Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany (original) (raw)

Acanthite

Formula: Ag2S

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Actinolite

Formula: ◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2

Adamite

Formula: Zn2(AsO4)(OH)

Adamite var. Copper-bearing Adamite

Formula: (Zn,Cu)2AsO4OH

Description: Possibly zincolivenite?

'Agardite'

Agardite-(Ce) (TL)

Formula: CeCu6(AsO4)3(OH)6 · 3H2O

Type Locality:

References:

Aksenov, Sergey M., Chukanov, Nikita V., Göttlicher, Jörg, Möckel, Steffen, Varlamov, Dmitriy, Van, Konstantin V., Rastsvetaeva, Ramiza K. (2018) New insights into the crystal chemistry of agardite-(Ce): refinement of the crystal structure, hydrogen bonding, and epitaxial intergrowths with the Sb-analogue of auriacusite. Physics and Chemistry of Minerals, 45 (1) 39-50 doi:10.1007/s00269-017-0899-9

Agardite-(La)

Formula: LaCu6(AsO4)3(OH)6 · 3H2O

References:

Göb, S., Wenzel, T., Bau, M., Jacob, D. E., Loges, A., Markl, G. (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany. The Canadian Mineralogist, 49 (5) 1305-1333 doi:10.3749/canmin.49.5.1305

Agardite-(Nd)

Formula: NdCu6(AsO4)3(OH)6 · 3H2O

References:

Göb, S., Wenzel, T., Bau, M., Jacob, D. E., Loges, A., Markl, G. (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany. The Canadian Mineralogist, 49 (5) 1305-1333 doi:10.3749/canmin.49.5.1305

Agardite-(Y)

Formula: YCu6(AsO4)3(OH)6 · 3H2O

Description: Never analytically confirmed; Dietrich et al. (1969), who had studied Clara agardites and "chlorotiles", only write that they are "relatively rich in Ce".

Akaganeite

Formula: (Fe3+,Ni2+)8(OH,O)16Cl1.25 · nH2O

Albite

Formula: Na(AlSi3O8)

Allargentum

Formula: (Ag1-xSbx)

Alloclasite

Formula: Co1-xFexAsS

Allophane

Formula: (Al2O3)(SiO2)1.3-2 · 2.5-3H2O

Almandine

Formula: Fe2+3Al2(SiO4)3

Alum-(K)

Formula: KAl(SO4)2 · 12H2O

Ammoniojarosite

Formula: (NH4)Fe3+3(SO4)2(OH)6

Anatase

Formula: TiO2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Anglesite

Formula: PbSO4

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Anhydrite

Formula: CaSO4

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Ankerite

Formula: Ca(Fe2+,Mg)(CO3)2

Description: Often confused with Fe-bearing dolomite. Analytically confirmed only by Kolitsch et al. (2019).

Annabergite

Formula: Ni3(AsO4)2 · 8H2O

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Antimony

Formula: Sb

Antlerite

Formula: Cu3(SO4)(OH)4

Aragonite

Formula: CaCO3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Arsenbrackebuschite (TL)

Formula: Pb2Fe3+(AsO4)2(OH)

Type Locality:

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Arsenic

Formula: As

Arseniosiderite

Formula: Ca2Fe3+3(AsO4)3O2 · 3H2O

Arsenocrandallite

Formula: CaAl3(AsO4)(AsO3OH)(OH)6

Arsenogorceixite (TL)

Formula: BaAl3(AsO4)(AsO3OH)(OH)6

Type Locality:

Habit: Crystalline crusts, tabular xls

Colour: Various shades

'Arsenogorceixite-Arsenogoyazite Series'

Arsenogoyazite (TL)

Formula: SrAl3(AsO4)(AsO3OH)(OH)6

Type Locality:

Arsenolite

Formula: As2O3

Arsenopyrite

Formula: FeAsS

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Arsentsumebite

Formula: Pb2Cu(AsO4)(SO4)(OH)

Description: SO4-free variety.

Arthurite

Formula: CuFe3+2(AsO4)2(OH)2 · 4H2O

Atacamite

Formula: Cu2(OH)3Cl

Atelestite

Formula: Bi2(AsO4)O(OH)

Auriacusite

Formula: Fe3+Cu2+(AsO4)O

Aurichalcite

Formula: (Zn,Cu)5(CO3)2(OH)6

Autunite ?

Formula: Ca(UO2)2(PO4)2 · 10-12H2O

Description: Never confirmed by X-ray diffraction methods (unlike meta-autunite).

Azurite

Formula: Cu3(CO3)2(OH)2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Babánekite

Formula: Cu3(AsO4)2 · 8H2O

Bararite

Formula: (NH4)2[SiF6]

Bariandite

Formula: Al0.6(V5+,V4+)8O20 · 9H2O

Bariopharmacosiderite (TL)

Formula: Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O

Type Locality:

Baryte

Formula: BaSO4

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Schwarzenbruch, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Baryte var. Meißelspat

Formula: BaSO4

Bassetite

Formula: Fe2+(UO2)2(PO4)2 · 10H2O

Bastnäsite-(Ce)

Formula: Ce(CO3)F

Bastnäsite-(La)

Formula: La(CO3)F

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Bastnäsite-(Nd)

Formula: Nd(CO3)F

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Bayldonite

Formula: PbCu3(AsO4)2(OH)2

Beaverite-(Cu)

Formula: Pb(Fe3+2Cu)(SO4)2(OH)6

Becquerelite

Formula: Ca(UO2)6O4(OH)6 · 8H2O

Benauite (TL)

Formula: SrFe3+3(PO4)(PO3OH)(OH)6

Type Locality:

Habit: Tabular

Colour: Yellowish, brown-orange

Benjaminite

Formula: Ag3Bi7S12

Beraunite

Formula: Fe3+6(PO4)4O(OH)4 · 6H2O

Bernalite

Formula: Fe(OH)3 · nH2O (n = 0.0 to 0.25)

Berryite

Formula: Cu3Ag2Pb3Bi7S16

Beudantite

Formula: PbFe3(AsO4)(SO4)(OH)6

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Beyerite

Formula: Ca(BiO)2(CO3)2

Billietite

Formula: Ba(UO2)6O4(OH)6 · 4-8H2O

Billingsleyite

Formula: Ag7AsS6

'Bindheimite'

Formula: Pb2Sb2O6O

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Biotite'

Formula: K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2

Birnessite

Formula: (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O

Bismuth

Formula: Bi

Bismuthinite

Formula: Bi2S3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Bismutite

Formula: (BiO)2CO3

Bismutoferrite

Formula: Fe3+2Bi(SiO4)2(OH)

Blatonite

Formula: (UO2)CO3 · H2O

Bohdanowiczite

Formula: AgBiSe2

Bornite

Formula: Cu5FeS4

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Botallackite

Formula: Cu2(OH)3Cl

Breithauptite

Formula: NiSb

Breithauptite var. Arite

Formula: Ni(Sb,As)

Brochantite

Formula: Cu4(SO4)(OH)6

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Bromargyrite

Formula: AgBr

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Brookite

Formula: TiO2

Brucite

Formula: Mg(OH)2

Cacoxenite

Formula: Fe3+24AlO6(PO4)17(OH)12 · 75H2O

Calcioandyrobertsite

Formula: KCaCu5(AsO4)4(H2AsO4) · 2H2O

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Calcite

Formula: CaCO3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Caledonite

Formula: Pb5Cu2(SO4)3(CO3)(OH)6

Camérolaite

Formula: Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4)

Carbonatecyanotrichite

Formula: Cu4Al2(CO3,SO4)(OH)12 · 2H2O

Carlhintzeite

Formula: Ca2[AlF6]F · H2O

Carminite

Formula: PbFe3+2(AsO4)2(OH)2

Carnotite

Formula: K2(UO2)2(VO4)2 · 3H2O

Cassiterite

Formula: SnO2

Cattierite

Formula: CoS2

Celadonite

Formula: K(MgFe3+◻)(Si4O10)(OH)2

Celestine

Formula: SrSO4

Cerianite-(Ce)

Formula: (Ce4+,Th)O2

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Cerussite

Formula: PbCO3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Cervantite

Formula: Sb3+Sb5+O4

Cesàrolite

Formula: PbMn4+3O6(OH)2

Chalcanthite

Formula: CuSO4 · 5H2O

Chalcocite

Formula: Cu2S

Chalcophyllite

Formula: Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O

Chalcopyrite

Formula: CuFeS2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Chalcosiderite

Formula: CuFe3+6(PO4)4(OH)8 · 4H2O

Chamosite

Formula: (Fe2+)5Al(Si,Al)4O10(OH,O)8

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Chenevixite

Formula: Cu2Fe3+2(AsO4)2(OH)4

Chlorargyrite

Formula: AgCl

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Chlorite Group'

Chromite

Formula: Fe2+Cr3+2O4

Chrysocolla

Formula: Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O, x < 1

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Chukhrovite-(Ce)

Formula: Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O

Cinnabar

Formula: HgS

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Clairite

Formula: (NH4)2Fe3(SO4)4(OH)3 · 3H2O

Claraite (TL)

Formula: (Cu,Zn)15(CO3)4(AsO4)2(SO4)(OH)14 · 7H2O

Type Locality:

Clausthalite

Formula: PbSe

Clinobisvanite

Formula: Bi(VO4)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Clinochlore

Formula: Mg5Al(AlSi3O10)(OH)8

Description: Reported as "pennine" by Kaiser (1984)

Clinoclase

Formula: Cu3(AsO4)(OH)3

Cobaltite

Formula: CoAsS

Cobaltkoritnigite

Formula: Co(AsO3OH) · H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Coffinite

Formula: U(SiO4) · nH2O

Conichalcite

Formula: CaCu(AsO4)(OH)

Connellite

Formula: Cu19(SO4)(OH)32Cl4 · 3H2O

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Copiapite

Formula: Fe2+Fe3+4(SO4)6(OH)2 · 20H2O

Copper

Formula: Cu

Coquimbite

Formula: AlFe3(SO4)6(H2O)12 · 6H2O

Cordierite

Formula: (Mg,Fe)2Al3(AlSi5O18)

Corkite

Formula: PbFe3(PO4)(SO4)(OH)6

Description: The mineral contains only traces of sulphate and, therefore, is possibly a new mineral (P-analogue of segnitite)

Cornubite

Formula: Cu5(AsO4)2(OH)4

Cornwallite

Formula: Cu5(AsO4)2(OH)4

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Coronadite

Formula: Pb(Mn4+6Mn3+2)O16

Cotunnite

Formula: PbCl2

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Covellite

Formula: CuS

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Crandallite

Formula: CaAl3(PO4)(PO3OH)(OH)6

Cryptohalite

Formula: (NH4)2[SiF6]

Cryptomelane

Formula: K(Mn4+7Mn3+)O16

Cualstibite (TL)

Formula: Cu2Al(OH)6[Sb5+(OH)6]

Type Locality:

'Cualstibite-1M' (FRL)

Formula: (Cu,Al)3(OH)6[Sb5+(OH)6]

Type Locality:

Habit: Tabular with triangular outline

Colour: Pale bluish

'Cualstibite-1T'

Formula: Cu2AlSb(OH)12

Cuprite

Formula: Cu2O

Cuprite var. Chalcotrichite

Formula: Cu2O

Cuprobismutite

Formula: Cu8AgBi13S24

Cupropavonite

Formula: Cu0.9Ag0.5Pb0.6Bi2.5S5

Cupropearceite

Formula: [Cu6As2S7][Ag9CuS4]

Cupropolybasite

Formula: [Cu6Sb2S7][Ag9CuS4]

'Cuproroméite'

Formula: Cu2Sb2(O,OH)7

Cuprotungstite

Formula: Cu2(WO4)(OH)2

Cyanotrichite

Formula: Cu4Al2(SO4)(OH)12 · 2H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Dantopaite

Formula: Ag5Bi13S22

Delafossite

Formula: CuFeO2

Descloizite

Formula: PbZn(VO4)(OH)

Devilline

Formula: CaCu4(SO4)2(OH)6 · 3H2O

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Diadochite

Formula: Fe3+2(PO4)(SO4)(OH) · 6H2O

Diaphorite

Formula: Ag3Pb2Sb3S8

Digenite

Formula: Cu9S5

Djurleite

Formula: Cu31S16

Dolomite

Formula: CaMg(CO3)2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Doyleite

Formula: Al(OH)3

Dravite

Formula: NaMg3Al6(Si6O18)(BO3)3(OH)3(OH)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Dreyerite

Formula: Bi(VO4)

Description: small straw yellow crystals in the sub mm size range is accompanied by limonite, baryte and quartz in vugs in dark purple fluorite (stinkspath)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Dufrénite

Formula: Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O

Duftite

Formula: PbCu(AsO4)(OH)

References:

Callegari, A.M., Boiocchi, M., Zema, M. Tarantino, S.C. (2017): Crystal structure refinement of duftite, PbCu(AsO4)(OH), from Grube Clara, Oberwolfach, Schwarzwald, Germany. Neues Jahrbuch für Mineralogie - Abhandlungen: Journal of Mineralogy and Geochemistry 194, 157-164.

Dussertite

Formula: BaFe3+3(AsO4)(AsO3OH)(OH)6

Dyscrasite (TL)

Formula: Ag3Sb

Type Locality:

'Elsmoreite Group' ?

Description: 11/8/2016: Stuart Mills; original analysis by EDS + PXRD does not fully quantify the Pb content of the elsmoreite group mineral, therefore it is not certain that it corresponds to jixianite (itself of questionable status) or to Pb-rich hydroxykenoelsmoreite or hydrokenoelsmoreite or another new elsmoreite group mineral.

Elyite

Formula: Pb4Cu(SO4)O2(OH)4 · H2O

Description: Part of the elyite originated due to the use of concrete in underground workings. Other samples clearly show a natural origin.

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Emplectite

Formula: CuBiS2

Enargite

Formula: Cu3AsS4

Erythrite

Formula: Co3(AsO4)2 · 8H2O

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Ettringite

Formula: Ca6Al2(SO4)3(OH)12 · 26H2O

Description: The ettringite found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed phase.

Eulytine

Formula: Bi4(SiO4)3

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Famatinite

Formula: Cu3SbS4

Ferberite

Formula: FeWO4

Feroxyhyte

Formula: Fe3+O(OH)

Ferrihydrite

Formula: Fe3+10O14(OH)2

Ferrilotharmeyerite

Formula: CaZnFe3+(AsO4)2(OH) · H2O

Description: The sample described by WALENTA (2002) was in fact Zn-dominant.

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Ferroberaunite

Formula: Fe2+Fe3+5(PO4)4(OH)5 · 6H2O

Florencite-(Ce)

Formula: CeAl3(PO4)2(OH)6

Florencite-(La)

Formula: LaAl3(PO4)2(OH)6

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Fluocerite-(Ce)

Formula: CeF3

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Fluocerite-(La)

Formula: LaF3

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Fluorapatite

Formula: Ca5(PO4)3F

Fluorite

Formula: CaF2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Schwarzenbruch, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Fluorite var. Stink-Fluss

Formula: CaF2

Fluorphosphohedyphane

Formula: Ca2Pb3(PO4)3F

Francevillite

Formula: Ba(UO2)2(VO4)2 · 5H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

'Freibergite Subgroup'

Formula: (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1

Gahnite

Formula: ZnAl2O4

Galena

Formula: PbS

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Gartrellite

Formula: PbCuFe3+(AsO4)2(OH) · H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Gasparite-(Ce)

Formula: Ce(AsO4)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Gearksutite

Formula: Ca[Al(F,OH)5(H2O)]

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Geerite

Formula: Cu8S5

Geocronite

Formula: Pb14Sb6S23

Gerhardtite

Formula: Cu2(NO3)(OH)3

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Gersdorffite

Formula: NiAsS

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Gilmarite

Formula: Cu3(AsO4)(OH)3

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

'Glauconite'

Formula: K0.60-0.85(Fe3+,Mg,Al)2(Si,Al)4O10](OH)2

Description: SEM-EDS by Joy Desor. Wet Chemical: Water content prooved by heating up in melting point tube.

Goethite

Formula: α-Fe3+O(OH)

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Goethite var. Samtblende

Formula: α-Fe3+O(OH)

Gold

Formula: Au

Goldhillite

Formula: Cu5Zn(AsO4)2(OH)6 · H2O

Gorceixite

Formula: BaAl3(PO4)(PO3OH)(OH)6

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)

Goudeyite

Formula: AlCu6(AsO4)3(OH)6 · 3H2O

Goyazite

Formula: SrAl3(PO4)(PO3OH)(OH)6

Graphite

Formula: C

Graulichite-(Ce)

Formula: CeFe3+3(AsO4)2(OH)6

Description: Pb-rich variety; very fine-grained.

Greenockite

Formula: CdS

Description: Originally reported greenockite (Kaiser, 1984) was later found to be amorphous CdS ("Xantochroite") (Walenta, 1992). Greenockite was later confirmed as well-developed tiny crystals (Milke & Schimak, 2011).

Guanajuatite

Formula: Bi2Se3

Guérinite

Formula: Ca6(HAsO4)3(AsO4)2 · 10.5H2O

Gustavite

Formula: AgPbBi3S6

Gypsum

Formula: CaSO4 · 2H2O

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Halite

Formula: NaCl

Halloysite

Formula: Al2(Si2O5)(OH)4

Halotrichite

Formula: FeAl2(SO4)4 · 22H2O

Hechtsbergite

Formula: Bi2(VO4)O(OH)

Heisenbergite

Formula: UO2(OH) · 2H2O (simplified UO3 · 2H2 O)

Hematite

Formula: Fe2O3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Hemimorphite

Formula: Zn4Si2O7(OH)2 · H2O

Hentschelite

Formula: CuFe3+2(PO4)2(OH)2

Heyrovskýite

Formula: Pb6Bi2S9

References:

Anthony, John Williams, Bideaux, Richard A., Bladh, Kenneth W., Nichols, Monte C. (1990) Handbook of Mineralogy Vol. 1 - Elements, Sulfides, Sulfosalts. Mineral Data Publishing, Tucson, Arizona.

Hidalgoite

Formula: PbAl3(AsO4)(SO4)(OH)6

Hloušekite

Formula: (Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2O

Hollandite

Formula: Ba(Mn4+6Mn3+2)O16

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Streckfeld, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Hornblende Root Name Group'

Formula: ◻Ca2(Z2+4Z3+)(AlSi7O22)(OH,F,Cl)2

Description: Exact nature appears to be unknown.

Hörnesite

Formula: Mg3(AsO4)2 · 8H2O

Hübnerite

Formula: MnWO4

Hydrocalumite

Formula: Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O

Hydrocerussite

Formula: Pb3(CO3)2(OH)2

Description: Some of the hydrocerussite (but not all) originates from the use of concrete as a constructing material underground.

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Hydrohalite

Formula: NaCl · 2H2O

Hydrokenoelsmoreite

Formula: ◻2W2O6(H2O)

Description: Usually brown-yellow, but black V- and Cr-bearing varieties are also known. Some samples grade into jixianite.

Hydrokenoelsmoreite var. Ferritungstite

Hydrokenoralstonite

Formula: Na0.5(Al,Mg)2(F,OH)6 · H2O

Hydroplumboelsmoreite ?

Formula: (Pb,◻)(W,Fe3+)2O6 · H2O

Description: 11/8/2016: Stuart Mills; original analysis by EDS + PXRD does not fully quantify the Pb content of the elsmoreite group mineral, therefore it is not certain that it corresponds to jixianite (itself of questionable status) or to Pb-rich hydroxykenoelsmoreite or hydrokenoelsmoreite or another new elsmoreite group mineral.

Hydrotalcite

Formula: Mg6Al2(CO3)(OH)16 · 4H2O

Hydrotungstite

Formula: WO3 · 2H2O

Hydrozincite

Formula: Zn5(CO3)2(OH)6

Ianthinite

Formula: U4+(UO2)5O7 · 10H2O

Description: Dehydrates (and turns yellow) to metaschoepite(?) and paraschoepite(?).

Idaite

Formula: Cu5FeS6

Ilmenite

Formula: Fe2+TiO3

Localities:

Frohnbach brook alluvials, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)

Iodargyrite

Formula: AgI

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Jalpaite

Formula: Ag3CuS2

Jamesonite

Formula: Pb4FeSb6S14

Jarosite

Formula: KFe3+3(SO4)2(OH)6

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Johnbaumite

Formula: Ca5(AsO4)3(OH)

Jordanite

Formula: Pb14As6S23

Kaolinite

Formula: Al2(Si2O5)(OH)4

Kasolite

Formula: Pb(UO2)(SiO4) · H2O

Kettnerite

Formula: CaBiCO3OF

Keutschite

Formula: Cu2AgAsS4

'K Feldspar'

'K Feldspar var. Adularia'

Formula: KAlSi3O8

Khaidarkanite

Formula: Cu4Al3(OH)14F3 · 2H2O

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis: 35(9): 22-27; 62 (in German).

Kidwellite

Formula: NaFe3+9+x(PO4)6(OH)11 · 3H2O, x = 0.33

Kintoreite

Formula: PbFe3(PO4)(PO3OH)(OH)6

Description: Habit similar to beudantite/segnitite and also corkite and indistinguishable from those without analysis.

Koechlinite

Formula: Bi2MoO6

Kornelite

Formula: Fe2(SO4)3 · 7H2O

Köttigite

Formula: Zn3(AsO4)2 · 8H2O

Langite

Formula: Cu4(SO4)(OH)6 · 2H2O

'Laubmannite (of Moore)'

Formula: (Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1.

Laueite

Formula: Mn2+Fe3+2(PO4)2(OH)2 · 8H2O

Laumontite

Formula: CaAl2Si4O12 · 4H2O

Laurelite

Formula: Pb7F12Cl2

Lavendulan

Formula: NaCaCu5(AsO4)4Cl · 5H2O

Leadhillite

Formula: Pb4(CO3)2(SO4)(OH)2

Lenoblite

Formula: V4+2O4 · 2H2O

Lepidocrocite

Formula: γ-Fe3+O(OH)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wintereck, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Streckfeld, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Libethenite

Formula: Cu2(PO4)(OH)

'Limonite'

Linarite

Formula: PbCu(SO4)(OH)2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)

Lindackerite

Formula: CuCu4(AsO4)2(HAsO4)2 · 9H2O

Lindbergite

Formula: Mn2+(C2O4) · 2H2O

Linnaeite

Formula: Co2+Co3+2S4

Lipscombite

Formula: Fe2+Fe3+2(PO4)2(OH)2

Löllingite

Formula: FeAs2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Lotharmeyerite

Formula: CaZn2(AsO4)2 · 2H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Lukrahnite

Formula: CaCuFe3+(AsO4)2(OH,H2O)2

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Luzonite

Formula: Cu3AsS4

Magnesiochromite

Formula: MgCr2O4

Magnesite

Formula: MgCO3

Magnetite

Formula: Fe2+Fe3+2O4

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Frohnbach brook alluvials, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Malachite

Formula: Cu2(CO3)(OH)2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Manganese Oxides'

Manganite

Formula: Mn3+O(OH)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Manganogel'

Formula: ~MnO2 · nH2O

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Marcasite

Formula: FeS2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Mascagnite

Formula: (NH4)2SO4

Massicot

Formula: PbO

Description: The massicot found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed mineral. The typical paragenesis includes hydrocerussite.

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Matildite

Formula: AgBiS2

Mawbyite

Formula: PbFe3+2(AsO4)2(OH)2

Mckinstryite

Formula: Ag5-xCu3+xS4

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Melanterite

Formula: Fe2+(H2O)6SO4 · H2O

Meniaylovite

Formula: Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O

Mercury

Formula: Hg

Mereheadite

Formula: Pb47Cl25(OH)13O24(CO3)(BO3)2

Meta-autunite

Formula: Ca(UO2)2(PO4)2 · 6H2O

Metaheinrichite

Formula: Ba(UO2)2(AsO4)2 · 8H2O

Metanováčekite

Formula: Mg(UO2)2(AsO4)2 · 8H2O

Metaschoepite ?

Formula: (UO2)8O2(OH)12 · 10H2O

Metatorbernite

Formula: Cu(UO2)2(PO4)2 · 8H2O

Metatyuyamunite

Formula: Ca(UO2)2(VO4)2 · 3H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Metazeunerite

Formula: Cu(UO2)2(AsO4)2 · 8H2O

Meurigite-K

Formula: KFe3+8(PO4)6(OH)7 · 6.5H2O

Description: See also phosphofibrite.

Meymacite

Formula: WO3 · 2H2O

Microcline

Formula: K(AlSi3O8)

Microcline var. Hyalophane

Formula: (K,Ba)[Al(Si,Al)Si2O8]

Millerite

Formula: NiS

Mimetite

Formula: Pb5(AsO4)3Cl

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Mimetite var. Campylite

Formula: Pb5(AsO4)3Cl

Mixite

Formula: BiCu6(AsO4)3(OH)6 · 3H2O

Mohrite

Formula: (NH4)2Fe(SO4)2 · 6H2O

Molybdenite

Formula: MoS2

Monazite-(Ce)

Formula: Ce(PO4)

Monazite-(La)

Formula: La(PO4)

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Monohydrocalcite

Formula: CaCO3 · H2O

Montmorillonite

Formula: (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O

Moolooite

Formula: Cu(C2O4) · nH2O

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis: 35(9): 22-27; 62 (in German).

Mottramite

Formula: PbCu(VO4)(OH)

Muscovite

Formula: KAl2(AlSi3O10)(OH)2

Muscovite var. Fuchsite

Formula: K(Al,Cr)3Si3O10(OH)2

Description: Green scaly aggregate in the so-called "Scheelite paragenesis".

Muscovite var. Illite

Formula: K0.65Al2.0[Al0.65Si3.35O10](OH)2

Muscovite var. Sericite

Formula: KAl2(AlSi3O10)(OH)2

Namibite

Formula: Cu(BiO)2(VO4)(OH)

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Natrodufrénite

Formula: NaFe2+Fe3+5(PO4)4(OH)6 · 2H2O

Natrozippeite

Formula: Na5(UO2)8(SO4)4O5(OH)3 · 12H2O

Naumannite

Formula: Ag2Se

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Nickeline

Formula: NiAs

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Nickellotharmeyerite

Formula: CaNi2(AsO4)2 · 2H2O

Nickelskutterudite

Formula: NiAs3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Description: Originally described as chloanthite.

Nickeltsumcorite

Formula: Pb(Ni,Fe3+)2(AsO4)2(H2O,OH)2

Nollmotzite (TL)

Formula: Mg[U5+(U6+O2)2O4F3] · 4H2O

Type Locality:

References:

Plášil, Jakub, Kampf, Anthony R., Škoda, Radek, Čejka, Jiří (2018) Nollmotzite, Mg[UV(UVIO2)2O4F3]·4H2O, the first natural uranium oxide containing fluorine. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 74 (4) 362-369 doi:10.1107/s2052520618007321

Nontronite

Formula: Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Nováčekite

Formula: Mg(UO2)2(AsO4)2 · 10H2O

Nsutite

Formula: (Mn4+,Mn2+)(O,OH)2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Oberwolfachite (TL)

Formula: SrFe3+3(AsO4)(SO4)(OH)6

Type Locality:

References:

Chukanov, Nikita V., Möhn, Gerhard, Dal Bo, Fabrice, Zubkova, Natalia V., Varlamov, Dmitry A., Pekov, Igor V., Jouffret, Laurent, Henot, Jean-Marc, Chollet, Pascal, Vessely, Yannick, Friis, Henrik, Ksenofontov, Dmitry A., Agakhanov, Atali A., Britvin, Sergey N., Desor, Joy, Koshlyakova, Natalia N., Pushcharovsky, Dmitry Yu. (2021) Oberwolfachite, SrFe3+3(AsO4)(SO4)(OH)6, a new alunite-supergroup mineral from the Clara mine, Schwarzwald, Germany and Monterniers mine, Rhône, France. Mineralogical Magazine, 85 (5) 808-816 doi:10.1180/mgm.2021.63

Ogdensburgite

Formula: Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O

Olenite

Formula: NaAl3Al6(Si6O18)(BO3)3O3(OH)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Olivenite

Formula: Cu2(AsO4)(OH)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Olivenite var. Zinc-bearing Olivenite

Formula: (Cu,Zn)2(AsO4)(OH)

Description: Some of this (especially with Cu:Zn around 1:1) may actually represent zincolivenite.

Omphacite

Formula: (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6

Opal

Formula: SiO2 · nH2O

Opal var. Opal-AN

Formula: SiO2 · nH2O

Orthoclase

Formula: K(AlSi3O8)

Osarizawaite

Formula: Pb(Al2Cu2+)(SO4)2(OH)6

Description: The osarizawaite described from the Clara mine [SCHNORRER-KÖHLER, G. (1988): Osarizawait, PbCuAl2(SO4)2(OH)6, ein Mineral der Alunit-Beudantit-Crandallit-Gruppe aus der Grube Clara im Schwarzwald. - Aufschluss, 39 (1), 49-51. (in German)], which was only identified by XRD and polarised-light microscopy, later was found to be a complex solid-solution member of the crandallite group instead [KOLITSCH, U., BLASS, G., GRAF, H.-W. & GRÖBNER, J. (2004): Neufunde aus der Grube Clara im mittleren Schwarzwald. Lapis 29 (2) 18-23; 50. (in German)

Oxyplumboroméite

Formula: Pb2Sb2O6O

Paraschoepite ?

Formula: UO3 · 2H2O

Parasymplesite

Formula: Fe2+3(AsO4)2 · 8H2O

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Paratacamite

Formula: Cu3(Cu,Zn)(OH)6Cl2

Parnauite

Formula: Cu9(AsO4)2(SO4)(OH)10 · 7H2O

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pavonite

Formula: AgBi3S5

Pearceite

Formula: [Ag6As2S7][Ag9CuS4]

'Pearceite-Tac'

References:

Hejny, C., Wierer, A., Venturi, A. (2021): High pressure behaviour of pearceite-polybasite group minerals. Poster, MinPet 2021, Vienna, Austria, September 19-21, 2021

Pentlandite

Formula: (NixFey)Σ9S8

Perovskite

Formula: CaTiO3

Pharmacosiderite

Formula: KFe3+4(AsO4)3(OH)4 · 6-7H2O

Phaunouxite

Formula: Ca3(AsO4)2 · 11H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Philipsbornite

Formula: PbAl3(AsO4)(AsO3OH)(OH)6

Philipsburgite ?

Formula: Cu5Zn(AsO4)(PO4)(OH)6 · H2O

Description: Blaß, G. & Graf, H. W. (1994): Neufunde von bekannten Fundstellen (XI). Mineralien-Welt 5 (3), 53-55. describe a "P-free" phillipsburgite which corresponds to goldhillite (IMA 2021-034).

Phlogopite

Formula: KMg3(AlSi3O10)(OH)2

Phosgenite

Formula: Pb2CO3Cl2

Phosphofibrite (TL)

Formula: (H2O,K)3.5Fe8(PO4)6(OH)7 · 5H2O

Type Locality:

Description: A Cu-free variety is described by Walenta (1997); see also meurigite.

Phosphohedyphane

Formula: Ca2Pb3(PO4)3Cl

Phosphosiderite

Formula: FePO4 · 2H2O

Phyllotungstite (TL)

Formula: (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K)

Type Locality:

Pitticite

Formula: (Fe, AsO4, H2O) (?)

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Plagionite

Formula: Pb5Sb8S17

Plumboagardite

Formula: (Pb,REE,Ca)Cu6(AsO4)3(OH)6 · 3H2O

Plumbogummite

Formula: PbAl3(PO4)(PO3OH)(OH)6

Plumbojarosite

Formula: Pb0.5Fe3+3(SO4)2(OH)6

Plumbonacrite

Formula: Pb5O(OH)2(CO3)3

Description: All or at least the majority of the plumbonacrite found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed mineral.

Polybasite

Formula: [Ag6Sb2S7][Ag9CuS4]

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Polybasite-Tac'

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Polydymite

Formula: Ni2+Ni3+2S4

Posnjakite

Formula: Cu4(SO4)(OH)6 · H2O

Prehnite

Formula: Ca2Al2Si3O10(OH)2

Preisingerite

Formula: Bi3(AsO4)2O(OH)

Prosopite

Formula: CaAl2F4[(OH)4-xFx]

Protasite

Formula: Ba(UO2)3O3(OH)2 · 3H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Proustite

Formula: Ag3AsS3

Pseudomalachite

Formula: Cu5(PO4)2(OH)4

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Pucherite

Formula: Bi(VO4)

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Pyrargyrite

Formula: Ag3SbS3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pyrite

Formula: FeS2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pyrite var. Bravoite

Formula: (Fe,Ni)S2

Pyrolusite

Formula: Mn4+O2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pyromorphite

Formula: Pb5(PO4)3Cl

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pyrostilpnite

Formula: Ag3SbS3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Pyrrhotite

Formula: Fe1-xS

Quartz

Formula: SiO2

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Quartz var. Agate

Quartz var. Amethyst

Formula: SiO2

Quartz var. Aventurine

Formula: SiO2

Quartz var. Carnelian

Quartz var. Chalcedony

Formula: SiO2

Quartz var. Eisenkiesel

Formula: SiO2

Quartz var. Milky Quartz

Formula: SiO2

Quartz var. Rock Crystal

Formula: SiO2

Quartz var. Smoky Quartz

Formula: SiO2

Rammelsbergite

Formula: NiAs2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Ramsdellite

Formula: Mn4+O2

Rankachite (TL)

Formula: Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O

Type Locality:

Habit: Tabular to fibrous

Colour: Dark brown

Raspite

Formula: Pb(WO4)

Rauenthalite

Formula: Ca3(AsO4)2 · 10H2O

Reichenbachite

Formula: Cu5(PO4)2(OH)4

Description: Analysed by J. Desor & G. Blaß (EDX + Raman)

'Rhabdophane'

Rhabdophane-(Ce)

Formula: Ce(PO4) · 0.6H2O

Rhabdophane-(Ce) var. Lead-bearing Rhabdophane-(Ce)

Formula: (Ce,La,Pb)(PO4) · H2O

Rhabdophane-(La)

Formula: La(PO4) · H2O

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Rhabdophane-(Nd)

Formula: Nd(PO4) · H2O

Rhodochrosite

Formula: MnCO3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Rhomboclase

Formula: (H5O2)Fe3+(SO4)2 · 2H2O

Richelsdorfite

Formula: Ca2Cu5Sb(AsO4)4(OH)6Cl · 6H2O

Rietveldite

Formula: Fe(UO2)(SO4)2(H2O)5

Rockbridgeite

Formula: Fe2+Fe3+4(PO4)3(OH)5

Romanèchite

Formula: (Ba,H2O)2(Mn4+,Mn3+)5O10

'Roméite Group'

Formula: A2(Sb5+)2O6Z

'Roméite Group var. Bismutostibiconite' (FRL)

Formula: Bi(Sb5+,Fe3+)2O7

Type Locality:

Römerite

Formula: Fe2+Fe3+2(SO4)4 · 14H2O

Rooseveltite

Formula: Bi(AsO4)

Rosasite

Formula: (Cu,Zn)2(CO3)(OH)2

Roscoelite

Formula: K(V3+,Al)2(AlSi3O10)(OH)2

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Rosiaite

Formula: PbSb5+2O6

Rouaite

Formula: Cu2(NO3)(OH)3

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Roxbyite

Formula: Cu9S5

Rozenite

Formula: FeSO4 · 4H2O

Russellite

Formula: Bi2WO6

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Rutherfordine

Formula: (UO2)CO3

Rutile

Formula: TiO2

Safflorite

Formula: (Co,Ni,Fe)As2

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Sainfeldite

Formula: Ca5(AsO4)2(AsO3OH)2 · 4H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Scheelite

Formula: Ca(WO4)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Schoepite

Formula: (UO2)8O2(OH)12 · 12H2O

Schorl

Formula: NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Schultenite

Formula: Pb(HAsO4)

Schumacherite

Formula: Bi3(VO4)2O(OH)

Scorodite

Formula: Fe3+AsO4 · 2H2O

Scotlandite

Formula: PbSO3

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Seelite

Formula: Mg(UO2)(As3+O3)0.7(AsO4)0.3 · 7H2O

Segnitite

Formula: PbFe3+3AsO4(AsO3OH)(OH)6

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Selbite'

Formula: (Ag2S, CaMg(CO3)2, Ag)

Selenium

Formula: Se

Sellaite

Formula: MgF2

Semseyite

Formula: Pb9Sb8S21

Sengierite

Formula: Cu2(UO2)2(VO4)2 · 6H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Serpierite

Formula: Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O

Siderite

Formula: FeCO3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Description: Often Mn-bearing.

Siderite var. Sphärosiderite

Formula: FeCO3

Description: Described and photographed specimen does not fit the definition of sphärosiderite.

'Siderogel'

Formula: ~FeO(OH) · nH2O

Siderotil

Formula: FeSO4 · 5H2O

Sidpietersite

Formula: Pb2+4(S2O3)O2(OH)2

Description: in the collection of F. Schimak. Sidpietersite forms white thin tabular xls xls close to galena. A SXRD confirmed sidpietersite Raman reference from Tsumeb was used to confirm sidpietersite from the Clara mine. The mineral is light sensitive and easily burns when using higher laser intensity. The thiosulfate transition is around 440cm^(-1).

Siegenite

Formula: CoNi2S4

Sillimanite

Formula: Al2(SiO4)O

Silver

Formula: Ag

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Skinnerite

Formula: Cu3SbS3

Sklodowskite

Formula: Mg(UO2)2(SiO3OH)2 · 6H2O

Skutterudite

Formula: CoAs3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Slottaite (TL)

Formula: SrFe3+3(PO4)(SO4)(OH)6

Type Locality:

Smithsonite

Formula: ZnCO3

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Smythite

Formula: (Fe,Ni)3+xS4 (x=0-0.3)

Spangolite

Formula: Cu6Al(SO4)(OH)12Cl · 3H2O

Spertiniite

Formula: Cu(OH)2

Description: The influence of concrete (used underground) on the genesis of this mineral is unclear.

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Sphalerite

Formula: ZnS

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Spionkopite

Formula: Cu39S28

Stephanite

Formula: Ag5SbS4

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Stewartite

Formula: Mn2+Fe3+2(PO4)2(OH)2 · 8H2O

'Stibiconite'

Formula: Sb3+Sb5+2O6(OH)

Stibnite

Formula: Sb2S3

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Stolzite

Formula: Pb(WO4)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Strashimirite

Formula: Cu8(AsO4)4(OH)4 · 5H2O

Strelkinite

Formula: Na2(UO2)2(VO4)2 · 6H2O

Strengite

Formula: FePO4 · 2H2O

Stromeyerite

Formula: AgCuS

Strontianite

Formula: SrCO3

Studtite

Formula: [(UO2)(O2)(H2O)2] · H2O

Sulphur

Formula: S8

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Susannite

Formula: Pb4(CO3)2(SO4)(OH)2

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.-W. (2007) Neufunde aus der Grube Clara im mittleren Schwarzwald (III): Cerianit-(Ce), Dravit, Florencit-(La), Gilmarit, Olenit und Scotlandit. Lapis, 32 (6) 19-23

Svabite

Formula: Ca5(AsO4)3F

Symplesite

Formula: Fe2+3(AsO4)2 · 8H2O

Synchysite-(Ce)

Formula: CaCe(CO3)2F

Szomolnokite

Formula: FeSO4 · H2O

Takovite

Formula: Ni6Al2(OH)16[CO3] · 4H2O

Talc

Formula: Mg3Si4O10(OH)2

Tangdanite

Formula: Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O

Tennantite-(Fe)

Formula: Cu6(Cu4Fe2+2)As4S12S

'Tennantite Subgroup'

Formula: Cu6(Cu4C2+2)As4S12S

'Tennantite-Tetrahedrite Series'

Tennantite-(Zn)

Formula: Cu6(Cu4Zn2)As4S12S

Tenorite

Formula: CuO

Tetrahedrite-(Cd)

Formula: Cu6(Cu4Cd2)Sb4S12S

Tetrahedrite-(Fe)

Formula: Cu6(Cu4Fe2+2)Sb4S12S

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

'Tetrahedrite Subgroup'

Formula: Cu6(Cu4C2+2)Sb4S12S

Localities:

Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Tetrahedrite-(Zn)

Formula: Cu6(Cu4Zn2)Sb4S12S

Theisite

Formula: Cu5Zn5(AsO4,SbO4)2(OH)14

Thometzekite

Formula: PbCu2+2(AsO4)2 · 2H2O

Tinticite

Formula: Fe3+3(PO4)2(OH)3 · 3H2O

Titanite

Formula: CaTi(SiO4)O

Todorokite

Formula: (Na,Ca,K,Ba,Sr)1-x(Mn,Mg,Al)6O12 · 3-4H2O

Torbernite

Formula: Cu(UO2)2(PO4)2 · 12H2O

Tripuhyite

Formula: Fe3+Sb5+O4

Tschermigite

Formula: (NH4)Al(SO4)2 · 12H2O

Tsumcorite

Formula: PbZn2(AsO4)2 · 2H2O

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Tsumebite

Formula: Pb2Cu(PO4)(SO4)(OH)

Tungstibite (TL)

Formula: Sb3+2WO6

Type Locality:

Habit: Spherical or radiating fibrous aggregates; chlorite-like

Colour: Greyish green

Tyrolite

Formula: Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O

Tyuyamunite

Formula: Ca(UO2)2(VO4)2 · 5-8H2O

'UKI-1975-(SO:AlCu)'

Formula: (Cu, Al, SO4, H2O)

'UM1975-08-AsOSO:FeHPb'

Formula: Pb2Fe(AsO4)(SO4)(OH)

'UM1999-38-WO:CrV'

Formula: (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]

'UM2004-56-OS:BiCuPb'

Formula: PbCu4Bi4S2(O,OH,H2O)16 (?)

'UM2005-31-SiO:CuH'

Formula: Cu11(SiO4)(OH)18 · 9H2O (?)

Umangite

Formula: Cu3Se2

'Unnamed (Arseniosiderite-related mineral)'

Formula: Ca, Fe, As, O, H

'Unnamed (Ba-analogue of Calcioaravaipaite)'

Formula: ~BaCa2Al(F,OH)9

'Unnamed (Ba-Fe Vanadate)'

Formula: Ba, Fe, V, O, H

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

'Unnamed (Ba-Mn Oxalate Tetrahydrate)'

Formula: BaMn(C2O4)2 · 4H2O

'Unnamed (Ca Arsenate Hydrate II)'

Formula: Ca3(AsO4)2 · ~5.9H2O

'Unnamed (Ce Tungstate)'

Formula: Ce2WO6 · nH2O (?)

'Unnamed (Fe-analogue of Argentotennantite-(Zn))'

Formula: Ag6(Cu4Fe2)As4S12S

'Unnamed (Kogarkoite-like mineral)'

Formula: Na, F, SO4 (?)

'Unnamed (P-analogue of Schultenite)'

Formula: PbH(PO4)

'Unnamed (Partially dehydrated Arsenuranospathite)'

Formula: Al(UO2)2(AsO4)2F · ~10H2O

'Unnamed (Pb Oxysulphate Hydrate)'

Formula: 3PbO · PbSO4 · H2O

Description: Formed by anthropogenous processes (concrete used in mine) (Kolitsch, 2000).

'Unnamed (Sb-analogue of Auriacusite)'

Formula: Fe3+Cu2+[(Sb,As)O4]O

References:

Aksenov, Sergey M., Chukanov, Nikita V., Göttlicher, Jörg, Möckel, Steffen, Varlamov, Dmitriy, Van, Konstantin V., Rastsvetaeva, Ramiza K. (2018) New insights into the crystal chemistry of agardite-(Ce): refinement of the crystal structure, hydrogen bonding, and epitaxial intergrowths with the Sb-analogue of auriacusite. Physics and Chemistry of Minerals, 45 (1) 39-50 doi:10.1007/s00269-017-0899-9

'Unnamed (Se-analogue of Dantopaite)'

Formula: Ag5Bi13(Se,S)22

'Unnamed (U-Ca Fluoride-Oxide(?))'

Formula: U, Ca, F, O(?)

Uraninite

Formula: UO2

Uraninite var. Pitchblende

Formula: UO2

Description: Unconfirmed at the time of Walenta (1982), but later found by several collectors. Often altered to secondary uranium minerals.

Uranophane

Formula: Ca(UO2)2(SiO3OH)2 · 5H2O

Uranosphaerite

Formula: Bi(UO2)O2(OH)

Description: Orange or red crystal aggregates.

Uranotungstite (TL)

Formula: (Ba0.35Pb0.27)Σ0.62[(U6+O2)2(W6+0.98Fe3+0.26◻0.75)O4.7(OH)2.5(H2O)1.75](H2O)1.67

Type Locality:

Uricite

Formula: C5H4N4O3

References:

Kolitsch, U., Gröbner, J., Brandstätter, F., Bayerl, R. (2010) Neufunde aus der Grube Clara im mittleren Schwarzwald (IV): Calcioandyrobertsit, Cotunnit, Gerhardtit, Khaidarkanit, Lukrahnit, Mckinstryit, Moolooit, Rhabdophan-(La), Rouait und Uricit. Lapis, 35 (9) München. 22-27

Usovite

Formula: Ba2CaMgAl2F14

Habit: Lath-shaped with sword-like outline.

Colour: Colourless

Vaesite

Formula: NiS2

Valentinite

Formula: Sb2O3

Varlamoffite

Formula: Sn1-xFexO2-x(OH)

Description: Reinvestigation by Walenta (1997) of originally described material strongly suggests a mixture of cassiterite and some amorphous substance.

Vaterite

Formula: CaCO3

Description: Sample described by Walenta (1995) originated due to the use of concrete in underground workings. Subsequent finds (Kolitsch et al., 2010) are clearly of different, natural origin.

Vauquelinite

Formula: Pb2Cu(CrO4)(PO4)(OH)

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Vésigniéite

Formula: BaCu3(VO4)2(OH)2

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Volborthite

Formula: Cu3(V2O7)(OH)2 · 2H2O

References:

Kolitsch, U., Götzinger, M. (2000) Einige Neufunde aus der Grube Clara im mittleren Schwarzwald: Eulytin, Namibit, Volborthit, Gearksutit, Spertiniit, Monazit-(La), Protasit, Sainfeldit, Cyanotrichit und Vauquelinit. Der Erzgräber, 14 (2) 33-47

Voltaite

Formula: K2Fe2+5Fe3+3Al(SO4)12 · 18H2O

Vyacheslavite

Formula: U(PO4)(OH)

Wakefieldite-(Ce)

Formula: Ce(VO4)

Description: Kolitsch et al. (2005): Cerium dominance not yet confirmed: the analysed sample is Nd-rich, but probably Ce-dominant; Kolitsch et al. (2019): Cerium dominance clearly confirmed (Ce:Nd ~ 2:1).

References:

Kolitsch, U., Gröbner, J., Blaß, G., Graf, H.W., Pring, A. (2005) Neufunde aus der Grube Clara im mittleren Schwarzwald (II): Dreyerit, Gasparit-(Ce), Klinobisvanit, Kobaltkoritnigit, Metatyuyamunit, Roscoelith, Sengierit, Vésigniéit und Wakefieldit. Lapis: 30(9): 35-39; 58 (in German).

Walpurgite

Formula: (BiO)4(UO2)(AsO4)2 · 2H2O

Weddellite

Formula: Ca(C2O4) · (2.5-x)H2O

Weilerite

Formula: BaAl3(AsO4)(SO4)(OH)6

Description: Never analytically confirmed; source uncertain.

Willemite

Formula: Zn2SiO4

Wittichenite

Formula: Cu3BiS3

Wooldridgeite

Formula: Na2CaCu2+2(P2O7)2 · 10H2O

Wroewolfeite

Formula: Cu4(SO4)(OH)6 · 2H2O

Wulfenite

Formula: Pb(MoO4)

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Wüstite

Formula: FeO

'Xanthochroite'

Formula: CdS

Habit: Thin glassy x-ray amorphous bright yellow crusts on gneiss

Colour: yellow

Xenotime-(Y)

Formula: Y(PO4)

Yarrowite

Formula: Cu9S8

Yttrotungstite-(Nd)

Formula: NdW2O7(OH) · H2O

Yukonite

Formula: Ca3Fe3+(AsO4)2(OH)3 · 5H2O

Localities:

Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany

Zálesíite

Formula: CaCu6(AsO4)2(AsO3OH)(OH)6 · 3H2O

Zeunerite

Formula: Cu(UO2)2(AsO4)2 · 12H2O

Zharchikhite

Formula: AlF(OH)2

Zincolivenite

Formula: CuZn(AsO4)(OH)

Description: Probably more common.

Zinkenite

Formula: Pb9Sb22S42

Zippeite

Formula: K3(UO2)4(SO4)2O3(OH) · 3H2O

Zircon

Formula: Zr(SiO4)