Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany (original) (raw)
Formula: Ag2S
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: ◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2
Formula: Zn2(AsO4)(OH)
ⓘ Adamite var. Copper-bearing Adamite
Formula: (Zn,Cu)2AsO4OH
Description: Possibly zincolivenite?
Formula: CeCu6(AsO4)3(OH)6 · 3H2O
Type Locality:
References:
Aksenov, Sergey M., Chukanov, Nikita V., Göttlicher, Jörg, Möckel, Steffen, Varlamov, Dmitriy, Van, Konstantin V., Rastsvetaeva, Ramiza K. (2018) New insights into the crystal chemistry of agardite-(Ce): refinement of the crystal structure, hydrogen bonding, and epitaxial intergrowths with the Sb-analogue of auriacusite. Physics and Chemistry of Minerals, 45 (1) 39-50 doi:10.1007/s00269-017-0899-9
Formula: LaCu6(AsO4)3(OH)6 · 3H2O
References:
Göb, S., Wenzel, T., Bau, M., Jacob, D. E., Loges, A., Markl, G. (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany. The Canadian Mineralogist, 49 (5) 1305-1333 doi:10.3749/canmin.49.5.1305
Formula: NdCu6(AsO4)3(OH)6 · 3H2O
References:
Göb, S., Wenzel, T., Bau, M., Jacob, D. E., Loges, A., Markl, G. (2011) The redistribution of rare-earth elements in secondary minerals of hydrothermal veins, Schwarzwald, southwestern Germany. The Canadian Mineralogist, 49 (5) 1305-1333 doi:10.3749/canmin.49.5.1305
Formula: YCu6(AsO4)3(OH)6 · 3H2O
Description: Never analytically confirmed; Dietrich et al. (1969), who had studied Clara agardites and "chlorotiles", only write that they are "relatively rich in Ce".
Formula: (Fe3+,Ni2+)8(OH,O)16Cl1.25 · nH2O
Formula: Na(AlSi3O8)
Formula: (Ag1-xSbx)
Formula: Co1-xFexAsS
Formula: (Al2O3)(SiO2)1.3-2 · 2.5-3H2O
Formula: Fe2+3Al2(SiO4)3
Formula: KAl(SO4)2 · 12H2O
Formula: (NH4)Fe3+3(SO4)2(OH)6
Formula: TiO2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: PbSO4
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaSO4
References:
Formula: Ca(Fe2+,Mg)(CO3)2
Description: Often confused with Fe-bearing dolomite. Analytically confirmed only by Kolitsch et al. (2019).
Formula: Ni3(AsO4)2 · 8H2O
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Sb
Formula: Cu3(SO4)(OH)4
Formula: CaCO3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb2Fe3+(AsO4)2(OH)
Type Locality:
References:
Formula: As
Formula: Ca2Fe3+3(AsO4)3O2 · 3H2O
Formula: CaAl3(AsO4)(AsO3OH)(OH)6
Formula: BaAl3(AsO4)(AsO3OH)(OH)6
Type Locality:
Habit: Crystalline crusts, tabular xls
Colour: Various shades
ⓘ 'Arsenogorceixite-Arsenogoyazite Series'
Formula: SrAl3(AsO4)(AsO3OH)(OH)6
Type Locality:
Formula: As2O3
Formula: FeAsS
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb2Cu(AsO4)(SO4)(OH)
Description: SO4-free variety.
Formula: CuFe3+2(AsO4)2(OH)2 · 4H2O
Formula: Cu2(OH)3Cl
Formula: Bi2(AsO4)O(OH)
Formula: Fe3+Cu2+(AsO4)O
Formula: (Zn,Cu)5(CO3)2(OH)6
Formula: Ca(UO2)2(PO4)2 · 10-12H2O
Description: Never confirmed by X-ray diffraction methods (unlike meta-autunite).
Formula: Cu3(CO3)2(OH)2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu3(AsO4)2 · 8H2O
Formula: (NH4)2[SiF6]
Formula: Al0.6(V5+,V4+)8O20 · 9H2O
Formula: Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O
Type Locality:
Formula: BaSO4
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Schwarzenbruch, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: BaSO4
Formula: Fe2+(UO2)2(PO4)2 · 10H2O
Formula: Ce(CO3)F
Formula: La(CO3)F
References:
Formula: Nd(CO3)F
References:
Formula: PbCu3(AsO4)2(OH)2
Formula: Pb(Fe3+2Cu)(SO4)2(OH)6
Formula: Ca(UO2)6O4(OH)6 · 8H2O
Formula: SrFe3+3(PO4)(PO3OH)(OH)6
Type Locality:
Habit: Tabular
Colour: Yellowish, brown-orange
Formula: Ag3Bi7S12
Formula: Fe3+6(PO4)4O(OH)4 · 6H2O
Formula: Fe(OH)3 · nH2O (n = 0.0 to 0.25)
Formula: Cu3Ag2Pb3Bi7S16
Formula: PbFe3(AsO4)(SO4)(OH)6
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ca(BiO)2(CO3)2
Formula: Ba(UO2)6O4(OH)6 · 4-8H2O
Formula: Ag7AsS6
Formula: Pb2Sb2O6O
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: K(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2
Formula: (Na,Ca)0.5(Mn4+,Mn3+)2O4 · 1.5H2O
Formula: Bi
Formula: Bi2S3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (BiO)2CO3
Formula: Fe3+2Bi(SiO4)2(OH)
Formula: (UO2)CO3 · H2O
Formula: AgBiSe2
Formula: Cu5FeS4
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu2(OH)3Cl
Formula: NiSb
Formula: Ni(Sb,As)
Formula: Cu4(SO4)(OH)6
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: AgBr
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: TiO2
Formula: Mg(OH)2
Formula: Fe3+24AlO6(PO4)17(OH)12 · 75H2O
Formula: KCaCu5(AsO4)4(H2AsO4) · 2H2O
References:
Formula: CaCO3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb5Cu2(SO4)3(CO3)(OH)6
Formula: Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4)
Formula: Cu4Al2(CO3,SO4)(OH)12 · 2H2O
Formula: Ca2[AlF6]F · H2O
Formula: PbFe3+2(AsO4)2(OH)2
Formula: K2(UO2)2(VO4)2 · 3H2O
Formula: SnO2
Formula: CoS2
Formula: K(MgFe3+◻)(Si4O10)(OH)2
Formula: SrSO4
Formula: (Ce4+,Th)O2
References:
Formula: PbCO3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Sb3+Sb5+O4
Formula: PbMn4+3O6(OH)2
Formula: CuSO4 · 5H2O
Formula: Cu2S
Formula: Cu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
Formula: CuFeS2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CuFe3+6(PO4)4(OH)8 · 4H2O
Formula: (Fe2+)5Al(Si,Al)4O10(OH,O)8
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu2Fe3+2(AsO4)2(OH)4
Formula: AgCl
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Fe2+Cr3+2O4
Formula: Cu2-xAlx(H2-xSi2O5)(OH)4 · nH2O, x < 1
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2O
Formula: HgS
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (NH4)2Fe3(SO4)4(OH)3 · 3H2O
Formula: (Cu,Zn)15(CO3)4(AsO4)2(SO4)(OH)14 · 7H2O
Type Locality:
Formula: PbSe
Formula: Bi(VO4)
References:
Formula: Mg5Al(AlSi3O10)(OH)8
Description: Reported as "pennine" by Kaiser (1984)
Formula: Cu3(AsO4)(OH)3
Formula: CoAsS
Formula: Co(AsO3OH) · H2O
References:
Formula: U(SiO4) · nH2O
Formula: CaCu(AsO4)(OH)
Formula: Cu19(SO4)(OH)32Cl4 · 3H2O
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Fe2+Fe3+4(SO4)6(OH)2 · 20H2O
Formula: Cu
Formula: AlFe3(SO4)6(H2O)12 · 6H2O
Formula: (Mg,Fe)2Al3(AlSi5O18)
Formula: PbFe3(PO4)(SO4)(OH)6
Description: The mineral contains only traces of sulphate and, therefore, is possibly a new mineral (P-analogue of segnitite)
Formula: Cu5(AsO4)2(OH)4
Formula: Cu5(AsO4)2(OH)4
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb(Mn4+6Mn3+2)O16
Formula: PbCl2
References:
Formula: CuS
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaAl3(PO4)(PO3OH)(OH)6
Formula: (NH4)2[SiF6]
Formula: K(Mn4+7Mn3+)O16
Formula: Cu2Al(OH)6[Sb5+(OH)6]
Type Locality:
Formula: (Cu,Al)3(OH)6[Sb5+(OH)6]
Type Locality:
Habit: Tabular with triangular outline
Colour: Pale bluish
Formula: Cu2AlSb(OH)12
Formula: Cu2O
Formula: Cu2O
Formula: Cu8AgBi13S24
Formula: Cu0.9Ag0.5Pb0.6Bi2.5S5
Formula: [Cu6As2S7][Ag9CuS4]
Formula: [Cu6Sb2S7][Ag9CuS4]
Formula: Cu2Sb2(O,OH)7
Formula: Cu2(WO4)(OH)2
Formula: Cu4Al2(SO4)(OH)12 · 2H2O
References:
Formula: Ag5Bi13S22
Formula: CuFeO2
Formula: PbZn(VO4)(OH)
Formula: CaCu4(SO4)2(OH)6 · 3H2O
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Fe3+2(PO4)(SO4)(OH) · 6H2O
Formula: Ag3Pb2Sb3S8
Formula: Cu9S5
Formula: Cu31S16
Formula: CaMg(CO3)2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Al(OH)3
Formula: NaMg3Al6(Si6O18)(BO3)3(OH)3(OH)
References:
Formula: Bi(VO4)
Description: small straw yellow crystals in the sub mm size range is accompanied by limonite, baryte and quartz in vugs in dark purple fluorite (stinkspath)
References:
Formula: Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O
Formula: PbCu(AsO4)(OH)
References:
Formula: BaFe3+3(AsO4)(AsO3OH)(OH)6
Formula: Ag3Sb
Type Locality:
Description: 11/8/2016: Stuart Mills; original analysis by EDS + PXRD does not fully quantify the Pb content of the elsmoreite group mineral, therefore it is not certain that it corresponds to jixianite (itself of questionable status) or to Pb-rich hydroxykenoelsmoreite or hydrokenoelsmoreite or another new elsmoreite group mineral.
Formula: Pb4Cu(SO4)O2(OH)4 · H2O
Description: Part of the elyite originated due to the use of concrete in underground workings. Other samples clearly show a natural origin.
References:
Formula: CuBiS2
Formula: Cu3AsS4
Formula: Co3(AsO4)2 · 8H2O
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ca6Al2(SO4)3(OH)12 · 26H2O
Description: The ettringite found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed phase.
Formula: Bi4(SiO4)3
References:
Formula: Cu3SbS4
Formula: FeWO4
Formula: Fe3+O(OH)
Formula: Fe3+10O14(OH)2
Formula: CaZnFe3+(AsO4)2(OH) · H2O
Description: The sample described by WALENTA (2002) was in fact Zn-dominant.
References:
Formula: Fe2+Fe3+5(PO4)4(OH)5 · 6H2O
Formula: CeAl3(PO4)2(OH)6
Formula: LaAl3(PO4)2(OH)6
References:
Formula: CeF3
References:
Formula: LaF3
References:
Formula: Ca5(PO4)3F
Formula: CaF2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Schwarzenbruch, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaF2
Formula: Ca2Pb3(PO4)3F
Formula: Ba(UO2)2(VO4)2 · 5H2O
References:
Formula: (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1
Formula: ZnAl2O4
Formula: PbS
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: PbCuFe3+(AsO4)2(OH) · H2O
References:
Formula: Ce(AsO4)
References:
Formula: Ca[Al(F,OH)5(H2O)]
References:
Formula: Cu8S5
Formula: Pb14Sb6S23
Formula: Cu2(NO3)(OH)3
References:
Formula: NiAsS
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu3(AsO4)(OH)3
References:
Formula: K0.60-0.85(Fe3+,Mg,Al)2(Si,Al)4O10](OH)2
Description: SEM-EDS by Joy Desor. Wet Chemical: Water content prooved by heating up in melting point tube.
Formula: α-Fe3+O(OH)
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: α-Fe3+O(OH)
Formula: Au
Formula: Cu5Zn(AsO4)2(OH)6 · H2O
Formula: BaAl3(PO4)(PO3OH)(OH)6
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)
Formula: AlCu6(AsO4)3(OH)6 · 3H2O
Formula: SrAl3(PO4)(PO3OH)(OH)6
Formula: C
Formula: CeFe3+3(AsO4)2(OH)6
Description: Pb-rich variety; very fine-grained.
Formula: CdS
Description: Originally reported greenockite (Kaiser, 1984) was later found to be amorphous CdS ("Xantochroite") (Walenta, 1992). Greenockite was later confirmed as well-developed tiny crystals (Milke & Schimak, 2011).
Formula: Bi2Se3
Formula: Ca6(HAsO4)3(AsO4)2 · 10.5H2O
Formula: AgPbBi3S6
Formula: CaSO4 · 2H2O
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: NaCl
Formula: Al2(Si2O5)(OH)4
Formula: FeAl2(SO4)4 · 22H2O
Formula: Bi2(VO4)O(OH)
Formula: UO2(OH) · 2H2O (simplified UO3 · 2H2 O)
Formula: Fe2O3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Zn4Si2O7(OH)2 · H2O
Formula: CuFe3+2(PO4)2(OH)2
Formula: Pb6Bi2S9
References:
Formula: PbAl3(AsO4)(SO4)(OH)6
Formula: (Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2O
Formula: Ba(Mn4+6Mn3+2)O16
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Streckfeld, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
ⓘ 'Hornblende Root Name Group'
Formula: ◻Ca2(Z2+4Z3+)(AlSi7O22)(OH,F,Cl)2
Description: Exact nature appears to be unknown.
Formula: Mg3(AsO4)2 · 8H2O
Formula: MnWO4
Formula: Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2O
Formula: Pb3(CO3)2(OH)2
Description: Some of the hydrocerussite (but not all) originates from the use of concrete as a constructing material underground.
References:
Formula: NaCl · 2H2O
Formula: ◻2W2O6(H2O)
Description: Usually brown-yellow, but black V- and Cr-bearing varieties are also known. Some samples grade into jixianite.
ⓘ Hydrokenoelsmoreite var. Ferritungstite
Formula: Na0.5(Al,Mg)2(F,OH)6 · H2O
Formula: (Pb,◻)(W,Fe3+)2O6 · H2O
Description: 11/8/2016: Stuart Mills; original analysis by EDS + PXRD does not fully quantify the Pb content of the elsmoreite group mineral, therefore it is not certain that it corresponds to jixianite (itself of questionable status) or to Pb-rich hydroxykenoelsmoreite or hydrokenoelsmoreite or another new elsmoreite group mineral.
Formula: Mg6Al2(CO3)(OH)16 · 4H2O
Formula: WO3 · 2H2O
Formula: Zn5(CO3)2(OH)6
Formula: U4+(UO2)5O7 · 10H2O
Description: Dehydrates (and turns yellow) to metaschoepite(?) and paraschoepite(?).
Formula: Cu5FeS6
Formula: Fe2+TiO3
Localities:
Frohnbach brook alluvials, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)
Formula: AgI
References:
Formula: Ag3CuS2
Formula: Pb4FeSb6S14
Formula: KFe3+3(SO4)2(OH)6
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ca5(AsO4)3(OH)
Formula: Pb14As6S23
Formula: Al2(Si2O5)(OH)4
Formula: Pb(UO2)(SiO4) · H2O
Formula: CaBiCO3OF
Formula: Cu2AgAsS4
Formula: KAlSi3O8
Formula: Cu4Al3(OH)14F3 · 2H2O
References:
Formula: NaFe3+9+x(PO4)6(OH)11 · 3H2O, x = 0.33
Formula: PbFe3(PO4)(PO3OH)(OH)6
Description: Habit similar to beudantite/segnitite and also corkite and indistinguishable from those without analysis.
Formula: Bi2MoO6
Formula: Fe2(SO4)3 · 7H2O
Formula: Zn3(AsO4)2 · 8H2O
Formula: Cu4(SO4)(OH)6 · 2H2O
Formula: (Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1.
Formula: Mn2+Fe3+2(PO4)2(OH)2 · 8H2O
Formula: CaAl2Si4O12 · 4H2O
Formula: Pb7F12Cl2
Formula: NaCaCu5(AsO4)4Cl · 5H2O
Formula: Pb4(CO3)2(SO4)(OH)2
Formula: V4+2O4 · 2H2O
Formula: γ-Fe3+O(OH)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wintereck, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Streckfeld, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu2(PO4)(OH)
Formula: PbCu(SO4)(OH)2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany ? (more information)
Formula: CuCu4(AsO4)2(HAsO4)2 · 9H2O
Formula: Mn2+(C2O4) · 2H2O
Formula: Co2+Co3+2S4
Formula: Fe2+Fe3+2(PO4)2(OH)2
Formula: FeAs2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaZn2(AsO4)2 · 2H2O
References:
Formula: CaCuFe3+(AsO4)2(OH,H2O)2
References:
Formula: Cu3AsS4
Formula: MgCr2O4
Formula: MgCO3
Formula: Fe2+Fe3+2O4
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Frohnbach brook alluvials, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu2(CO3)(OH)2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ferdinand Mine (St. Ferdinand Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Mn3+O(OH)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: ~MnO2 · nH2O
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: FeS2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (NH4)2SO4
Formula: PbO
Description: The massicot found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed mineral. The typical paragenesis includes hydrocerussite.
References:
Formula: AgBiS2
Formula: PbFe3+2(AsO4)2(OH)2
Formula: Ag5-xCu3+xS4
References:
Formula: Fe2+(H2O)6SO4 · H2O
Formula: Ca4[(SO4)(SiF6)(AlF6)]F · 12H2O
Formula: Hg
Formula: Pb47Cl25(OH)13O24(CO3)(BO3)2
Formula: Ca(UO2)2(PO4)2 · 6H2O
Formula: Ba(UO2)2(AsO4)2 · 8H2O
Formula: Mg(UO2)2(AsO4)2 · 8H2O
Formula: (UO2)8O2(OH)12 · 10H2O
Formula: Cu(UO2)2(PO4)2 · 8H2O
Formula: Ca(UO2)2(VO4)2 · 3H2O
References:
Formula: Cu(UO2)2(AsO4)2 · 8H2O
Formula: KFe3+8(PO4)6(OH)7 · 6.5H2O
Description: See also phosphofibrite.
Formula: WO3 · 2H2O
Formula: K(AlSi3O8)
Formula: (K,Ba)[Al(Si,Al)Si2O8]
Formula: NiS
Formula: Pb5(AsO4)3Cl
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb5(AsO4)3Cl
Formula: BiCu6(AsO4)3(OH)6 · 3H2O
Formula: (NH4)2Fe(SO4)2 · 6H2O
Formula: MoS2
Formula: Ce(PO4)
Formula: La(PO4)
References:
Formula: CaCO3 · H2O
Formula: (Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O
Formula: Cu(C2O4) · nH2O
References:
Formula: PbCu(VO4)(OH)
Formula: KAl2(AlSi3O10)(OH)2
Formula: K(Al,Cr)3Si3O10(OH)2
Description: Green scaly aggregate in the so-called "Scheelite paragenesis".
Formula: K0.65Al2.0[Al0.65Si3.35O10](OH)2
Formula: KAl2(AlSi3O10)(OH)2
Formula: Cu(BiO)2(VO4)(OH)
References:
Formula: NaFe2+Fe3+5(PO4)4(OH)6 · 2H2O
Formula: Na5(UO2)8(SO4)4O5(OH)3 · 12H2O
Formula: Ag2Se
References:
Formula: NiAs
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaNi2(AsO4)2 · 2H2O
Formula: NiAs3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Description: Originally described as chloanthite.
Formula: Pb(Ni,Fe3+)2(AsO4)2(H2O,OH)2
Formula: Mg[U5+(U6+O2)2O4F3] · 4H2O
Type Locality:
References:
Plášil, Jakub, Kampf, Anthony R., Škoda, Radek, Čejka, Jiří (2018) Nollmotzite, Mg[UV(UVIO2)2O4F3]·4H2O, the first natural uranium oxide containing fluorine. Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, 74 (4) 362-369 doi:10.1107/s2052520618007321
Formula: Na0.3Fe2((Si,Al)4O10)(OH)2 · nH2O
References:
Formula: Mg(UO2)2(AsO4)2 · 10H2O
Formula: (Mn4+,Mn2+)(O,OH)2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: SrFe3+3(AsO4)(SO4)(OH)6
Type Locality:
References:
Chukanov, Nikita V., Möhn, Gerhard, Dal Bo, Fabrice, Zubkova, Natalia V., Varlamov, Dmitry A., Pekov, Igor V., Jouffret, Laurent, Henot, Jean-Marc, Chollet, Pascal, Vessely, Yannick, Friis, Henrik, Ksenofontov, Dmitry A., Agakhanov, Atali A., Britvin, Sergey N., Desor, Joy, Koshlyakova, Natalia N., Pushcharovsky, Dmitry Yu. (2021) Oberwolfachite, SrFe3+3(AsO4)(SO4)(OH)6, a new alunite-supergroup mineral from the Clara mine, Schwarzwald, Germany and Monterniers mine, Rhône, France. Mineralogical Magazine, 85 (5) 808-816 doi:10.1180/mgm.2021.63
Formula: Ca2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2O
Formula: NaAl3Al6(Si6O18)(BO3)3O3(OH)
References:
Formula: Cu2(AsO4)(OH)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
ⓘ Olivenite var. Zinc-bearing Olivenite
Formula: (Cu,Zn)2(AsO4)(OH)
Description: Some of this (especially with Cu:Zn around 1:1) may actually represent zincolivenite.
Formula: (NaaCabFe2+cMgd)(AleFe3+fFe2+gMgh)Si2O6
Formula: SiO2 · nH2O
Formula: SiO2 · nH2O
Formula: K(AlSi3O8)
Formula: Pb(Al2Cu2+)(SO4)2(OH)6
Description: The osarizawaite described from the Clara mine [SCHNORRER-KÖHLER, G. (1988): Osarizawait, PbCuAl2(SO4)2(OH)6, ein Mineral der Alunit-Beudantit-Crandallit-Gruppe aus der Grube Clara im Schwarzwald. - Aufschluss, 39 (1), 49-51. (in German)], which was only identified by XRD and polarised-light microscopy, later was found to be a complex solid-solution member of the crandallite group instead [KOLITSCH, U., BLASS, G., GRAF, H.-W. & GRÖBNER, J. (2004): Neufunde aus der Grube Clara im mittleren Schwarzwald. Lapis 29 (2) 18-23; 50. (in German)
Formula: Pb2Sb2O6O
Formula: UO3 · 2H2O
Formula: Fe2+3(AsO4)2 · 8H2O
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu3(Cu,Zn)(OH)6Cl2
Formula: Cu9(AsO4)2(SO4)(OH)10 · 7H2O
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: AgBi3S5
Formula: [Ag6As2S7][Ag9CuS4]
References:
Formula: (NixFey)Σ9S8
Formula: CaTiO3
Formula: KFe3+4(AsO4)3(OH)4 · 6-7H2O
Formula: Ca3(AsO4)2 · 11H2O
References:
Formula: PbAl3(AsO4)(AsO3OH)(OH)6
Formula: Cu5Zn(AsO4)(PO4)(OH)6 · H2O
Description: Blaß, G. & Graf, H. W. (1994): Neufunde von bekannten Fundstellen (XI). Mineralien-Welt 5 (3), 53-55. describe a "P-free" phillipsburgite which corresponds to goldhillite (IMA 2021-034).
Formula: KMg3(AlSi3O10)(OH)2
Formula: Pb2CO3Cl2
Formula: (H2O,K)3.5Fe8(PO4)6(OH)7 · 5H2O
Type Locality:
Description: A Cu-free variety is described by Walenta (1997); see also meurigite.
Formula: Ca2Pb3(PO4)3Cl
Formula: FePO4 · 2H2O
Formula: (H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K)
Type Locality:
Formula: (Fe, AsO4, H2O) (?)
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb5Sb8S17
Formula: (Pb,REE,Ca)Cu6(AsO4)3(OH)6 · 3H2O
Formula: PbAl3(PO4)(PO3OH)(OH)6
Formula: Pb0.5Fe3+3(SO4)2(OH)6
Formula: Pb5O(OH)2(CO3)3
Description: All or at least the majority of the plumbonacrite found to date originates from the use of concrete as a constructing material underground. It is not a naturally formed mineral.
Formula: [Ag6Sb2S7][Ag9CuS4]
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ni2+Ni3+2S4
Formula: Cu4(SO4)(OH)6 · H2O
Formula: Ca2Al2Si3O10(OH)2
Formula: Bi3(AsO4)2O(OH)
Formula: CaAl2F4[(OH)4-xFx]
Formula: Ba(UO2)3O3(OH)2 · 3H2O
References:
Formula: Ag3AsS3
Formula: Cu5(PO4)2(OH)4
References:
Formula: Bi(VO4)
References:
Formula: Ag3SbS3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: FeS2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Ludwigs Trost Mine (Ludwigstrost Mine), Kuschbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (Fe,Ni)S2
Formula: Mn4+O2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb5(PO4)3Cl
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ag3SbS3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Fe1-xS
Formula: SiO2
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: SiO2
Formula: SiO2
Formula: SiO2
Formula: SiO2
Formula: SiO2
Formula: SiO2
Formula: SiO2
Formula: NiAs2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Mn4+O2
Formula: Ca0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2O
Type Locality:
Habit: Tabular to fibrous
Colour: Dark brown
Formula: Pb(WO4)
Formula: Ca3(AsO4)2 · 10H2O
Formula: Cu5(PO4)2(OH)4
Description: Analysed by J. Desor & G. Blaß (EDX + Raman)
Formula: Ce(PO4) · 0.6H2O
ⓘ Rhabdophane-(Ce) var. Lead-bearing Rhabdophane-(Ce)
Formula: (Ce,La,Pb)(PO4) · H2O
Formula: La(PO4) · H2O
References:
Formula: Nd(PO4) · H2O
Formula: MnCO3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (H5O2)Fe3+(SO4)2 · 2H2O
Formula: Ca2Cu5Sb(AsO4)4(OH)6Cl · 6H2O
Formula: Fe(UO2)(SO4)2(H2O)5
Formula: Fe2+Fe3+4(PO4)3(OH)5
Formula: (Ba,H2O)2(Mn4+,Mn3+)5O10
Formula: A2(Sb5+)2O6Z
ⓘ 'Roméite Group var. Bismutostibiconite' (FRL)
Formula: Bi(Sb5+,Fe3+)2O7
Type Locality:
Formula: Fe2+Fe3+2(SO4)4 · 14H2O
Formula: Bi(AsO4)
Formula: (Cu,Zn)2(CO3)(OH)2
Formula: K(V3+,Al)2(AlSi3O10)(OH)2
References:
Formula: PbSb5+2O6
Formula: Cu2(NO3)(OH)3
References:
Formula: Cu9S5
Formula: FeSO4 · 4H2O
Formula: Bi2WO6
References:
Formula: (UO2)CO3
Formula: TiO2
Formula: (Co,Ni,Fe)As2
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Ca5(AsO4)2(AsO3OH)2 · 4H2O
References:
Formula: Ca(WO4)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (UO2)8O2(OH)12 · 12H2O
Formula: NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)
References:
Formula: Pb(HAsO4)
Formula: Bi3(VO4)2O(OH)
Formula: Fe3+AsO4 · 2H2O
Formula: PbSO3
References:
Formula: Mg(UO2)(As3+O3)0.7(AsO4)0.3 · 7H2O
Formula: PbFe3+3AsO4(AsO3OH)(OH)6
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Josephs Treu Mine (Josephstreu Mine), Tiefenbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (Ag2S, CaMg(CO3)2, Ag)
Formula: Se
Formula: MgF2
Formula: Pb9Sb8S21
Formula: Cu2(UO2)2(VO4)2 · 6H2O
References:
Formula: Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O
Formula: FeCO3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Description: Often Mn-bearing.
ⓘ Siderite var. Sphärosiderite
Formula: FeCO3
Description: Described and photographed specimen does not fit the definition of sphärosiderite.
Formula: ~FeO(OH) · nH2O
Formula: FeSO4 · 5H2O
Formula: Pb2+4(S2O3)O2(OH)2
Description: in the collection of F. Schimak. Sidpietersite forms white thin tabular xls xls close to galena. A SXRD confirmed sidpietersite Raman reference from Tsumeb was used to confirm sidpietersite from the Clara mine. The mineral is light sensitive and easily burns when using higher laser intensity. The thiosulfate transition is around 440cm^(-1).
Formula: CoNi2S4
Formula: Al2(SiO4)O
Formula: Ag
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu3SbS3
Formula: Mg(UO2)2(SiO3OH)2 · 6H2O
Formula: CoAs3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: SrFe3+3(PO4)(SO4)(OH)6
Type Locality:
Formula: ZnCO3
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: (Fe,Ni)3+xS4 (x=0-0.3)
Formula: Cu6Al(SO4)(OH)12Cl · 3H2O
Formula: Cu(OH)2
Description: The influence of concrete (used underground) on the genesis of this mineral is unclear.
References:
Formula: ZnS
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu39S28
Formula: Ag5SbS4
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Mn2+Fe3+2(PO4)2(OH)2 · 8H2O
Formula: Sb3+Sb5+2O6(OH)
Formula: Sb2S3
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb(WO4)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu8(AsO4)4(OH)4 · 5H2O
Formula: Na2(UO2)2(VO4)2 · 6H2O
Formula: FePO4 · 2H2O
Formula: AgCuS
Formula: SrCO3
Formula: [(UO2)(O2)(H2O)2] · H2O
Formula: S8
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Pb4(CO3)2(SO4)(OH)2
References:
Formula: Ca5(AsO4)3F
Formula: Fe2+3(AsO4)2 · 8H2O
Formula: CaCe(CO3)2F
Formula: FeSO4 · H2O
Formula: Ni6Al2(OH)16[CO3] · 4H2O
Formula: Mg3Si4O10(OH)2
Formula: Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O
Formula: Cu6(Cu4Fe2+2)As4S12S
Formula: Cu6(Cu4C2+2)As4S12S
ⓘ 'Tennantite-Tetrahedrite Series'
Formula: Cu6(Cu4Zn2)As4S12S
Formula: CuO
Formula: Cu6(Cu4Cd2)Sb4S12S
Formula: Cu6(Cu4Fe2+2)Sb4S12S
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu6(Cu4C2+2)Sb4S12S
Localities:
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: Cu6(Cu4Zn2)Sb4S12S
Formula: Cu5Zn5(AsO4,SbO4)2(OH)14
Formula: PbCu2+2(AsO4)2 · 2H2O
Formula: Fe3+3(PO4)2(OH)3 · 3H2O
Formula: CaTi(SiO4)O
Formula: (Na,Ca,K,Ba,Sr)1-x(Mn,Mg,Al)6O12 · 3-4H2O
Formula: Cu(UO2)2(PO4)2 · 12H2O
Formula: Fe3+Sb5+O4
Formula: (NH4)Al(SO4)2 · 12H2O
Formula: PbZn2(AsO4)2 · 2H2O
References:
Formula: Pb2Cu(PO4)(SO4)(OH)
Formula: Sb3+2WO6
Type Locality:
Habit: Spherical or radiating fibrous aggregates; chlorite-like
Colour: Greyish green
Formula: Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O
Formula: Ca(UO2)2(VO4)2 · 5-8H2O
Formula: (Cu, Al, SO4, H2O)
Formula: Pb2Fe(AsO4)(SO4)(OH)
Formula: (V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]
Formula: PbCu4Bi4S2(O,OH,H2O)16 (?)
Formula: Cu11(SiO4)(OH)18 · 9H2O (?)
Formula: Cu3Se2
ⓘ 'Unnamed (Arseniosiderite-related mineral)'
Formula: Ca, Fe, As, O, H
ⓘ 'Unnamed (Ba-analogue of Calcioaravaipaite)'
Formula: ~BaCa2Al(F,OH)9
Formula: Ba, Fe, V, O, H
References:
ⓘ 'Unnamed (Ba-Mn Oxalate Tetrahydrate)'
Formula: BaMn(C2O4)2 · 4H2O
ⓘ 'Unnamed (Ca Arsenate Hydrate II)'
Formula: Ca3(AsO4)2 · ~5.9H2O
Formula: Ce2WO6 · nH2O (?)
ⓘ 'Unnamed (Fe-analogue of Argentotennantite-(Zn))'
Formula: Ag6(Cu4Fe2)As4S12S
ⓘ 'Unnamed (Kogarkoite-like mineral)'
Formula: Na, F, SO4 (?)
ⓘ 'Unnamed (P-analogue of Schultenite)'
Formula: PbH(PO4)
ⓘ 'Unnamed (Partially dehydrated Arsenuranospathite)'
Formula: Al(UO2)2(AsO4)2F · ~10H2O
ⓘ 'Unnamed (Pb Oxysulphate Hydrate)'
Formula: 3PbO · PbSO4 · H2O
Description: Formed by anthropogenous processes (concrete used in mine) (Kolitsch, 2000).
ⓘ 'Unnamed (Sb-analogue of Auriacusite)'
Formula: Fe3+Cu2+[(Sb,As)O4]O
References:
Aksenov, Sergey M., Chukanov, Nikita V., Göttlicher, Jörg, Möckel, Steffen, Varlamov, Dmitriy, Van, Konstantin V., Rastsvetaeva, Ramiza K. (2018) New insights into the crystal chemistry of agardite-(Ce): refinement of the crystal structure, hydrogen bonding, and epitaxial intergrowths with the Sb-analogue of auriacusite. Physics and Chemistry of Minerals, 45 (1) 39-50 doi:10.1007/s00269-017-0899-9
ⓘ 'Unnamed (Se-analogue of Dantopaite)'
Formula: Ag5Bi13(Se,S)22
ⓘ 'Unnamed (U-Ca Fluoride-Oxide(?))'
Formula: U, Ca, F, O(?)
Formula: UO2
Formula: UO2
Description: Unconfirmed at the time of Walenta (1982), but later found by several collectors. Often altered to secondary uranium minerals.
Formula: Ca(UO2)2(SiO3OH)2 · 5H2O
Formula: Bi(UO2)O2(OH)
Description: Orange or red crystal aggregates.
Formula: (Ba0.35Pb0.27)Σ0.62[(U6+O2)2(W6+0.98Fe3+0.26◻0.75)O4.7(OH)2.5(H2O)1.75](H2O)1.67
Type Locality:
Formula: C5H4N4O3
References:
Formula: Ba2CaMgAl2F14
Habit: Lath-shaped with sword-like outline.
Colour: Colourless
Formula: NiS2
Formula: Sb2O3
Formula: Sn1-xFexO2-x(OH)
Description: Reinvestigation by Walenta (1997) of originally described material strongly suggests a mixture of cassiterite and some amorphous substance.
Formula: CaCO3
Description: Sample described by Walenta (1995) originated due to the use of concrete in underground workings. Subsequent finds (Kolitsch et al., 2010) are clearly of different, natural origin.
Formula: Pb2Cu(CrO4)(PO4)(OH)
References:
Formula: BaCu3(VO4)2(OH)2
References:
Formula: Cu3(V2O7)(OH)2 · 2H2O
References:
Formula: K2Fe2+5Fe3+3Al(SO4)12 · 18H2O
Formula: U(PO4)(OH)
Formula: Ce(VO4)
Description: Kolitsch et al. (2005): Cerium dominance not yet confirmed: the analysed sample is Nd-rich, but probably Ce-dominant; Kolitsch et al. (2019): Cerium dominance clearly confirmed (Ce:Nd ~ 2:1).
References:
Formula: (BiO)4(UO2)(AsO4)2 · 2H2O
Formula: Ca(C2O4) · (2.5-x)H2O
Formula: BaAl3(AsO4)(SO4)(OH)6
Description: Never analytically confirmed; source uncertain.
Formula: Zn2SiO4
Formula: Cu3BiS3
Formula: Na2CaCu2+2(P2O7)2 · 10H2O
Formula: Cu4(SO4)(OH)6 · 2H2O
Formula: Pb(MoO4)
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Fortuna Mine, Gelbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: FeO
Formula: CdS
Habit: Thin glassy x-ray amorphous bright yellow crusts on gneiss
Colour: yellow
Formula: Y(PO4)
Formula: Cu9S8
Formula: NdW2O7(OH) · H2O
Formula: Ca3Fe3+(AsO4)2(OH)3 · 5H2O
Localities:
Clara Mine, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Wenzel Mine, Frohnbach valley, Oberwolfach, Ortenaukreis, Freiburg Region, Baden-Württemberg, Germany
Formula: CaCu6(AsO4)2(AsO3OH)(OH)6 · 3H2O
Formula: Cu(UO2)2(AsO4)2 · 12H2O
Formula: AlF(OH)2
Formula: CuZn(AsO4)(OH)
Description: Probably more common.
Formula: Pb9Sb22S42
Formula: K3(UO2)4(SO4)2O3(OH) · 3H2O
Formula: Zr(SiO4)