:10.1180/minmag.2014.078.4.10

Pekov, Igor V., Shchipalkina, Nadezhda V., Zubkova, Natalia V., Gurzhiy, Vladislav V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Vigasina, Marina F., Koshlyakova, Natalia N., Sidorov, Evgeny G., Giester, Gerald (2019) Alkali sulfates with aphthitalite-like structures from fumaroles of the Tolbachik Volcano, Kamchatka, Russia. I. Metathénardite, a natural high-temperature modification of Na2SO4. The Canadian Mineralogist, 57 (6) 885-901 doi:10.3749/canmin.1900050

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Bulakh, M. O., Pekov, I. V., Koshlyakova, N. N., Sidorov, E. G. (2022) Ludwigite and Yuanfuliite from Fumarolic Exhalations of the Tolbachik Volcano, Kamchatka, Russia. Geology of Ore Deposits, 64 (8) 607-621 doi:10.1134/s1075701522080037

Tin

Formula: Sn

References:

Gordeev, E. I., Karpov, G. A., Anikin, L. P., Krivovichev, S. V., Filatov, S. K., Antonov, A. V., & Ovsyannikov, A. A. (2014, January). Diamonds in lavas of the Tolbachik fissure eruption in Kamchatka. In Doklady Earth Sciences (Vol. 454, No. 1, pp. 47-49). Pleiades Publishing.

Tistarite

Formula: Ti3+2O3

Titanite

Formula: CaTi(SiO4)O

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Titanium

Formula: Ti

Tolbachite (TL)

Formula: CuCl2

Localities:

First scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Tremolite

Formula: ◻Ca2Mg5(Si8O22)(OH)2

Trevorite

Formula: Ni2+Fe3+2O4

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Tridymite

Formula: SiO2

Tripuhyite

Formula: Fe3+Sb5+O4

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Tungsten

Formula: W

Udinaite (TL)

Formula: NaMg4(VO4)3

Type Locality:

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Uklonskovite

Formula: NaMg(SO4)F · 2H2O

References:

Pekov, Igor V., Krzhizhanovskaya, Maria G., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G. (2015) Kononovite, NaMg(SO4)F, a new mineral from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 27 (4) 575-580 doi:10.1127/ejm/2015/0027-2457

Ulvöspinel

Formula: TiFe2+2O4

'UM1984-21-PO:AsCu'

Formula: Cu3(PO4,AsO4)2

References:

Filatov, S.K., Gaidamako, L.M., Glavatskikh, S.F., Starova, G.L., Sorokin, N.D. (1984): Exhalation lammerite Cu3[(As,P)O4]2,(Kamchatka). Doklady Akad. Nauk SSSR: 279: 197-200 (in Russian)

'UM1995-05-E:FeMn'

Formula: Fe6Mn

'Unnamed (Lyonsite-like Cu-Fe-Vanadate)'

Formula: (Cu,Zn)2(Fe,Al)2[(V,Mo,S,As)O4]3

Urusovite (TL)

Formula: CuAl(AsO4)O

Localities:

Novaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vanthoffite

Formula: Na6Mg(SO4)4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Glavnaya Tenoritovaya fumarole (Major Tenorite), Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vasilseverginite (TL)

Formula: Cu9O4(AsO4)2(SO4)2

Type Locality:

References:

Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Krivovichev, S.V., Vigasina, M.F. and Sidorov, E.G. (2021) Vasilseverginite, Cu9O4(AsO4)2(SO4)2, a new fumarolic mineral with a hybrid structure containing novel anion-centered tetrahedral structural units. American Mineralogist: 106: 633-640.

Vergasovaite (TL)

Formula: Cu3(SO4)(MoO4,SO4)O

Localities:

Treschina fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Vernadite

Formula: (Mn4+,Fe3+,Ca,Na)(O,OH)2 · nH2O

References:

Pekov, I. V., Agakhanov, A. A., Zubkova, N. V., Koshlyakova, N. N., Shchipalkina, N. V., Sandalov, F. D., ... & Sidorov, E. G. (2020). Oxidizing-type fumaroles of the Tolbachik Volcano, a mineralogical and geochemical unique. Russian Geology and Geophysics, 61(5-6), 675-688.

Viskontite (TL)

Formula: Pb5Cu2(SO4)3(SeO3)(OH)6

Type Locality:

Vladkuzminite (TL)

Formula: K4CuZn3(AsO4)4

Type Locality:

References:

Koshlyakova, N. N., Pekov, I. V., Agakhanov, A. A., Burns, P. C., Zubkova, N. V., Vigasina, M. F., Britvin, S. N., Hazen, R. M., and Zhitova, E. S.: Vladkuzminite, IMA 2023-106, in: CNMNC Newsletter 78, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-361-2024, 2024.

Vlodavetsite (TL)

Formula: AlCa2(SO4)2F2Cl · 4H2O

Volborthite

Formula: Cu3(V2O7)(OH)2 · 2H2O

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Krzątała, Arkadiusz, Belakovskiy, Dmitry I., Galuskina, Irina O., Galuskin, Evgeny V., Britvin, Sergey N., Sidorov, Evgeny G., Vapnik, Yevgeny, Pushcharovsky, Dmitry Yu (2022) Pliniusite, Ca5(VO4)3F, a new apatite-group mineral and the novel natural ternary solid-solution system pliniusite–svabite–fluorapatite. American Mineralogist, 107 (8) 1626-1634 doi:10.2138/am-2022-8100

Wagnerite

Formula: Mg2(PO4)F

References:

Pekov, Igor V., Koshlyakova, Natalia N., Zubkova, Natalia V., Belakovskiy, Dmitry I., Vigasina, Marina F., Agakhanov, Atali A., Ksenofontov, Dmitry A., Turchkova, Anna G., Britvin, Sergey N., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2022) A Natural Vanadate–Arsenate Isomorphous Series with Jeffbenite-Type Structure: New Fumarolic Minerals Udinaite, NaMg4(VO4)3, and Arsenudinaite, NaMg4(AsO4)3. Minerals, 12 (7) 850 doi:10.3390/min12070850

Wollastonite

Formula: Ca3(Si3O9)

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Wrightite (TL)

Formula: K2Al2O(AsO4)2

Type Locality:

References:

Shablinskii, Andrey P., Filatov, Stanislav K., Vergasova, Lidyua P., Avdontseva, Eugeniya Yu., Moskaleva, Svetlana V. (2018) Wrightite, K2Al2O(AsO4)2, a new oxo-orthoarsenate from the Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik volcano, Kamchatka peninsula, Russia. Mineralogical Magazine, 82 (6) 1243-1251 doi:10.1180/minmag.2017.081.091

Wulfenite

Formula: Pb(MoO4)

Wulffite (TL)

Formula: K3NaCu4O2(SO4)4

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Yangzhumingite

Formula: KMg2.5(Si4O10)F2

References:

Shchipalkina, Nadezhda V., Pekov, Igor V., Koshlyakova, Natalia N., Britvin, Sergey N., Zubkova, Natalia V., Varlamov, Dmitry A., Sidorov, Eugeny G. (2020) Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates. European Journal of Mineralogy, 32 (1) 121-136 doi:10.5194/ejm-32-121-2020

Yaroshevskite (TL)

Formula: Cu9O2(VO4)4Cl2

Localities:

Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Yuanfuliite

Formula: Mg(Fe3+,Al)O(BO3)

Localities:

Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Yurgensonite (TL)

Formula: K2SnTiO2(AsO4)2

Type Locality:

Yurmarinite (TL)

Formula: Na7(Fe3+,Mg,Cu)4(AsO4)6

Type Locality:

References:

Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Lykova, I. S., Vigasina, M. F., Sidorov, E. G., Pushcharovsky, D. Yu. (2014) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. I. Yurmarinite, Na7(Fe3+,Mg,Cu)4(AsO4)6. Mineralogical Magazine, 78 (4) 905-917 doi:10.1180/minmag.2014.078.4.10

Ziesite

Formula: β-Cu2(V2O7)

References:

Pekov, I. V., Zubkova, N. V., Zelenski, M. E., Yapaskurt, V. O., Polekhovsky, Yu. S., Fadeeva, O. A., Pushcharovsky, D. Yu. (2013) Yaroshevskite, Cu9O2(VO4)4Cl2, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 77 (1) 107-116 doi:10.1180/minmag.2013.077.1.10

Zinc

Formula: Zn

References:

Gordeev, E. I., Karpov, G. A., Anikin, L. P., Krivovichev, S. V., Filatov, S. K., Antonov, A. V., & Ovsyannikov, A. A. (2014, January). Diamonds in lavas of the Tolbachik fissure eruption in Kamchatka. In Doklady Earth Sciences (Vol. 454, No. 1, pp. 47-49). Pleiades Publishing.

Zincite

Formula: ZnO

Localities:

2012-2013 Fissure Tolbachik Eruption site, Plosky Tolbachik Volcano, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia
Yadovitaya fumarole, Second scoria cone, Northern Breakthrough (North Breach), Great Fissure eruption (Main Fracture), Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia

Zincobradaczekite (TL)

Formula: NaZn2Cu2(AsO4)3

Type Locality:

References:

Pekov, I.V., Lykova, I., Koshlyakova, N.N., Belakovskiy, D.I., Vigasina, M.F., Turchkova, A.G., Britvin, S.N., Sidorov, E.G., Scheidl, K.S. (2020) A new mineral species zincobradaczekite, NaCuCuZn2(AsO4)3, and a new isomorphous series bradaczekite–zincobradaczekite in the alluaudite group. Physics and Chemistry of Minerals, 47, 36.

Zincochromite

Formula: ZnCr2O4

References:

Pekov, I.V., Sandalov, F.D., Koshlyakova, N.N., Vigasina, M.F., Polekhovsky, Y.S., Britvin, S.N., Sidorov, E.G., Turchkova, A.G. (2018): Copper in Natural Oxide Spinels: The New Mineral Thermaerogenite CuAl2O4, Cuprospinel and Cu-Enriched Varieties of Other Spinel-Group Members from Fumaroles of the Tolbachik Volcano, Kamchatka, Russia[i]. Minerals: 8: 498

Zincomenite (TL)

Formula: ZnSeO3

Type Locality:

References:

Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Britvin, Sergey N., Chukanov, Nikita V., Lykova, Inna S., Sidorov, Evgeny G., Pushcharovsky, Dmitry Y. (2016) Zincomenite, ZnSeO3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. European Journal of Mineralogy, 28 (5) 997-1004 doi:10.1127/ejm/2016/0028-2564

Zircarsite (TL)

Formula: Na18Cu12ZrO8(AsO4)8Cl6

Type Locality:

References:

Koshlyakova, N. N., Pekov, I. V., Agakhanov, A. A., Burns, P. C., Bullock, E., Yapaskurt, V. O., Zubkova, N. V., Britvin, S. N., Hazen, R. M., and Zhitova, E. S.: Zircarsite, IMA 2024-037, in: CNMNC Newsletter 81, Eur. J. Mineral., 36, https://doi.org/10.5194/ejm-36-917-2024, 2024.

Zircon

Formula: Zr(SiO4)

References:

Zelenski, M., Kamenetsky, V. S., Taran, Y., & Kovalskii, A. M. (2020). Mineralogy and origin of aerosol from an arc basaltic eruption: Case study of Tolbachik volcano, Kamchatka. Geochemistry, Geophysics, Geosystems, 21(2), e2019GC008802.

Zubkovaite (TL)

Formula: Ca3Cu3(AsO4)4

Type Locality:

References:

Pekov, Igor V., Lykova, Inna S., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Britvin, Sergey N., Turchkova, Anna G., Sidorov, Evgeny G., Scheidl, Katharina S. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. XII. Zubkovaite, Ca3Cu3(AsO4)4. Mineralogical Magazine, 83 (6) 879-886 doi:10.1180/mgm.2019.33